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    • 12. 发明专利
    • PRINTING WIRE FOR PRINTER
    • JPS62259868A
    • 1987-11-12
    • JP10448686
    • 1986-05-07
    • TOSHIBA CORP
    • SAITO HIROYUKIKOIZUMI HIDEOTAKAHASHI TSUTAEITO MASAMI
    • B41J2/25C22C1/04C22C27/04C22C32/00
    • PURPOSE:To provide wt. reduction and high speed printing operation and to obtain excellent durability by enhancing hardness and reducing abrasion, by forming a printing wire by processing a sintered body of doped molybdenum containing one or more kind of aluminum, silicon and potassium. CONSTITUTION:A printing wire is formed by processing a sintered body of doped molybdenum containing one or more kind of aluminum (Al), silicon (Si) and potassium (K) and, if surface reducing processing is applied to the sintered body comprising the doped molybdenum, a high hardness product can be obtained by the actions of Al, Si and K. The compositional range of Al. Si and K is set to 0.005-0.75% on a wt. basis and, if the contents thereof are too little, effect is reduced and, if too much, the surface reducing processing is difficult. The doped molybdenum powder having one kind or plural kinds of Al, Si and K added thereto in a predetermined ratio is pressed to mold a compacted powder which is, in turn, sintered to obtain the rod-shaped sintered body. Next, rolling processing and wire drawing processing are applied to the sintered body to form a wire material which is, in turn, cut into a predetermined length to form the printing wire.
    • 13. 发明专利
    • PRINTING WIRE FOR PRINTER
    • JPS62259867A
    • 1987-11-12
    • JP10448586
    • 1986-05-07
    • TOSHIBA CORP
    • SAITO HIROYUKIKOIZUMI HIDEOITO MASAMI
    • B41J2/25C22C1/04C22C27/04
    • PURPOSE:To provide a light wt. printing wire having high strength, by forming said printing wire from a sintered alloy wherein rhenium is added to a high m.p. metal. CONSTITUTION:A high m.p. metal forming a printing wire is tungsten (W) and molybdenum (Mo) and rhenium is added to said metal in a wt. ratio of 1-35%. If the addition ratio thereof is 35% or more, material cost becomes high and the processability of the obtained alloy is lowered because the hardness thereof becomes high. The printing wire is prepared by applying rolling processing and wire drawing processing to a sintered bar formed by sintering a compacted powder comprising a tungsten-rhenium powder mixture of a molybdenum-rhenium powder mixture to form a wire material and cutting said wire material. The working ratio to the sintered bar is set to 98% or more. If the sintered bar is processed at this high working ratio, the structure of the printing wire can be developed sufficiently into a fibrous state and the printing wire sufficiently developing the excellent strength characteristic possessed by the tungsten-rhenium alloy and the molybdenum-rhenium alloy can be manufactured.
    • 14. 发明专利
    • Junction electrode for glass smelting
    • 用于玻璃熔接的接头电极
    • JPS6126519A
    • 1986-02-05
    • JP14737584
    • 1984-07-16
    • Toshiba Corp
    • UEDA SHIGERUKOIZUMI HIDEO
    • H05B3/03C03B5/027C03B5/03
    • PURPOSE: To provide the titled junction electrode capable of preventing the oxidation without cooling the electrode, by joining a glass-smelting part made of Mo and a holding part made of a heat-resisting alloy having oxidation resistance.
      CONSTITUTION: The objective glass smelting junction electrode is manufactured by joining the glass smelting part 1 made of a round Mo rod and the holding part 2 made of a round rod of a heat-resisting alloy (e.g. Fe-Al-Cr alloy) resistance to oxidation. The glass smelting part 1 is inserted to the inside of the furnace wall 6, and the holding part 2 is fixed to the furnace wall 6 with the holder case 3. The base of the holding part 2 is connected to an electrical source to energize the junction electrode. The glass in the furnace is molten by the electrical current applied from the glass smelting part 1. Since the oxidation can be prevented by the use of the above electrode without cooling the electrode exposed to air, the electrode-cooling apparatus can be omitted resulting in remarkable reduction of the initial cost, and molten glass having uniform quality can be produced. Furthermore, the cost of electrode can be reduced because expensive Mo is used only to a part of the electrode.
      COPYRIGHT: (C)1986,JPO&Japio
    • 目的:提供能够防止氧化而不冷却电极的标称接合电极,通过接合由Mo制成的玻璃熔融部件和由具有抗氧化性的耐热合金制成的保持部件。 构成:目标玻璃熔融接合电极通过将由圆形Mo棒制成的玻璃熔炼部分1和由耐热合金(例如Fe-Al-Cr合金)的圆棒制成的保持部分2接合而制造, 氧化。 将玻璃熔融部1插入炉壁6的内部,将保持部2用保持器壳体3固定在炉壁6上。保持部2的基部与电源连接, 接电极。 炉内的玻璃被从玻璃熔炼部分1施加的电流熔化。由于可以通过使用上述电极来防止氧化,而不会使暴露于空气的电极冷却,可以省略电极冷却装置,从而导致 可以显着降低初始成本,并且可以产生具有均匀质量的熔融玻璃。 此外,由于昂贵的Mo仅用于电极的一部分,所以可以降低电极的成本。
    • 15. 发明专利
    • Production of molybdenum jig for high-temperature heat treatment
    • 生产用于高温热处理的莫氏金刚石
    • JPS59150072A
    • 1984-08-28
    • JP1978183
    • 1983-02-10
    • Toshiba Corp
    • FUKAZAWA MIHARUKAWAI MITSUOKOIZUMI HIDEOSAITOU HIROYUKIUEDA SHIGERU
    • B22F3/24C22C1/05C22C27/04C22F1/18
    • PURPOSE: To obtain an Mo jig for a high-temp. heat treatment having excellent high-temp. strength by subjecting a doped Mo material subjected to reduction working at a prescribed reduction ratio or above to stress relief annealing at the recrystallization temp. or below then forming the material and subjecting the formed material to a heat treatment at the temp. higher than the recrystallization temp.
