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1. 发明专利

JPS61137873A Production of n,n-pentamethylenethiolcarbamic acid alkali metal salt 失效
标题翻译：生产N，N-戊酸乙酯酸性碱金属盐
公开(公告)号：JPS61137873A
公开(公告)日：1986-06-25
申请号：JP25931184
申请日：1984-12-10
申请人： Mitsubishi Petrochem Co Ltd
发明人： AYUSAWA TADASHI , IWANE HIROSHI , KUJIRA KATSUFUMI , KAWAHARA TAKAYUKI , TSUKAMOTO SEIICHI
IPC分类号： C07D295/02 , C07D295/20
摘要： PURPOSE: To obtain an aqueous layer containing the titled substance, by reacting an alkali metal hydroxide to an organic solvent solution of an N,N- pentamethylenethiolcarbamic acid piperidinium salt in the presence of water, and distilling the aqueous layer to recover the by-produced piperidine.
CONSTITUTION: An alkali metal hydroxide is added to a solution of an N,N- pentamethylenethiolcarbamic acid piperidinium salt in an organic solvent (e.g. hydrophobic aromatic hydrocarbon, aliphatic hydrocarbon, ether, etc.) at a molar ratio of 1:(1W1.5), and reacted with each other to obtain the titledsubstance. The aqueous layer is distilled to recover the fraction containing by produced piperidine, and the aqueous layer containing the titled substance (the compound of formula) is obtained as the distillation residue. The distillation is carried out at the column bottom temperature of ≤70°C under reduced pressure. The concentration of the alkali metal salt in the aqueous layer containing the titled substance is 40W50wt%.
USE: Used as synthetic intermediate of herbicide.
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：目的：为了获得含有标题物质的含水层，在水存在下，通过碱金属氢氧化物与N，N-五亚甲基硫代氨基甲酸哌啶鎓盐的有机溶剂溶液反应，蒸馏除去副产物哌啶。构成：将碱金属氢氧化物以1：（1-1.5）的摩尔比加入到N，N-五亚甲基硫代氨基哌啶鎓盐的有机溶剂（例如疏水性芳族烃，脂族烃，醚等）的溶液中），并进行反应，得到标题物质。蒸馏水层以回收由产生的哌啶含有的级分，得到含有标题物质（式的化合物）的水层作为蒸馏残渣。蒸馏在塔底温度<70℃，减压下进行。含有标题物质的水层中的碱金属盐的浓度为40〜50重量％。用途：用作除草剂的合成中间体。

2. 发明专利

JPS61134380A Production of piperidine 失效
标题翻译：哌啶的生产
公开(公告)号：JPS61134380A
公开(公告)日：1986-06-21
申请号：JP25526984
申请日：1984-12-03
申请人： Mitsubishi Petrochem Co Ltd
发明人： MORI SHOICHIRO , HAMANA RYOZO , NOMURA YUTAKA
IPC分类号： C07D295/02 , B01J23/00 , B01J23/46 , C07B61/00
CPC分类号： Y02P20/52
摘要： PURPOSE: To produce efficiently piperidine useful as a raw material for drugs, agricultural chemicals, or rubber chemicals, etc., by hydrogenating catalytically tetrahydrofurfurylamine by the use of a ruthenium group catalyst.
CONSTITUTION: Tetrahydrofurfurylamine is catalytically hydrogenated by the use of a ruthenium group catalyst in the form of ruthenium metal, ruthenium oxide, etc. or in the form of these ruthenium components supported on a carrier (e.g., alumina, etc.) in a solvent preferably n-hexane, benzene, tertiary butyl alcohol etc. at 160W250°C at about 3W60atom hydrogen partial pressure, to produce piperidine. An amount of the catalyst used is preferably 0.01W0.3pt.wt. based on the raw material. In the reaction system, a small amount of ammonia may be present in order to improve selectivity of the aimed reaction product.
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：目的：通过使用钌基催化剂氢化催化四氢糠胺，生产有效的用作药物，农药或橡胶化学品等的原料的哌啶。构成：四氢糠胺通过使用钌金属，氧化钌等形式的钌基催化剂催化氢化，或以这些钌组分的形式在载体（例如氧化铝等）中在溶剂中的溶剂优选正己烷，苯，叔丁醇等，在约160〜250℃，约3-60原子氢分压下，生成哌啶。所使用的催化剂的量优选为0.01-0.3pt.wt。基于原料。在反应体系中，为了提高目标反应产物的选择性，可能存在少量的氨。

