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41. 发明专利

JPS6026006A COAGULATION OF POLYMER LATEX 失效
公开(公告)号：JPS6026006A
公开(公告)日：1985-02-08
申请号：JP13446483
申请日：1983-07-25
申请人： MITSUBISHI RAYON CO
发明人： SUGIMORI TERUHIKO , TAJIRI TAKAYUKI , HIRONAKA AKIO , HABARA HIDEAKI
IPC分类号： C08F6/00 , C08C1/00 , C08C1/15 , C08F6/22
摘要： PURPOSE:To achieve energy preservation and upgrading of product properties by process rationalization, by recirculating a filtrate obtained form solid/liquid separation to a pH adjustment tank for reuse. CONSTITUTION:A polymer latex (e.g., a latex obtained by emulsion-polymerizing an ethylenic monomer) is fed to a coagulation tank 1, where it is treated with a coagulating agent (e.g., sulfuric acid). The formed slurry is fed to a pH adjustment tank 2, where its pH is adjusted with a pH adjusting agent (e.g., sodium hydroxide). This slurry is then fed to a solidification tank 3, where it is treated at a predetermined solidification temperature, and then fed to a solid/liquid separation tank 4. The filtrate obtained here is recirculated through a line 5 to the pH adjustment tank 2. At this time, an alkaline substance is supplied from an alkali reservoir 6. By the recirculation and reuse of the filtrate, the process can be rationalized and at the same time, energy necessary for solid/liquid separation or the like, can reduced. In addition, it is possible to obtain a product property which is better than that obtained when an alkaline substance is added directly to the pH adjustment tank.

42. 发明专利

JPS5947692B2 JPS5947692B2 - 失效
公开(公告)号：JPS5947692B2
公开(公告)日：1984-11-21
申请号：JP12089775
申请日：1975-10-07
申请人： Mitsubishi Rayon Co
发明人： SUGIMORI TERUHIKO , HIRONAKA AKIO , TAJIRI TAKAYUKI
IPC分类号： C08L33/00 , C08J3/02 , C08L33/02 , C08L33/18 , C08L33/20 , D01F6/18 , D01F6/38

43. 发明专利

JPS59182801A Method for coagulating polymer latex 失效
标题翻译：凝聚聚合物的方法
公开(公告)号：JPS59182801A
公开(公告)日：1984-10-17
申请号：JP5770583
申请日：1983-03-31
申请人： Mitsubishi Rayon Co Ltd
发明人： SUGIMORI TERUHIKO , TAJIRI TAKAYUKI , HIRONAKA AKIO , HABARA HIDEAKI
IPC分类号： C08F6/00 , C08F6/22
摘要： PURPOSE: To obtain a polymer granular or particulate material having excellent powder characteristics, by coagulating the titled latex with a coagulating nozzle, capable of extruding a coagulating solution through the central part of a base board, and obtained by mounting capillaries on the base board under specific conditions.
CONSTITUTION: A nozzle for coagulating a latex, having a structure capable of extruding a coagulating solution through the central part of a base board 2, and obtained by mounting plural capillaries 1 on the base board 2 to give ≥1mm mutual gap between the capillaries 1 and ≥3mm protrusion length of the capillaries 1 on the base board 2 is usually dipped in a coagulation bath, and a polymer latex is introduced into a holder 3 of the above-mentioned nozzle, extruded through the tips of the capillaries 1 at the same time to come into contact with the coagulating solution around the nozzle and extruded through the central part of the base board 2 and coagulated.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：目的：为了获得具有优异粉末特性的聚合物颗粒或颗粒材料，通过凝结喷嘴的标题胶乳凝结，能够通过基板的中心部分挤出凝固溶液，并将毛细管安装在基板上具体条件。构成：用于凝结胶乳的喷嘴，其具有能够通过基板2的中心部分挤出凝结液的结构，并且通过将多个毛细管1安装在基板2上而得到= 1mm。毛细管1和> = 3mm之间的相互间隙。通常将基板2上的毛细管1的突出长度浸入凝固浴中，并将聚合物胶乳引入到上述喷嘴的保持器3中，同时通过毛细管1的尖端挤出与喷嘴周围的凝固溶液接触并通过基板2的中心部分挤出并凝结。

