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1. 发明专利

JP2003313011A Method for producing metal oxide 审中-公开
标题翻译：生产金属氧化物的方法
公开(公告)号：JP2003313011A
公开(公告)日：2003-11-06
申请号：JP2002120941
申请日：2002-04-23
申请人： Toyota Central Res & Dev Lab Inc , Toyota Motor Corp , トヨタ自動車株式会社 , 株式会社豊田中央研究所
发明人： ISHIBASHI KAZUNOBU , ITO YUSUKE , SUDA AKIHIKO , SOFUGAWA HIDEO , TAKAHASHI NAOKI
IPC分类号： B01D53/94 , B01J23/42 , B01J23/63 , B01J37/08 , C01B13/18 , C01F7/30 , C01G25/00
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a metal oxide suitable for use as a catalyst carrier of a catalyst for cleaning of exhaust gas of an internal combustion engine and maintaining a large specific surface area with age and to provide a method for producing a multiple metal oxide having a widely selective composition and a large specific surface area. SOLUTION: In the method for producing a metal oxide, a solution prepared by dissolving at least one metal compound is impregnated into a porous material having pores and reducible to ashes, and after firing in a non-oxidizing atmosphere the porous material is burned and removed. Preferably the pores have 2-40 nm average pore diameter. When the multiple metal oxide is produced, preferably a solution prepared by dissolving at least two metal compounds is impregnated into the above porous material and the porous material is exposed to gaseous ammonia and fired in a non-oxidizing atmosphere. In the case where the metal compound is an aluminum compound, α-alumina is produced. COPYRIGHT: (C)2004,JPO
摘要翻译：解决问题的方法：提供适合用作内燃机的排气净化用催化剂的催化剂载体的金属氧化物的制造方法，并且随着时效维持大的比表面积，具有广泛选择性组成和大比表面积的多金属氧化物的制造方法。解决方案：在金属氧化物的制造方法中，将通过溶解至少一种金属化合物制备的溶液浸渍到具有孔隙并可还原成灰分的多孔材料中，并且在非氧化性气氛中烧成多孔材料烧毁优选孔具有2-40nm平均孔径。当制备多重金属氧化物时，优选将通过溶解至少两种金属化合物制备的溶液浸渍到上述多孔材料中，并将多孔材料暴露于气态氨并在非氧化性气氛中烧制。在金属化合物为铝化合物的情况下，制造α-氧化铝。版权所有（C）2004，JPO

2. 发明专利

JP2001038211A CATALYST AND METHOD FOR CLEANING EXHAUST GAS 失效
公开(公告)号：JP2001038211A
公开(公告)日：2001-02-13
申请号：JP21719699
申请日：1999-07-30
申请人： TOYOTA CENTRAL RES & DEV , TOYOTA MOTOR CORP
发明人： TAKAHASHI NAOKI , SUDA AKIHIKO , HACHISUGA ICHIRO
IPC分类号： B01D53/94 , B01J23/58 , B01J23/63 , B01J23/66 , F01N3/08 , F01N3/10 , F01N3/28
摘要： PROBLEM TO BE SOLVED: To provide a catalyst and method having high NOx cleaning capacity especially against high temp. exhaust gas of 400 deg.C or higher. SOLUTION: In a catalyst for cleaning exhaust gas constituted of a carrier containing titania and zirconia, the NOx occluding material comprising at least one of alkali metal, alkaline earth metal and rare earth elements carried on the carrier and noble metal carried on the carrier, the weight ratio of zirconia in the carrier is 50-90 wt.%, pref., 50-80 wt.%, more pref., 60-80 wt.% per the total weight of zirconia and titania.