3. 发明专利

JPS61134356A Production of m-aminoacetophenone 失效
标题翻译：生产M-氨基丙酸乙酯
公开(公告)号：JPS61134356A
公开(公告)日：1986-06-21
申请号：JP25724784
申请日：1984-12-05
申请人： Mitsubishi Petrochem Co Ltd , Mitsubishi Yuka Fine Chem Co Ltd
发明人： AOKI TADAMICHI , SEO SHOICHI
IPC分类号： C07B61/00 , B01J23/00 , B01J23/02 , B01J23/40 , B01J27/20 , C07C67/00 , C07C213/00 , C07C225/22
CPC分类号： Y02P20/52
摘要： PURPOSE: m-Nitroacetophenone is hydrogenated in the presence of a catalyst and additives to enable high-selectivity and high-yield production of a compound which is used as a starting material for medicines and agricultural chemicals with inhibition of carbonyl hydrogenation.
CONSTITUTION: The hydrogenation of m-nitroacetophenone is carried out in the presence of a catalyst of a metal in the platinum group such as palladium and an additive, at least one selected from alkali metal hydroxide, alkaline earth metal hydroxide, alkali metal carbonate and alkali metal bicarbonate such as sodium hydroxide at room temperature up to 150°C and normal pressure to 20kg/cm
2 , preferably at room temperature to 100°C and normal pressure to 10kg/cm
2 G to give the objective compound.
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：目的：将间 - 硝基苯乙酮在催化剂和添加剂存在下氢化，使高选择性和高产率的化合物被用作具有抑制羰基氢化作用的药物和农用化学原料。构成：间硝基苯乙酮的氢化在铂族金属的催化剂如钯和添加剂的存在下进行，选自碱金属氢氧化物，碱土金属氢氧化物，碱金属碳酸盐和碱中的至少一种金属碳酸氢盐如氢氧化钠，室温至150℃，常压至20kg / cm 2，优选室温至100℃，常压至10kg / cm 2，得到目的复合。

4. 发明专利

JPS61130836A Piezo-electric sensor 失效
标题翻译： PIEZO-ELECTRIC传感器
公开(公告)号：JPS61130836A
公开(公告)日：1986-06-18
申请号：JP25429184
申请日：1984-11-30
申请人： Mitsubishi Petrochem Co Ltd
发明人： IKEDA SHOICHI
IPC分类号： G01L1/16 , G01P15/09 , H01L41/00 , H01L41/113
CPC分类号： H01L41/1132
摘要： PURPOSE:To eliminate effect of noises due to pyroelectric phenomenon, by providing positive and negative electrodes on one surface of a piezo-electric body in the same area while a neutral electrode on the other surface thereof. CONSTITUTION:Positive and negative electrodes 2 and 3 are provided on the one surface of a piezo-electric body 1 in the same area while a neutral electrode 4 on the other surface thereof 1. This can eliminates effect of noises due to pyroelectric phenomenon. In other words, electric charge proportinal to the ambient temperature is generated in the positive and negative electrodes 2 and 3. But since, both the electrodes 2 and 3 are located on the same polarization surface while they are the same in the area, output voltages generated in the both the electrodes 2 and 3 due to pyroelectric phenomenon are equal and will not change being cancelled. This can elimiates effect of noises due to pyroelectric phenomenon.
摘要翻译：目的：为了消除由于热电现象引起的噪声的影响，通过在同一区域的压电体的一个表面上设置正极和负极，而在另一个表面上设置中性电极。构成：在同一区域中的压电体1的一个表面上设置正极和负极2和3，而在另一个表面上的中性电极4设置有负电极2和3。这可以消除由于热电现象引起的噪声的影响。换句话说，在正极和负极2和3中产生与环境温度成比例的电荷。但是由于电极2和3两者位于相同的偏振面上，而是在该区域中相同，所以输出电压由于热电现象在电极2和3两者中产生的相等并且不会改变被取消。这可以消除由于热电现象引起的噪声的影响。

