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    • 13. 发明专利
    • Composite oxide and catalyst for purifying exhaust gas
    • 用于净化排气的复合氧化物和催化剂
    • JP2006137651A
    • 2006-06-01
    • JP2004330884
    • 2004-11-15
    • Toyota Central Res & Dev Lab IncToyota Motor Corpトヨタ自動車株式会社株式会社豊田中央研究所
    • MORIKAWA AKIRAYAMAMURA YOSHIESUDA AKIHIKOTANABE TOSHITAKATAKAHASHI NAOKIKANAZAWA TAKAAKI
    • C01G25/00B01D53/94B01J23/58B01J23/63B01J32/00B01J37/08F01N3/10
    • Y02C20/20
    • PROBLEM TO BE SOLVED: To provide a catalyst for purifying an exhaust gas where the stability and the easy reducibility of a rhodium oxide coexist by controlling solid basicity in a suitable range. SOLUTION: A composite oxide comprises at least one kind (a) of metal elements selected from an alkali metal, an alkaline earth metal, a rare earth element, a group 3 element and a group 4 element except Zr, and ZrO 2 . The CO 2 adsorbing amount per unit weight of the composite oxide after heat-treated in 3 hours or more at 1,000°C is 8.2-29 μmol/g and the CO 2 adsorbing amount per unit specific surface area of the complex oxide is 0.2-2.3 μmol/m 2 . As the stability and the easy reducibility of the rhodium oxide coexist by controlling the solid basicity in the suitable range, the purifying activity of the catalyst is high from a low temperature region and is kept high after exposed in a high temperature atmosphere and its durability is excellent. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供一种用于净化排气的催化剂,其中通过将固体碱度控制在适当的范围内,氧化铑的稳定性和易还原性共存。 解决方案:复合氧化物包括选自碱金属,碱土金属,稀土元素,第3族元素和除Zr以外的第4族元素的金属元素中的至少一种(a) SB> 2 。 在1,000℃下3小时以上热处理后的复合氧化物的每单位重量的CO 吸附量为8.2-29μmol/ g,CO 2 复合氧化物的单位比表面积的吸附量为0.2〜2.3μmol/ m 2。 由于通过将固体碱度控制在适当范围内,氧化铑的稳定性和易还原性共存,所以催化剂的净化活性从低温区域高,并且在高温气氛中暴露后保持高温,其耐久性为 优秀。 版权所有(C)2006,JPO&NCIPI
    • 19. 发明专利
    • Compound metal oxide porous body
    • 化合物金属氧化物多孔体
    • JP2007063057A
    • 2007-03-15
    • JP2005249879
    • 2005-08-30
    • Toyota Central Res & Dev Lab Inc株式会社豊田中央研究所
    • YAMAMOTO TOSHIOSUDA AKIHIKOMORIKAWA AKIRA
    • C01G25/00B01D53/94B01J23/63B01J35/10F01N3/10
    • PROBLEM TO BE SOLVED: To provide a compound metal oxide porous body having extremely excellent high temperature durability, keeping the specific surface area and cleaning performance at a high level even after a high-temperature durability test, and useful as a catalyst for purifying exhaust gas or the like. SOLUTION: The compound metal oxide porous body comprises metal oxide fine particles comprising primary particles having diameters of 50 nm or less and alumina fine particles comprising primary particles having diameters of 50 nm or less and at least one crystal phase selected from a group consisting of γ-phase, δ-phase, θ-phase and α-phase and is characterized in that the content of the metal oxide is 45 mass% or more and that the specific surface area after a durability test at 1,000°C for 5 hours is 40 m 2 /g or more. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:为了提供具有非常优异的耐高温性的复合金属氧化物多孔体,即使在高温耐久性试验后也将比表面积和清洁性能保持在高水平,并且可用作催化剂 净化废气等。 解决方案:复合金属氧化物多孔体包括包含直径为50nm以下的一次粒子的金属氧化物微粒和包含直径为50nm以下的一次粒子的氧化铝微粒和至少一种选自基团的晶相 由γ相,δ相,θ相和α相组成,其特征在于,金属氧化物的含量为45质量%以上,耐久性试验后的比表面积在1000℃下为5 小时为40米 2 / g以上。 版权所有(C)2007,JPO&INPIT
    • 20. 发明专利
    • Manufacturing method of porous composite metal oxide material
    • 多孔复合金属氧化物材料的制造方法
    • JP2007044585A
    • 2007-02-22
    • JP2005229319
    • 2005-08-08
    • Toyota Central Res & Dev Lab Inc株式会社豊田中央研究所
    • YAMAMOTO TOSHIOSUDA AKIHIKO
    • B01J37/04B01D53/94B01J23/63B01J32/00B01J37/08F01N3/10F01N3/28
    • PROBLEM TO BE SOLVED: To provide a method of obtaining efficiently a porous composite metal oxide material useful as a catalyst for purifying exhaust gas, or the like, which is extremely excellent in durability for high temperature, and in which even under high temperatures a specific surface area and purification capability are maintained in a high level. SOLUTION: The manufacturing method of the porous composite metal oxide material comprises a dispersion mixing process of dispersion-mixing a first metal oxide powder which is an agglomerate of primary particles having a diameter of 50 nm or less, and has an average particle diameter of 200 nm or less, and a second metal oxide powder which is an agglomerate of primary particles having a diameter of 50 nm or less, and has an average particle diameter of 200 nm or less, in a dispersion medium by using microbeads having a diameter of 150 μm or less, to obtain a uniform dispersion liquid of the first metal oxide powder with the second metal oxide powder, and a drying process of drying the uniform dispersion liquid to obtain the porous composite metal oxide material. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供一种有效地获得用作净化废气的催化剂的多孔复合金属氧化物等的方法,其耐高温性极其优异,并且甚至在高温下 温度比表面积和净化能力保持在高水平。 解决方案:多孔复合金属氧化物材料的制造方法包括将作为直径为50nm以下的一次粒子的附聚物的第一金属氧化物粉末分散混合并具有平均粒子的分散混合工序 直径为200nm以下的第二金属氧化物粉末和作为直径为50nm以下,平均粒径为200nm以下的一次粒子的附聚物的第二金属氧化物粉末,通过使用具有 直径为150μm以下,得到第一金属氧化物粉末与第二金属氧化物粉末的均匀分散液,干燥该均匀分散液的干燥工序,得到多孔复合金属氧化物材料。 版权所有(C)2007,JPO&INPIT