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    • 120. 发明专利
    • DOPING OF III-V COMPOUND SEMICONDUCTOR
    • JPH02229425A
    • 1990-09-12
    • JP4970189
    • 1989-03-01
    • RIKAGAKU KENKYUSHO
    • IIMURA YASUFUMIDEN SHOJINAGATA AKIRAAOYANAGI KATSUNOBUNANBA SUSUMU
    • H01L21/205H01L21/203
    • PURPOSE:To control an amount of impurities in a crystal highly accurately and simply by a method wherein an energy and a density, i.e., a filament current and a grid voltage, of an electron beam which is applied to a Group III organic metal compound gas as a dopant gas containing dopant atoms are changed and a raw-material gas is operated. CONSTITUTION:When the Group III organic compound gas is passed inside a grid 18, it collides with thermoelectrons; its one part is decomposed and ionized and reaches a substrate 26. On the other hand, a Group V compound gas is pyrolyzed by using a heater 30; Group V atoms reach the substrate 26. A sufficient surface mobility is given to Ga and As which have reached the substrate 26; a growth film is heated so as to be transformed into a single crystal. In addition, an extraction electrode 32 and a quadruple pole 34 are installed between the grid 18 and the substrate 26. The Group V organic compound gas is decomposed and ionized inside the grid 18; after that, only ions containing carbon atoms are introduced into the quadruple pole 34 by using the extraction electrode 32; only desired ions are incident on the growth substrate 26. As a result, impurities can be controlled with a higher accuracy.