5. 发明专利

JPS61123518A Manufacture of dielectric film 失效
标题翻译：电介质薄膜的制造
公开(公告)号：JPS61123518A
公开(公告)日：1986-06-11
申请号：JP24581284
申请日：1984-11-20
申请人： Mitsubishi Petrochem Co Ltd
发明人： HOSONO TAIJI , OKUYAMA KATSUMI , ITO MINORU , MIZUTANI HIROYASU
IPC分类号： B32B7/02 , B29C55/02 , B29K105/16 , B29L9/00 , H01B17/60 , H01B19/00
摘要： PURPOSE: To obtain the title item that is excellent in electrical properties such as dielectric strength and dielectric property and has less voids, by layering a thermoplastic filmy material to firmly adhere to the surface of a thermoplastic filmy material containing a dispersed dielectric fine particles, and stretching them at a specified temperature.
CONSTITUTION: First, a filmy material of a thermoplastic resin (B) is layered to firmly adhere on the surface of a filmy material of a plastic resin containing preferably 10W75wt% of a dispersed dielectric fine powder (A) such as barium titanate or the like for example by heating and melting them in separate extruders, and laminating them in a co-extruding die to be extruded. then, the obtained laminate is stretched at a temperature where the resin (A) becomes the melted state, that is at or lower than the melting temperature of the resin (B) and/or at or higher than the glass transition temperature of the resin and where the resin (B) can be stretched so that the disired item is obtained.
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：目的：为了获得绝缘强度和介电性能等电学性能优异，空隙小的标题，通过将热塑性薄膜材料层叠以牢固地附着到含有分散的电介质微粒的热塑性薄膜材料的表面，以及在指定的温度下拉伸它们。构成：首先，将热塑性树脂（B）的薄膜材料分层以牢固地粘附在塑料树脂的膜状材料的表面上，所述塑料树脂优选含有10-75wt％的分散的电介质细粉末（A）如钛酸钡或例如通过在单独的挤出机中加热和熔融它们，并将它们层压在共挤出模具中以进行挤出。然后，将所得到的层压体在树脂（A）成为熔融状态的温度下拉伸，即等于或低于树脂（B）的熔融温度和/或等于或高于树脂的玻璃化转变温度并且可以拉伸树脂（B），从而获得不需要的物品。

6. 发明专利

JPS61106554A Production of n-arylimide 失效
标题翻译： N-亚胺酰胺的生产
公开(公告)号：JPS61106554A
公开(公告)日：1986-05-24
申请号：JP22726984
申请日：1984-10-29
申请人： Mitsubishi Petrochem Co Ltd
发明人： KANAYAMA KAORU , ONUMA YOSHINOBU
IPC分类号： C07D207/448 , C07D207/452 , C07D209/48 , C07D209/76
摘要： PURPOSE: In the reaction between an unsaturated dicarboxylic acid anhydride and an aromatic monoamine, a mixed solvent of aromatic hydrocarbon and aprotonic polar solvent is used and, after the reaction, the product is dehydratively cyclized in the presence of a catalyst to give the titled substance of high purity.
CONSTITUTION: A mixed solvent consisting of 50W98wt% of an aromatic hydrocarbon solvent and 50W2wt%, preferably 2W30wt% of an aprotonic polar solvent is used to effect the reaction between an unsaturated dicarboxylic anhydride of formula I (D is divalent organic group bearing a carbon-carbon double bond) and an aromatic monoamine of formula II (X
1 is H, halogen, alkyl, alkoxy, nitro, hydroxyl; X
2 is H, halogen, alkyl) whereby an N-arylamidic acid is obtained. Then, without isolation of the product, the dehydrative cyclization is effected in the presence of an acid catalyst at 60W170°C to give a compound of formula III. The amount of the compound of formula I used in the reaction is preferably 1.0W1.3mol per mol of the compound of formula II.
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：目的：在不饱和二羧酸酐与芳香族单胺的反应中，使用芳香族烃和非质子极性溶剂的混合溶剂，反应后，在催化剂存在下使产物脱水环化，得到标题物质的高纯度。组成：使用由50-98wt％的芳族烃溶剂和50-2wt％，优选2-30wt％的非质子极性溶剂组成的混合溶剂来实现式I的不饱和二羧酸酐（D是二价的带有碳 - 碳双键的有机基团）和式II的芳族单胺（X1是H，卤素，烷基，烷氧基，硝基，羟基; X2是H，卤素，烷基），由此得到N-芳基酰胺酸。然后，不分离产物，脱水环化在酸催化剂存在下在60-170℃下进行，得到式III化合物。在反应中使用的式I化合物的量优选为每摩尔式II化合物1.0-1.3摩尔。