44. 发明专利

JPS5924709A Production of thermoplastic resin 失效
标题翻译：生产热塑性树脂
公开(公告)号：JPS5924709A
公开(公告)日：1984-02-08
申请号：JP13411582
申请日：1982-07-30
申请人： Mitsubishi Rayon Co Ltd
发明人： SUGIMORI TERUHIKO , TAJIRI TAKAYUKI
IPC分类号： C08F6/00 , C08F6/22 , C08F279/00 , C08F279/04
摘要： PURPOSE: To obtain the titled resin excellent in blendability and free from a need of washing operation, by coagulating an MBS resin latex at a temperature in a specified range to form a coagulated slurry, and adding thereto an alkaline substance at a temperature in a specified range to adjust its pH to a specified value.
CONSTITUTION: A latex of a thermoplastic resin is formed which contains a monomer component at least 90wt% of which consisting of butadiene, methyl methacrylate, and styrene. Then, this latex is brought into contact with a coagulating solution (an example of a coagulant being sulfuric acid) at a temperature in the range of 0W80°C to form a coagulated slurry and then an alkaline substance (e.g., sodium hydroxide) is added to the obtained slurry so that the pH of the slurry is higher by at least 0.1 than the initial pH, and that the pH of the entire mixture is adjusted to 7.0 or below. Then, the desired thermoplastic resin is obtained by solidifying the coagulated particles of the coagulated slurry by heating.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：目的：为了获得混合性优异且不需要洗涤操作的标题树脂，通过在特定范围的温度下使MBS树脂胶乳凝固形成凝固的浆料，并在特定温度下加入碱性物质范围将其pH值调整到指定值。构成：形成热塑性树脂的胶乳，其包含至少90重量％的由丁二烯，甲基丙烯酸甲酯和苯乙烯组成的单体成分。然后，使该胶乳在0-80℃的温度下与凝固溶液（作为硫酸的凝结剂的实例）接触以形成凝结的浆料，然后加入碱性物质（例如氢氧化钠）添加到所获得的浆料中，使得浆料的pH比初始pH高至少0.1，并且将整个混合物的pH调节至7.0以下。然后，通过加热固化凝固浆料的凝固颗粒，获得所需的热塑性树脂。

45. 发明专利

JPS5721411A Production of impact-resistant resin by continuous emulsion polymerization 失效
标题翻译：通过连续乳化聚合生产耐冲击树脂
公开(公告)号：JPS5721411A
公开(公告)日：1982-02-04
申请号：JP9591180
申请日：1980-07-14
申请人： Mitsubishi Rayon Co Ltd
发明人： SUGIMORI TERUHIKO , TAJIRI TAKAYUKI
IPC分类号： C08F4/00 , C08F2/22 , C08F2/44 , C08F4/04 , C08F4/28 , C08F4/32 , C08F279/02 , C08F291/00
摘要： PURPOSE: To produce title polymer having excellent impact resistance and appearance, by emulsion-polymerizing a monomer in the presence of a rubbery polymer with the aid of a combination of an azo compound type initiator and a peroxide type initiator.
CONSTITUTION: A rubbery polymer, e.g., polybutadiene, and one or more monomers, e.g., styrene or acrylonitrile, are dispersed in water in an amount of 80W 500pts.wt. per 100pts.wt. solids of the latex after polymerization, with the aid of an emulsifier, and emulsion-polymerized in the presence of an azo compound type initiator, e.g., 2,2'-azobiaisobutyronitrile, and a peroxide type initiator, e.g., 1- hydroxybutyl n-butyl peroxide.
EFFECT: It is possible to control the grafting ratio and the degree of polymerization of the polymer to be produced at desired values, by properly selecting the ratio of the azo compound type initiator to the peroxide type initiator.
COPYRIGHT: (C)1982,JPO&Japio
摘要翻译：目的：为了制备具有优异的耐冲击性和外观的标题聚合物，通过在偶联化合物型引发剂和过氧化物型引发剂的组合的帮助下，在橡胶状聚合物存在下使单体乳化聚合。构成：橡胶状聚合物，例如聚丁二烯和一种或多种单体，例如苯乙烯或丙烯腈，以80-500pts.wt。的量分散在水中。每100pts.wt 聚合后的胶乳的固体，借助于乳化剂，并在偶氮化合物型引发剂例如2,2'-偶氮二异丁腈和过氧化物型引发剂（例如1-羟基丁基）的存在下进行乳液聚合，丁基过氧化物。效果：通过适当选择偶氮化合物型引发剂与过氧化物型引发剂的比例，可以控制所需聚合物的接枝率和聚合度。

46. 发明专利

JPS5425270A CONCENTRATION APPARATUS 失效
公开(公告)号：JPS5425270A
公开(公告)日：1979-02-26
申请号：JP9013677
申请日：1977-07-27
申请人： MITSUBISHI RAYON CO
发明人： SUGIMORI TERUHIKO , HIRONAKA AKIO , TAJIRI TAKAYUKI
IPC分类号： D01F6/18 , B01D1/16
摘要： PURPOSE:To reduce the concentration time while accomplishing effective concentration with a section of pressurizing and heating intended liquid of medium viscosity separated retained separately from the concentration chember.

