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    • 31. 发明专利
    • SEMICONDUCTOR DEVICE
    • JPS57192073A
    • 1982-11-26
    • JP7656081
    • 1981-05-22
    • HITACHI LTD
    • SHIMIZU SHINJIMIYAZAWA HIROYUKIKASAHARA OSAMU
    • H01L21/768H01L21/28H01L29/43H01L29/45
    • PURPOSE:To perform easily the heat treatment of impurity diffusion, etc., at a semiconductor device wherein a wiring layer is coming in contact with a semiconductor substrate directly by a method wherein the wiring layer is formed in laminated structure of an amorphous semiconductor - a high melting point metal. CONSTITUTION:Field SiO2 films 2 are made to grow on the main face of a P type silicon substrate 1, and after an oxidation resistive mask is etched, thin gate oxide films 15 are made to grow, and an opening 16 is formed by etching. Then the amorphous silicon film 13 and the molybednum film 14 are adhered in succession using the same sputtering device. Then phosphorus is made to diffuse in the silicon crystal of the substrate 1 at the region of the opening 16 through the molybdenum film 14 and the amorphous silicon film 13 to form the N type region 4a. Moreover a gate electrode and wiring 7, 8 and openings are formed respectively by etching, and the N type regions 4, 5, 11 are formed as the source or drain regions by the ion implantation method.
    • 37. 发明专利
    • FORMATION OF CAPACITIVE INSULATING FILM
    • JPH06140572A
    • 1994-05-20
    • JP29098392
    • 1992-10-29
    • HITACHI LTD
    • KASAHARA OSAMUSAKUMA HIROSHITSUCHIYA OSAMUSUGIURA JUN
    • H01L21/205H01L21/318H01L21/822H01L21/8242H01L27/04H01L27/10H01L27/108
    • PURPOSE:To provide a silicon nitride film having a film thickness with sufficient charge storage capacity, by changing a gas to an SiH3Cl2 gas halfway after an NH3 gas is supplied at first under lowering pressure in an initial kernel forming process, and also changing the gas halfway to the SiH3Cl2 gas after the NH3 gas is supplied under given pressure in a film growth process. CONSTITUTION:A growing process of a natural oxide film 11 over a lower electrode 2 is controlled by using a CVD system with a load lock mechanism so that a natural oxide film 11 can be made thin. In addition, an initial kernel forming process and a film growth process are carried out, in which a silicon nitride film 10 and a silicon nitride oxide film 11 obtained by oxidizing the silicon nitride film 10 are formed with their film thicknesses enough to hold a sufficient charge storage capacity. Then, a capacitive insulating film 1 thicker than a conventional one can be obtained. In this initial kernel forming process, the silicon nitride film 10 is grown on the silicon oxide at a rate nearly equal to that of the growth on the silicon. Consequently, a silicon nitride film 10 with sufficient film thickness, along with good acid-proof characteristics, can be obtained even on the silicon nitride film.
    • 40. 发明专利
    • METHOD AND APPARATUS FOR MANUFACTURE OF SEMICONDUCTOR INTEGRATED CIRCUIT DEVICE
    • JPH02277231A
    • 1990-11-13
    • JP9854889
    • 1989-04-18
    • HITACHI LTD
    • OWADA NOBUOKASAHARA OSAMU
    • H01L21/285H01L21/28
    • PURPOSE:To prevent reliability of a connection hole from being lowered due to an abnormal growth of a tungsten (W) film by a method wherein film-formation parameters such as a flow rate of a reaction gas, a substrate temperature and the like are changed with the passage of time and the W film is grown intermittently. CONSTITUTION:A substrate 1 is housed in a low-pressure CVD apparatus 20 in order to fill a W film into the inside of a contact hole; the semiconductor substrate 1 is arranged and supported, in a state that a formation face of an integrated circuit is faced downward, on the bottom face of a hot chuck 23 installed in the center at the upper part of a chamber 21. A heating source 26 directly heats the rear of the substrate 1; its output is changed by using an output control means 27 at a desired cycle//; a reaction-gas supply source which has been filled with WF6 gas and silane gas is connected to one end of a reaction-gas introduction port 28 at the bottom part of the chamber 21; a flow rate of the reaction gases and their mixture ratio are changed by using a flow-rate control means 31 at a desired cycle. Thereby, it is possible to effectively prevent crystal particles from becoming coarse and large by an abnormal growth operation of the W film; it is possible to enhance reliability of a connection hole.