7. 发明专利

JPS61101505A Dehydrohalogenation of halogen-containing polymer 失效
标题翻译：含氢聚合物的脱氢脱氢酶
公开(公告)号：JPS61101505A
公开(公告)日：1986-05-20
申请号：JP22378884
申请日：1984-10-24
申请人： Mitsubishi Petrochem Co Ltd
发明人： KISE HIDEO , UNO YASUMITSU
IPC分类号： C08F8/00 , C08F8/26
摘要： PURPOSE: To obtain a porous substance of a porous polyacetylene structure, by dehydrohalogenating a halogen-containing polymer by immersing a solution of the polymer and a phase transfer catalyst component in an alkali solution.
CONSTITUTION: A halogen-containing polymer (e.g., polyvinyl halide or polyvinylidene halide polymer) and a phase transfer catalyst (e.g., tetrabutylammonium bromide or chloride) are dissolved in an organic solvent comprising a mixture of tetrahydrofuran, dioxane, etc. The concentration of the halogen-containing polymer is generally 1W50wt%, preferably, 3W30wt% and the amount of the phase transfer catalyst compound used is preferably 0.01W0.02g equivalent, based on the hydrogen halide. This polymer solution is immersed in an alkali solution to dehydrohalogenate the polymer.
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：目的：为了获得多孔聚乙炔结构的多孔物质，通过将聚合物和相转移催化剂组分的溶液浸入碱溶液中，使含卤聚合物脱卤化氢。构成：将含卤聚合物（例如，聚卤乙烯或聚偏二氯乙烯聚合物）和相转移催化剂（例如四丁基溴化铵或氯化物）溶解在包含四氢呋喃，二恶烷等的混合物的有机溶剂中。含卤聚合物通常为1-50重量％，优选3-30重量％，相对于所述卤化氢，相转移催化剂化合物的使用量优选为0.01-0.02g当量。将该聚合物溶液浸入碱溶液中以使聚合物脱卤化氢。

8. 发明专利

JPS6192454A Optical recording method 失效
标题翻译：光学记录方法
公开(公告)号：JPS6192454A
公开(公告)日：1986-05-10
申请号：JP21302584
申请日：1984-10-11
申请人： Mitsubishi Petrochem Co Ltd
发明人： ICHIHARA YOSHIJI , URATANI YASUYO
IPC分类号： B41M5/26 , G11B7/004 , G11B7/24 , G11B7/241 , G11B7/244 , G11B9/00 , G11B9/02 , G11B11/00 , G11B13/00
CPC分类号： G11B13/00 , G11B7/004 , G11B7/241
摘要： PURPOSE:To attain high-density recording by forming optical isotropy to a recording medium in the reading direction, applying an electric field to the recording part in a direction with a tile angle in the read direction, irradiating the light for heating the medium thereby decreasing a recording unit area. CONSTITUTION:An organic amorphous compound is used as the recording medium, where an anisotropy is caused in the refractive index by applying an electric field to orient a dipole and the orientation relax temperature of the radial causing the dipole is >=40 deg.C. In recording, electrodes 2a, 2b are provided in a direction having a tile angle theta to the read direction L of the recording medium L, an electric field is applied to a direction with a tilt in the reading direction and a ray T is irradiated. In reading the recording, orthogonal polarizers 3a, 3b are placed at both sides of the recording medium 1, and the ray L is received by an analyzer 4 through the polarizer 3a, the recording medium and the polarizer 3b. In erasing the recording, the entire recording medium 1 is heated to the orientation relax temperature of the polar radical or the orientation is relaxed by irradiating the light on the erased part only.
摘要翻译：目的：为了通过在读取方向上向记录介质形成光学各向同性来获得高密度记录，在读取方向上沿着具有瓦片角度的方向向记录部分施加电场，照射用于加热介质的光，从而减少记录单位区域。构成：使用有机非晶化合物作为记录介质，其中通过施加电场来定向偶极子并导致偶极子的径向取向松弛温度，折射率引起各向异性> 40℃。在记录中，电极2a，2b设置在与记录介质L的读取方向L相对应的瓦片角度θ的方向上，并且向沿着读取方向倾斜的方向施加电场并照射光线T. 在读取记录时，将正交偏振器3a，3b放置在记录介质1的两侧，并且通过偏振器3a，记录介质和偏振器3b由分析器4接收光线L. 在擦除记录时，将整个记录介质1加热到极性自由基的取向松弛温度，或者通过仅将光照射在被擦除部分上来放宽取向。

