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41. 发明专利

JPS60152860A HEAT STORAGE WATER TANK 失效
公开(公告)号：JPS60152860A
公开(公告)日：1985-08-12
申请号：JP781484
申请日：1984-01-19
申请人： MITSUBISHI YUKA FINE CHEM
发明人： TAKI KUNIYOSHI
IPC分类号： F24H9/00 , F24J2/46 , F28D20/00
摘要： PURPOSE:To improve the heat storaging property by a wall structure wherein resin foam is employed as a core material, on one side of which concrete, metal plate and the like are provided as a body, while on the other side of which a polymer cement layer with polymer cement mortar layer as a part thereof is provided. CONSTITUTION:The titled tank is equipped with walls consisting in cementing an outer body 11 composed of metal plate, concrete and the like, resin foam heat insulator 13, hardened substance of polymer cement composition 16 and hardened substance of polymer cement mortar composition 17 in the order named in the direction of wall thickness from the outside to the inside of the tank. In this case, the polymer cement composition 16 consists of aqueous resin emulsion, the film-forming temperature of which is below 10 deg.C, and hydraulic cement (80-400pts.wt. of which is blended to 100pts.wt. of the solid content of resin in said emulsion). The polymer cement mortar composition 17 consists of aqueous resin emulsion, the film-forming temperature of which is below 10 deg.C, and hydraulic cement (200-600pts.wt. of which is blended to 100pts.wt. of the solid content of resin in said emulsion). Furthermore, 100-300pts.wt. of fine aggregate is blended to 100pts.wt. of said hydraulic cement.

42. 发明专利

JPS6011438A PRODUCTION OF ETHYLENE GLYCOL DIALKYL ETHER 失效
公开(公告)号：JPS6011438A
公开(公告)日：1985-01-21
申请号：JP11801983
申请日：1983-06-29
申请人： MITSUBISHI PETROCHEMICAL CO , MITSUBISHI YUKA FINE CHEM
发明人： AOKI TADAMICHI , AYUSAWA TADASHI , NOMURA YUTAKA
IPC分类号： C07C41/01 , B01J23/00 , C07B61/00 , C07C41/00 , C07C41/06 , C07C43/10 , C07C67/00
摘要： PURPOSE:To provide the titled compound useful as various solvents, etc., easily in high yield, by the catalytic reaction of an ethylene glycol monoalkyl ether with a compound containing carbonyl group in the presence of hydrogen using a palladium catalyst containing carbon black as the carrier. CONSTITUTION:The objective compound is obtained by reacting an ethylene glycol monoalkyl ether (e.g. ethylene glycol monomethyl ether) with a carbonyl- containing compound (e.g. acetone) in the presence of hydrogen and a catalyst obtained by supporting a palladium compound such as palladium chloride, palladium nitrate, palladium hydroxide, etc. to a carbon black carrier such as furnace black, acetylene black, thermally cracked carbon, channel carbon, etc. The alkyl group of the objective compound can be changed easily by selecting the kind of the raw material.