3. 发明专利

JPH10202101A COMPOSITE OXIDE-CARRYING CATALYST SUPPORT 失效
公开(公告)号：JPH10202101A
公开(公告)日：1998-08-04
申请号：JP1246097
申请日：1997-01-27
申请人： TOYOTA CENTRAL RES & DEV , TOYOTA MOTOR CORP
发明人： SUZUKI TADASHI , SOFUGAWA HIDEO , SUDA AKIHIKO , MORIKAWA AKIRA , KAMITORI TOSHIO , KIMURA MAREO , SUGIURA MASAHIRO , UKIYOU YOSHIO , KANAZAWA TAKAAKI
IPC分类号： B01J23/10 , B01D53/86 , B01J32/00
摘要： PROBLEM TO BE SOLVED: To provide a catalyst support to be used for a catalyst for exhaust gas purification and having high heat resistance by adding a support having a large specific surface area to a suspension produced by adding an alkaline solution and hydrogen peroxide to a mixed solution containing cerium, aluminum, and zirconium ions and firing the resultant support. SOLUTION: A composite oxide-carrying catalyst support to be used for exhaust gas purification is produced by mixing a salt solution containing a plurality of elements at least containing cerium, zirconium, and aluminum with an alkaline solution and hydrogen peroxide solution to form precursors of composite oxides, adding a support powder with high specific surface area to the resultant suspension containing the precursors, and firing the obtained mixture. Though composition rations of the constituents are not specifically limited, the atomic ratio of cerium to the mixed solution (zirconium + cerium) containing core irons of cerium, aluminum, and zirconium is controlled to be in the range of 0.2-0.8. Moreover, the atomic ratio of aluminum to (zirconium + cerium) is preferably to be in the range of 0.2-2.

4. 发明专利

JPH09271637A CATALYST DEVICE FOR PURIFYING AMMONIA 失效
公开(公告)号：JPH09271637A
公开(公告)日：1997-10-21
申请号：JP30911796
申请日：1996-11-20
申请人： TOYOTA CENTRAL RES & DEV , TOYOTA MOTOR CORP
发明人： NAGAI YASUTAKA , SHINJO HIROBUMI , ITO YOSHIHIKO , MATSUNAGA SHINICHI , SUDA AKIHIKO , MIYOSHI NAOTO , HAYASHI TAKAHIRO , KANAZAWA TAKAAKI , KINUGASA YUKIO , TAKAOKA TOSHIBUMI , TSUJI SHINJI
IPC分类号： B01D53/86 , B01J23/42 , B01J23/44 , B01J23/60 , B01J29/46
摘要： PROBLEM TO BE SOLVED: To provide a novel catalyst device capable of efficiently converting ammonia to N2 within a wide temp. range and a high SV region to purify the same. SOLUTION: A catalyst high in the max. conversion temp. oxidizing ammonia to convert the same to nitrogen to maximize a conversion ratio is arranged on the upstream side of an exhaust gas passage and a catalyst low in the max. conversion temp. is arranged on the downstream side of the exhaust gas passage. Within a low temp. region, ammonia is not almost purified by the catalyst on the upstream side but purified by the catalyst on the downstream side and, within a high temp. region, ammonia is mainly purified by the catalyst on the upstream side to be converted to nitrogen.

5. 发明专利

JPH0498157A EVALUATION METHOD FOR SMELL 失效
公开(公告)号：JPH0498157A
公开(公告)日：1992-03-30
申请号：JP21603190
申请日：1990-08-15
申请人： TOYOTA CENTRAL RES & DEV , TOYOTA MOTOR CORP , TOYODA SPINNING & WEAVING
发明人： FUKUMOTO KAZUHIRO , TSUKIGASE AZUSA , SUDA AKIHIKO , HORII MITSUMASA , SUGIURA MASAHARU , ARAKI OSAMU , YAMADA YOSHIO , SEKIHARA TAKATOSHI , MATSUYAMA AKIHIRO
IPC分类号： G01N31/12 , G01N31/00
摘要： PURPOSE:To reproduce tobacco smells stuck to various test samples with excellent correlation to a field test, by gasifying separatingly a smell consisting of a high boiling point component, from the test sample which is removed of a low boiling point component of tobacco smell by means of curing, and evaluating the separated smell by means of a smell evaluation scale. CONSTITUTION:Cigarettes 3 are burnt a container 1 where a test sample 4 is provided, and tobacco smell is attracted to the sample 4. A low boiling point component of the tobacco smell is removed from the sample 4 with tobacco smell stuck to, by curing, and a high boiling point component is made to remain. The high boiling point component of the smell stuck to the test sample is separated into the container. The smell thus generated is felt actually, and subjected to a sense evaluation, or subjected to a quantitative analysis by means of an apparatus.