9. 发明专利

JPS6191138A Preparation of co-dimer of ethylene with styrene 失效
标题翻译：乙烯与苯乙烯的共聚物的制备
公开(公告)号：JPS6191138A
公开(公告)日：1986-05-09
申请号：JP21112684
申请日：1984-10-08
申请人： Mitsubishi Petrochem Co Ltd , Mitsubishi Yuka Fine Chem Co Ltd
发明人： KITATSUME SHOJI , OTAKA SATOSHI
IPC分类号： C07C2/02 , B01J31/00 , B01J31/22 , B01J31/24 , B01J31/26 , C07B31/00 , C07B37/02 , C07B61/00 , C07C1/00 , C07C17/00 , C07C17/275 , C07C22/04 , C07C22/06 , C07C22/08 , C07C25/24 , C07C27/00 , C07C37/14 , C07C39/19 , C07C67/00 , C07C69/76 , C07F7/08
CPC分类号： Y02P20/52
摘要： PURPOSE: To co-dimerize ethylene with styrenes by using an easily available and handleable catalyst composed of combination of an Ni (0-valent) complex, phosphine compound or alkyl halide, etc. and a halide of boron or Al.
CONSTITUTION: In co-dimerization of ethylene with styrenes, a catalyst containing combination of (A) an Ni (0-valent) complex [example; bis(cyclooctadiene)nickel], (B) a compound expressed by the formula PR
1
3 (R
1 represents alkyl, cycloalkyl, aryl, etc.) (example; trimethylphosphine), (C) a compound expressed by the formula R
2 X (R
2 represents alkyl, aryl, cycloalkyl, etc.; X represents Cl, Br or I) (example; methyl bromide) and (D) a compound expressed by the formula AY (A represents boron or Al; Y is halogen atom) (example; BF
3 ) is used.
EFFECT: The above-mentioned catalyst assures production of the aimed compound in good yield with a small amount of use.
USE: A raw material for polymers.
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：目的：通过使用由Ni（0价）络合物，膦化合物或烷基卤化物等与硼或Al的卤化物组合而成的容易获得和可处理的催化剂，使乙烯与苯乙烯共二聚。构成：在乙烯与苯乙烯的共二聚反应中，含有（A）Ni（0价）络合物的组合物的催化剂[ 双（环辛二烯）镍]，（B）由式PR 3表示的化合物（R 1表示烷基，环烷基，芳基等）（实例;三甲基膦），（C）由式R 2 X（R 2表示烷基，芳基，环烷基等; X表示Cl，Br或I）（实例;甲基溴）和（D）由式AY表示的化合物（A表示硼或Al; Y是卤素原子）（实例; BF 3）。效果：上述催化剂以少量的用途保证了目标化合物以良好的产率生产。用途：聚合物原料。

10. 发明专利

JPS6189258A Production of electrically conductive resin composition 失效
标题翻译：电导电树脂组合物的生产
公开(公告)号：JPS6189258A
公开(公告)日：1986-05-07
申请号：JP21109784
申请日：1984-10-08
申请人： Mitsubishi Petrochem Co Ltd
发明人： OKAMURA MICHIYA , YUI HIROSHI
IPC分类号： C08K3/04 , C08K3/00 , C08K3/02 , C08L101/00 , C08L101/02
摘要： PURPOSE: To obtain the titled composition having excellent electrical conductivity and moldability, and suitable as the housing of electronic apparatus, etc., by compounding a specific amount of carbon black to a nonpolar thermoplastic resin, and compounding a specific amount of the resultant nonpolar thermoplastic resin composition to a polar thermoplastic resin.
CONSTITUTION: (A) 90W30pts.(wt.), preferably 60W40pts. of a polar thermoplastic resin having γcp of ≤1 (e.g. nylon 6) is compounded with (B) 10W70pts., preferably 40W60pts. of a carbon black composition prepared by kneading (B
1 ) 50W90% nonpolar thermoplastic resin having γcp of ≥2 (e.g. α-olefin) with (B
2 ) 50W10% electrically conductive carbon black having a specific surface area of ≥850m
2 /g measured by BET process, wherein γcp=(√γc-√γp)
2 (γc is surface tension of carbon black and γp is surface tension of resin). The sum of the components A and B is 100pts.
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：目的：通过将特定量的炭黑与非极性热塑性树脂混合，并将特定量的所得非极性热塑性树脂复合而获得具有优异的导电性和成型性的标题组合物，并且适合作为电子设备的壳体等树脂组合物成极性热塑性树脂。构成：（A）90-30pts（wt。），优选60-40pts。具有gammacp <= 1（例如尼龙6）的极性热塑性树脂与（B）10-70pts，优选40-60pts混合。通过捏合（B1）具有> = 2的gammacp> = 2（例如α-烯烃）的50-90％非极性热塑性树脂与（B2）50-10％比表面积> 50％的导电炭黑混合制备的炭黑组合物 850m 2 / g，其中gammacp =（sq。rt。gammac-sq.mL.gammap）2（gammac是炭黑和gammap的表面张力是树脂的表面张力）。组分A和B的总和为100pts。

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