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    • 22. 发明专利
    • Method for recovering valuable metal
    • 恢复有价值金属的方法
    • JP2012224876A
    • 2012-11-15
    • JP2011090724
    • 2011-04-15
    • Sumitomo Metal Mining Co Ltd住友金属鉱山株式会社
    • TAKAHASHI JUNICHIMORI KAZUHIRO
    • C22B7/00C22B9/10C22B23/02H01M10/54
    • H01M10/54C21B3/02C21B11/10C22B1/02C22B7/001C22B7/006C22B15/0039C22B15/0056C22B21/0084C22B23/02C22B23/023Y02P10/214Y02P10/234Y02W30/54Y02W30/84
    • PROBLEM TO BE SOLVED: To provide a method that improves a recovery rate of valuable metals by reducing viscosity of slag when performing dry processing of a discarded battery, such as a lithium-ion battery.SOLUTION: The method for recovering valuable metals includes a dry step S20 including: a melting step ST21 of obtaining a molten material by melting a discarded battery containing aluminum and iron; a slag separation step ST22 of separating slag from the molten material; and an alloy separation step ST23 of separating an alloy of valuable metals from the molten material, wherein the slag has an aluminum oxide content of 5 mass% or higher but less than 20 mass% and an iron content in terms of metallic iron of 20-40 mass%. Furthermore, silicon oxide and calcium oxide are added as a flux in the melting step ST21 so that the slag has a melting point of 1,400°C or lower, and the melting step ST21 is conducted at 1,400°C or lower. Thus, since the slag has a reduced viscosity and hence is easy to separate from the alloy, the recovery rate of the alloy can be improved and also the operation at a low temperature of 1,400°C or lower becomes possible.
    • 要解决的问题:提供一种通过在对废弃电池例如锂离子电池进行干法处理时减少渣的粘度来提高有价金属的回收率的方法。 解决方案:回收贵重金属的方法包括:干步骤S20,包括:熔融步骤ST21,通过熔化含有铝和铁的废弃电池获得熔融材料; 将渣从熔融材料分离的渣分离步骤ST22; 以及从熔融材料中分离有价金属的合金的合金分离工序ST23,其中,所述炉渣的氧化铝含量为5质量%以上且小于20质量%,铁含量为20〜 40质量%。 此外,在熔融步骤ST21中,作为助熔剂添加氧化硅和氧化钙,使炉渣的熔点为1400℃以下,熔融步骤ST21在1400℃以下进行。 因此,由于渣具有降低的粘度,因此容易与合金分离,因此可以提高合金的回收率,并且可以在1400℃以下的低温下进行操作。 版权所有(C)2013,JPO&INPIT