6. 发明专利

JPH0473275A VEHICULAR SKIN MATERIAL 失效
公开(公告)号：JPH0473275A
公开(公告)日：1992-03-09
申请号：JP13316990
申请日：1990-05-23
申请人： TOYOTA CENTRAL RES & DEV , TOYODA SPINNING & WEAVING , TOYOTA MOTOR CORP
发明人： SUDA AKIHIKO , SUGIURA MASAHIRO , SEKIHARA TAKATOSHI , MATSUYAMA AKIHIRO , ARAKI OSAMU , YAMADA YOSHIO
IPC分类号： D06N7/00 , B32B25/10 , D06M11/00 , D06M11/74 , D06M11/77 , D06M15/693 , D06M23/00 , D06N7/02
摘要： PURPOSE:To obtain the subject skin material having function to remove malodor in car rooms for a long period by dispersing and fixing a hydrous magnesium silicate-based clay mineral and active carbon in a polymer latex layer prepared by homogeneously fusing a specific amount of a polymer latex between interstices of yarns in a fabric or surface thereof. CONSTITUTION:Active carbon is initially added to 100 pts. wt. polymer latex (e.g. synthetic resin-or rubber-latex), 5-100 pts. wt. hydrous magnesium silicate- based clay mineral and active carbon so as to provide 50-180 pts. wt. total amount of the aforementioned clay mineral and the active carbon and 1-30 pts. wt. polymeric surfactant (e.g. a tripolyphosphate or methyl cellulose) having >=10000 molecular weight as a penetrant is further mixed therewith to afford a homogeneous back coating agent. The resultant back coating agent is then applied to a fabric for a vehicular skin material and dried to provide a skin material in which the above-mentioned clay mineral and activated carbon are dispersed and fixed in a layer of fused and coated polymer latex particles at 15-135 g/m coating amount. Thereby, malodor in car rooms can effectively be removed for a long period and mechanical characteristics are excellent.

7. 发明专利

JP2012110859A EXHAUST GAS PURIFYING CATALYST AND METHOD OF MANUFACTURING THE SAME 审中-公开
公开(公告)号：JP2012110859A
公开(公告)日：2012-06-14
申请号：JP2010263457
申请日：2010-11-26
申请人： TOYOTA MOTOR CORP , TOYOTA CENTRAL RES & DEV
发明人： KUNO HISASHI , NOBUKAWA KEN , MORIKAWA AKIRA , YAMAMURA YOSHIE , HATANAKA MIHO , TAKAHASHI NAOKI , SUDA AKIHIKO
IPC分类号： B01J35/04 , B01D53/94 , B01J23/63 , B01J37/02 , F01N3/10 , F01N3/28
摘要： PROBLEM TO BE SOLVED: To provide an exhaust gas purifying catalyst based on the distribution of gas flow velocity in a cross section vertical to an exhaust gas flow, while improving exhaust gas purification effect.SOLUTION: The exhaust gas purifying catalyst is obtained by coating a substrate with a catalyst layer. A catalyst layer coated on the cross sectional center has an oxygen absorbing/releasing rate slower than a catalyst layer coated on the cross sectional outer periphery, in the cross section vertical to the exhaust gas flow. A method for manufacturing the catalyst for purifying exhaust gas is also provided.

8. 发明专利

JP2005125317A Oxygen storing/release material 有权
标题翻译：氧气储存/释放材料
公开(公告)号：JP2005125317A
公开(公告)日：2005-05-19
申请号：JP2004284619
申请日：2004-09-29
申请人： Toyota Central Res & Dev Lab Inc , Toyota Motor Corp , トヨタ自動車株式会社 , 株式会社豊田中央研究所
发明人： HATANAKA YOSHIO , YOKOTA KOJI , SOFUGAWA HIDEO , SUDA AKIHIKO , MORIKAWA AKIRA , YAMAMOTO TOSHIO , ARAKAWA KENJI , KUNO HISASHI
IPC分类号： B01J20/06 , B01J23/745 , B01J32/00
摘要： PROBLEM TO BE SOLVED: To provide an oxygen storing/release material which can develop a high level of oxygen storing/release capability without use of any noble metal such as Pt and, at the same time, is inexpensive. SOLUTION: This oxygen storing/release material comprises a ceria-containing carrier and iron oxide as active species contained in the carrier. A reduction reaction of Fe 2 O 3 occurs at a lower temperature than a reduction reaction of CeO 2 . Prior to CeO 2 , Fe 2 O 3 is reduced to Fe 3 O 4 , FeO or Fe, and, in a reducing atmosphere, oxygen transfer from the carrier to the active species "Fe" is accelerated. In an oxidizing atmosphere, independently of the presence of the active species, an oxidation reaction of the active species and the carrier proceeds very rapidly, and the carrier, in which the amount of oxygen is insufficient, takes in oxygen from the atmosphere. Further, the oxygen storing/release capability of the iron oxide per se is also added, and, consequently, a high level of oxygen storing/release capability can be developed. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供一种可以在不使用任何贵金属如Pt的情况下产生高水平的氧气储存/释放能力的氧气储存/释放材料，并且同时是便宜的。解决方案：该氧气储存/释放材料包含载体中含有的含有二氧化铈的载体和氧化铁作为活性物质。在比CeO SB 2还原反应更低的温度下进行Fe O 3 的还原反应。在CeO 2 之前，将Fe 2 3 还原成Fe 3 SB SB > FeO或Fe，并且在还原气氛中，从载体向活性物质“Fe”的氧转移加速。在氧化气氛中，与活性物质的存在无关，活性物质和载体的氧化反应非常迅速地进行，氧气量不足的载体从大气中吸收氧气。此外，还添加氧化铁本身的氧气储存/释放能力，因此，可以开发高水平的氧气储存/释放能力。版权所有（C）2005，JPO＆NCIPI