43. 发明专利

JPS59210057A Purification of dibromodicyanobutane 失效
标题翻译：双酚A基因的纯化
公开(公告)号：JPS59210057A
公开(公告)日：1984-11-28
申请号：JP8292483
申请日：1983-05-12
申请人： Mitsubishi Yuka Fine Chem Co Ltd
发明人： OOMORI HIROYUKI , HIGAKI YOSHIKAZU
IPC分类号： C07C255/10 , C07C67/00 , C07C253/00 , C07C253/34
CPC分类号： C07C255/00
摘要： PURPOSE: To prevent the discoloration of dibromodicyanobutane, emission of stimulant odor, corrosion of the apparatus, and the agglomeration of the product, by washing dibromodicyanobutane with water and then with a specific aqueous solution of an inorganic salt.
CONSTITUTION: A dibromodicyanobutane (e.g. 1,2-dibromo-2,4-dicyanobutane) can be purified by washing with an aqueous solution of a compound containing alkali metal, alkaline earth metal or ammonium ion as the cationic component and an oxygen-containing anion (e.g. nitrate radical, sulfate radical, etc.) as the anionic component at 0W70°C, preferably 10W40°C. The concentration of the solution is 0.01W50wt%, preferably 0.1W5wt%.
USE: Useful as a synthetic intermediate of agricultural chemicals and pharmaceuticals. Especially, 1,2-dibromo-2,4-dicyanobutane is useful as an antiseptic and a mildewproofing agent.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：目的：通过用水洗涤二溴二氰基丁烷，然后用特定的无机盐水溶液，防止二溴二氰基丁烷的变色，排放刺激性气味，设备腐蚀和产物的聚集。构成：可以用含有碱金属，碱土金属或铵离子的化合物的水溶液作为阳离子成分和含氧负离子来洗涤二溴二氰基丁烷（例如1,2-二溴-2,4-二氰基丁烷）（例如硝酸根，硫酸根等）作为阴离子组分，在0-70℃，优选10-40℃。溶液的浓度为0.01-50重量％，优选0.1-5重量％。用途：作为农药和药物的合成中间体有用。特别地，1,2-二溴-2,4-二氰基丁烷可用作防腐剂和防霉剂。

44. 发明专利

JPS59205167A Solvent for lithium secondary battery 失效
标题翻译：用于锂二次电池的溶剂
公开(公告)号：JPS59205167A
公开(公告)日：1984-11-20
申请号：JP7916083
申请日：1983-05-06
申请人： Mitsubishi Petrochem Co Ltd , Mitsubishi Yuka Fine Chem Co Ltd
发明人： MATSUDA YOSHIHARU , MORITA MASAYUKI , AOKI TADAMICHI , AYUSAWA TADASHI
IPC分类号： H01M4/36 , H01M10/05 , H01M10/052 , H01M10/0569 , H01M10/40
CPC分类号： H01M10/05 , H01M4/36
摘要： PURPOSE:To improve the charge-and-discharge property by using a mixture of ethylene glycol dialkyl ether having asymmetric construction and a specific organic solvent. CONSTITUTION:The present invention can be expressed by a general formula ( I ) R1-O-CH2-CH2-O-R2... ( I ) (provided that R1 and R2 are respectivey alkyl radicals having different constructions) and when using a mixture of ethylene glycol dialkyl ether having asymmetric construction and either of propylene carbonate, ethylene carbonate, gamma-butyrolactone, tetrahydrofuran, 1,3-diolasorane, 2-methyl tetrahydrofuran and sulforan, the polarization of the negative pole of a lithium secondary battery can be remarkably reduced. A metal compound or the like such as niobium, molybdenum and tantalum can be used as a positive active material in addition to MnO2, (CF)n, TiS2, TiO2, V2O5 and WS2. Further, electrolyte salt containing Li such as LiClO4, LiBF4, LiPF6 and LiAsF6 can be used as inorganic electrolyte salt while being combined with the solvent of the present invention.
摘要翻译：目的：通过使用具有不对称结构的乙二醇二烷基醚和特定有机溶剂的混合物来提高充放电性能。构成：本发明可以由通式（I）R 1 -O-CH 2 -CH 2 -O-R 2 ...（I）表示（条件是R 1和R 2各自为具有不同结构的烷基），并且当使用具有不对称结构的乙二醇二烷基醚与碳酸亚丙酯，碳酸亚乙酯，γ-丁内酯，四氢呋喃，1,3-二醇，甲苯，2-甲基四氢呋喃，和磺胺四醇的混合物，锂二次电池负极的极化可以是明显减少除了MnO 2，（CF）n，TiS 2，TiO 2，V 2 O 5和WS 2之外，可以使用铌，钼和钽等金属化合物等作为正极活性物质。此外，与LiClO 4，LiBF 4，LiPF 6和LiAsF 6等Li的电解质盐同时与本发明的溶剂组合可以作为无机电解质盐使用。