47. 发明专利

JPS5143427A 失效
公开(公告)号：JPS5143427A
公开(公告)日：1976-04-14
申请号：JP11532874
申请日：1974-10-07
申请人： MITSUBISHI RAYON CO
发明人： OSASHIMA YOSHIHIRO , SUGIMORI TERUHIKO , TAJIRI TAKAYUKI
IPC分类号： D01F6/18 , C08L33/20

48. 发明专利

JPH1010783A PRODUCTION OF RESIN BINDER FOR TONER 失效
公开(公告)号：JPH1010783A
公开(公告)日：1998-01-16
申请号：JP16608496
申请日：1996-06-26
申请人： MITSUBISHI RAYON CO
发明人： SHIMIZU KOJI , TAJIRI TAKAYUKI , INAGAKI MOTOJI , HARADA YOKO
IPC分类号： G03G9/087
摘要： PROBLEM TO BE SOLVED: To diminish a residual monomer in a resin in a short time without aggregating or caking resin particles and to suppress the emission of odor from a toner by using specified polymn. initiators and carrying out polymn. under specified polymn. conditions. SOLUTION: When a resin binder for a toner is produced by a suspension polymn. method using 1st and 2nd polymn. initiators in combination, a vinyl monomer mixture is suspension-polymerized with the 1st polymn. initiator and then heat treatment is carried out with the 2nd polymn. initiator whose 10hr half-life temp. is higher than that of the 1st polymn. initiator by 10-50 deg.C at a higher temp. than the 10hr half-life temp. of the 2nd polymn. initiator by 20-40 deg.C. Since the heat treatment is carried out after heating to a temp. region in which the high-temp. decomposition type 2nd polymn. initiator acts efficiently after the polymn. is practically finished, the residual monomer can be efficiently diminished in a short time.

49. 发明专利

JPH09216904A POWDER COATING RESIN AND ITS PRODUCTION 失效
公开(公告)号：JPH09216904A
公开(公告)日：1997-08-19
申请号：JP4846896
申请日：1996-02-13
申请人： MITSUBISHI RAYON CO
发明人： HARADA YOKO , INAGAKI MOTOJI , SHIMIZU KOJI , TAJIRI TAKAYUKI
IPC分类号： C08F2/38 , C08F220/10 , C08F220/32 , C09D5/03 , C09D125/00 , C09D125/08 , C09D133/04 , C09D133/06 , C09D133/14
摘要： PROBLEM TO BE SOLVED: To obtain a powder coating resin free from resin odor and excellent in film performance, etc., with good productivity by the suspension polymerization of a specified acrylic monomer component under specified temperature and pressure conditions using a chain transfer agent comprising terpinolene. SOLUTION: Thus resin comprises an acrylic resin and is produced by the suspension polymerization of a (meth)acrylic monomer component containing methyl (meth)acrylate, styrene monomer and glycidyl (meth)acrylate as the essential constituents at a temperature of 100 deg.C or higher under a pressure of 2kg/cm or above using a chain transfer agent comprising terpinolene. The amount of terpinolene is preferably controlled in a range from 0.1 to 5 pts.wt. based on 100 pts.wt. (meth)acrylic monomer component. It is desirable to use an azo compound having a 10-hr half-life temperature of below 60 deg.C (e.g. 2,2'- azobis-2,4-dimethylvaleronitrile) and an azo compound having a 10-hr half-life temperature of 60 deg.C or higher (e.g. 2,2'-azobisisobutyronitrile) as the polymerization initiators.

50. 发明专利

JPH0943899A POLYESTER RESIN FOR TONER AND TONER 失效
公开(公告)号：JPH0943899A
公开(公告)日：1997-02-14
申请号：JP19229695
申请日：1995-07-27
申请人： MITSUBISHI RAYON CO
发明人： IWASAKI HITOSHI , ITO KOICHI , NAGAI YOICHI , TAJIRI TAKAYUKI
IPC分类号： G03G9/087 , C08G63/16 , C08G63/18 , C08L67/00 , C08L67/02
摘要： PROBLEM TO BE SOLVED: To obtain a toner excellent in melt flowability and blocking resistance and capable of maintaining anti-offsetting property by using polyester resin obtd. by copolymn. with specified polycaprolactone as polyester resin for a toner. SOLUTION: This polyester resin is a polycondensation product consisting of acid components including arom. dicarboxylic acid as the principal component, at least one kind of arom. diol represented by formula I, diol components including aliphatic diol and at least one kind of polycaprolactone represented by formula II. The amt. of the arom. diol is 10-80mol% of the amt. of all the acid components, the amt. of the diol components including alipahtic diol is 20-90mol% of the amt. of all the acid components and the amt. of the polycaprolactone is 0.01-0.03mol% of the amt. of all the acid components. This polyester resin has 40-70 deg.C glass transition temp., 70-130 deg.C softening temp., a wt. average mol.wt. of 3,000-20,000 and a number average mol.wt. of 1,500-10,000. In the formulae I, II, each of R1 and R2 is

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