9. 发明专利

JP2004025013A Catalyst for exhaust gas purification and its manufacturing method 审中-公开
公开(公告)号：JP2004025013A
公开(公告)日：2004-01-29
申请号：JP2002184183
申请日：2002-06-25
申请人： Toyota Central Res & Dev Lab Inc , Toyota Motor Corp , トヨタ自動車株式会社 , 株式会社豊田中央研究所
发明人： SUDA AKIHIKO , SUZUKI TADASHI , MATSUNAGA SHINICHI , KUNO HISASHI , ISHIBASHI KAZUNOBU , KANAZAWA TAKAAKI
IPC分类号： B01D53/94 , B01J23/56 , B01J23/63 , B01J35/10
摘要： PROBLEM TO BE SOLVED: To provide a catalyst for exhaust gas purification which is improved in gas diffusion properties and enhanced in oxygen storing and discharging power with regard to the catalyst for purifying an automotive exhaust gas and the like. SOLUTION: The catalyst coating layer contains at least the powder of an oxygen storing and discharging material and has pores with a center pore diameter of 0.1 μm or larger, and the pore volume of the pores within the range of ±50% of the center pore diameter is made to be 0.05 cc/g or larger. Since the catalyst coating layer has a macropore, the gas diffusion properties are improved and the contact probability between the oxygen storing and discharging material and an exhaust gas is increased. Consequently, the oxygen storing and discharging power is enhanced and the purification rate is remarkedly increased as the catalyst coating layer is easily heated by the exhaust gas and reaches an activation temperature in a short time. COPYRIGHT: (C)2004,JPO

10. 发明专利

JPH0473277A VEHICULAR SKIN MATERIAL 失效
公开(公告)号：JPH0473277A
公开(公告)日：1992-03-09
申请号：JP13317190
申请日：1990-05-23
申请人： TOYOTA CENTRAL RES & DEV , TOYODA SPINNING & WEAVING , TOYOTA MOTOR CORP
发明人： SUDA AKIHIKO , SUGIURA MASAHIRO , SEKIHARA TAKATOSHI , MATSUYAMA AKIHIRO , ARAKI OSAMU , YAMADA YOSHIO
IPC分类号： D06N7/00 , B32B25/10 , D06M11/00 , D06M11/74 , D06M11/77 , D06M15/693 , D06M23/00
摘要： PURPOSE:To obtain the subject skin material having function to remove malodor in car rooms by dispersing specific amounts of a hydrous magnesium silicate clay mineral and active carbon in a layer in which a polymer latex having a specific particle diameter or above is fused and fusing the resultant dispersion to a fabric to be the vehicular skin material. CONSTITUTION:A polymeric surfactant having >=10000 molecular weight in an amount of 3-20 pts. wt. is initially added to a hydrous magnesium silicate-based clay mineral in an amount of 5-160 pts. wt. and active carbon in an amount so as to provide 50-180 pts. wt. total amount of the aforementioned clay mineral and the active carbon based on 100 pts. wt. polymer latex (e.g. synthetic resin -or rubber-latex) having >=0.25 mum average particle diameter and stirred to afford a slurry. The aforementioned polymer is then mixed in the resultant slurry to provide a back coating agent, which is subsequently applied to a fabric for a vehicular skin material composed of natural, synthetic fiber, etc. Thereby, the objective skin material in which the above-mentioned clay and active carbon are fixed in a polymer latex layer of fused and coated polymer latex particles at 15-135 g/m coating amount. Thereby, the aforementioned skin material has characteristics of removing malodor in car rooms and suppressing static electricity.

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