45. 发明专利

JPS59205161A Solvent for organic solvent battery 失效
标题翻译：有机溶剂电池溶剂
公开(公告)号：JPS59205161A
公开(公告)日：1984-11-20
申请号：JP7916183
申请日：1983-05-06
申请人： Mitsubishi Petrochem Co Ltd , Mitsubishi Yuka Fine Chem Co Ltd
发明人： MATSUDA YOSHIHARU , MORITA MASAYUKI , AOKI TADAMICHI , AYUSAWA TADASHI
IPC分类号： H01M6/16
CPC分类号： H01M6/164
摘要： PURPOSE:To improve the low temperature discharge property while lowering polarization of a negative pole by using a mixed solvent containing more than one kind of ethylene glycol dialkyl ether having a specific construction. CONSTITUTION:In an organic solvent battery making a light metal like lithium or the like to be a positive pole active material while using a nonaqueous organic solvent, the polarization of the negative pole of the battery can be remarkably reduced by using a mixed solvent, which can be expressed by a general formula ( I ), R1-O-CH2-CH2-CH2-O-R2...( I ) (provided that R1 and R2 are respectively alkyl radicals having no same construction) while containing at least one kind of ethylene glycol dialkyl ether [electrolyte (A)] having an asymmetrical construction. The desirable construction of said R1 and R2 is that in which the total carbon number is 3-8 while most desirably 3-5. Those having the total carbon number exceeding 8 can be also used while not being desirable due to high viscosity as the solvent. Inorganic electrolyte salt able to be used in combination with the solvent of this invention is that containing Li such as LiClO4, LiBF4, LiPF6 and LiAsF6, for instance, in the case of the negative pole of Li.
摘要翻译：目的：通过使用含有一种具有特定结构的乙二醇二烷基醚的混合溶剂，来提高低温放电性，同时降低负极的极化。构成：在使用非水有机溶剂的情况下，在使锂等轻金属成为正极活性物质的有机溶剂电池中，通过使用混合溶剂可以显着降低电池负极的极化，可以由通式（I），R 1 -O-CH 2 -CH 2 -CH 2 -O-R 2 ...（I）表示（条件是R1和R2分别是不同结构的烷基），同时含有至少一个具有不对称结构的乙二醇二烷基醚[电解质（A）]的种类。所述R1和R2的理想结构是其中总碳数为3-8，最优选为3-5。总碳数超过8的那些也可以使用，因为作为溶剂的高粘度而不是期望的。能够与本发明的溶剂组合使用的无机电解质盐例如在Li的负极的情况下含有Li，例如LiClO 4，LiBF 4，LiPF 6和LiAsF 6。

46. 发明专利

JPS62151473A OIL-MODIFIED ALKYD RESIN COATING COMPOSITION 失效
公开(公告)号：JPS62151473A
公开(公告)日：1987-07-06
申请号：JP29649685
申请日：1985-12-25
申请人： MITSUBISHI YUKA FINE CHEM
发明人： NISHIHARA YASUTAKA , KITANI YASUO , YOSHIDA YUJI
IPC分类号： C09D4/02 , C09D171/00
摘要： PURPOSE:The titled composition that is obtained by adding a plasticizer such as diburyl phthalate and a curing catalyst to an oil-modified alkyd and a specific acrylic polymerizable monomers, thus being a nonsolvent type coating composition which gives coating films with weathering resistance and high adhesion to metal and good gloss. CONSTITUTION:The objective composition is composed of (A) 100pts.wt. of an oil-modified alkyd, (B) 50-200pts.wt. of liquid acrylic polymerizable monomers which solubilize the component A and are liquid at 20 deg.C, (C) 10-50 pts.wt. per 100pts.wt. of components A and B in total, of a plasticizer, such as liquid chlorinated paraffin, dibutyl phthalate, dioctyl phthalate, dioctyl sebacate or octyl diphenyl phosphate and (D) an appropriate amount of a curing catalyst.