      CONSTITUTION: A doped Mo sintered material contg. 0.005W0.75wt% ≥1 kind among Al, Si and K is subjected to hot rolling at a reduction rate of ≥85%. The resulting doped Mo material is subjected to strain relief annealing as it is or at the recrystallization temp. or below and is then formed to a boat for heat treatment. Said boat is then heat-treated in a temp. range from the temp. higher by 100°C than the recrystallization temp. up to 2,200°C. The Mo jig for high- temp. heat treatment having improved resistance to thermal fatigue and creep strength is thus obtd. The Mo jig is usable in a stable state for a long time at elevated temp. and contributes to a considerable improvement in the operating efficiency and reliability of a ceramic calcining furnace and a high-temp. heat treating furnace, etc.
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:获得用于高温的Mo夹具。 热处理具有优异的高温。 通过在规定的压下率以上进行还原加工的掺杂Mo材料在再结晶温度下进行应力消除退火的强度。 或以下,然后形成材料并使所形成的材料在温度下进行热处理。 高于再结晶温度。 构成:掺杂的Mo烧结材料 Al,Si和K中的0.005-0.75重量%> = 1种以> 85%的还原率进行热轧。 所得掺杂的Mo材料按原样或在再结晶温度下进行应变消除退火。 或以下,然后形成船用于热处理。 然后将所述的船在温度下进行热处理。 范围从温度 比再结晶温度高100℃。 高达2200度 用于高温的Mo夹具 因此,耐热疲劳和蠕变强度的耐热性得到改善。 Mo夹具可在高温下长时间稳定使用。 并且有助于陶瓷煅烧炉和高温的操作效率和可靠性的显着提高。 热处理炉等
    • 18. 发明专利
    • Molybdenum alloy
    • 莫氏合金
    • JPS59116356A
    • 1984-07-05
    • JP22401682
    • 1982-12-22
    • Toshiba Corp
    • KOIZUMI HIDEOISHIHARA HIDEOMATSUMOTO TATSUHIKOFUKAZAWA MIHARU
    • C22C27/04
    • PURPOSE: To obtain an Mo alloy with a high recrystallization temp. and superior strength at high temp. by adding a small amount of Zn and a very small amount of B to Mo and by alloying them.
      CONSTITUTION: Powders of Mo, Zn and B and C are blended together in a prescribed ratio, and they are mixed by means of a magnetic pot roll. The mixture is press-molded under 3,000kg/cm
      2 pressure. The molded body is sintered by calcination at 1,830°C in a hydrogen atmosphere for 7hr, and two such sintered bodies are joined together and alloyed by a vacuum arc melting method using a consumable electrode to form an Mo alloy ingot contg. 0.02W0.5% Zr and 5W 100ppm B. The ingot is worked into a thin plate by hot forging, hot rolling and cold rolling. An Mo alloy with a high recrystallization temp. and superior strength at high temp. is obtd. and is used as a heat resistant material.
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:获得具有高再结晶温度的Mo合金。 在高温下具有优异的强度。 通过向Mo添加少量的Zn和非常少量的B并通过使它们合金化。 构成:将Mo,Zn和B和C的粉末以规定的比例混合在一起,并通过磁力罐辊混合。 将混合物在3000kg / cm 2压力下进行压模。 通过在氢气气氛中在1830℃下煅烧7小时,将两个这样的烧结体接合在一起并通过使用消耗电极的真空电弧熔化法进行合金烧结,形成Mo合金锭。 0.02-0.5%Zr和5-100ppm B.通过热锻,热轧和冷轧将锭加工成薄板。 具有高再结晶温度的Mo合金 在高温下具有优异的强度。 是obtd。 并用作耐热材料。
    • 19. 发明专利
    • Oxidation resistant molybdenum member
    • 耐氧化钼成员
    • JPS59113182A
    • 1984-06-29
    • JP22295982
    • 1982-12-21
    • Toshiba Corp
    • ISHIHARA HIDEOKOIZUMI HIDEO
    • B23K20/04C23C30/00
    • C23C30/00
    • PURPOSE:To obtain an Mo member with remarkably improved oxidation resistance by coating the surface of Mo or an Mo alloy with metallic Cr. CONSTITUTION:The surface of Mo or an Mo alloy is coated with a metallic Cr layer. Since the Cr layer is dense, an Mo member whose base material undergoes no oxidation is obtd. The preferred thickness of the Cr layer is >=about 10mum, and the layer is formed by a spraying method, a method for forming a thin film in vacuum such as a CV method or a vapor deposition method, or a method for press-bonding metallic Cr foil and carrying out mutual diffusion by heating. In case of the 1st and the 2nd methods, mutual diffusion is preferably carried out. The especially preferred method among said three methods is the 3rd method.
    • 目的:通过用金属Cr涂覆Mo或Mo合金的表面,获得具有显着提高的抗氧化性的Mo部件。 构成:Mo或Mo合金的表面涂有金属Cr层。 由于Cr层是致密的,所以不能氧化基材的Mo构件。 Cr层的优选厚度为> =10μm左右,通过喷涂法,CV法或蒸镀法等真空中形成薄膜的方法,或者压接方法 金属铬箔,通过加热进行相互扩散。 在第1和第2方法的情况下,优选进行相互扩散。 所述三种方法中特别优选的方法是第三种方法。