47. 发明专利

JPS6255021A PRODUCTION OF REGENERATED WOOD FOR CULTURING EDIBLE MUSHROOM 失效
公开(公告)号：JPS6255021A
公开(公告)日：1987-03-10
申请号：JP10302686
申请日：1986-05-07
申请人： SANYO WOOD PRESERVING , MITSUBISHI YUKA FINE CHEM , MORI SANGYO KK
发明人： KITADA MASAJI , FURUYA KOJI , YAMAMOTO KAZUNORI , SHIMIZU YUTAKA , NAGANO TADAHIRO , KODERA MANABU , SUGIMOTO YOSHIMASA
IPC分类号： A01G1/04

48. 发明专利

JPS6254253A FORMATION OF RELIEF 失效
公开(公告)号：JPS6254253A
公开(公告)日：1987-03-09
申请号：JP16851685
申请日：1985-08-01
申请人： SANYO KOKUSAKU PULP CO , MITSUBISHI YUKA FINE CHEM
发明人： TANI HIDEKI , HAYAMA KAZUHIDE , YAMASHITA AKIRA
IPC分类号： G03F1/00 , G03F1/40 , G03F1/88 , G03F7/26
摘要： PURPOSE:To easily, accurately and expensively form a relief by coating a water soluble photosensitive resin of a radiation curing type on a base material, then making recording with water ink, irradiating radiation thereto to cure said resin and developing the record with water or alkaline water. CONSTITUTION:The photosensitive resin of the radiation curing type consisting of the water soluble resin alone consisting of the deriv. of the radiation curing type obtd. from a natural resin such as casein, gelatin, starch or cellulose or essentially consisting of a mixture composed of said water soluble natural resin of the radiation curing type and

49. 发明专利

JPS6252158A HYDRAULIC CEMENT COMPOSITION AND MANUFACTURE OF CEMENT MOLDINGS 失效
公开(公告)号：JPS6252158A
公开(公告)日：1987-03-06
申请号：JP19340585
申请日：1985-09-02
申请人： MITSUBISHI YUKA FINE CHEM , UMEZAWA NORIHIRO
发明人： ISHII TERUHIKO , HATA KAZUYUKI
IPC分类号： C04B28/02 , C04B22/06 , C04B22/08 , C04B22/14 , C04B24/22 , C04B24/30

50. 发明专利

JPS6230135A STABILIZER FOR SYNTHETIC RESIN 失效
公开(公告)号：JPS6230135A
公开(公告)日：1987-02-09
申请号：JP16910385
申请日：1985-07-31
申请人： MITSUBISHI YUKA FINE CHEM , MITSUBISHI PETROCHEMICAL CO
发明人： IIDA KAZUYUKI , OMORI HIROYUKI , ONISHI AKIYOSHI , TAKAHASHI MASAMI
IPC分类号： C08L23/12 , C08K5/00 , C08K5/34 , C08K5/3432 , C08K5/3462 , C08K5/35 , C08K5/45 , C08K5/53 , C08L1/00 , C08L23/00 , C08L27/00 , C08L101/00
摘要： PURPOSE:A stabilizer for synthetic resins, consisting of a specific piperazine derivative and capable of remarkably improving not only heat aging resistance but also weather resistance by incorporation thereof together with various phenolic antioxidants in synthetic resins. CONSTITUTION:A stabilizer for synthetic resins consisting of a piperazine derivative expressed by formula I[R and R' and H or 1-6C alkyl; X is formula II, formula III, etc. (R1 and R2 are 1-18C alkyl, cycloalkyl, aryl, etc.; B is oxygen, sulfur atom, etc.); A is oxygen, sulfur or nitrogen atom; Z is formula IV, formula V, etc.; n and m are 0-4; l is 1-4]. 0.05-1pts.wt., preferably 0.08-0.5pts.wt. above-mentioned stabilizer, together with a phenolic antioxidant, is incorporated in 100pts.wt. synthetic resin. Preferably, a phosphite based compound, light stabilizer, etc., can be incorporated to further improve the heat and weather resistance.

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