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    • 9. 发明公开
    • METHOD FOR PRODUCING STANNOUS OXIDE, STANNOUS OXIDE, METHOD FOR PRODUCING Sn PLATING SOLUTION, AND METHOD FOR REMOVING IMPURITIES FROM SN PLATING SOLUTION
    • VERFAHREN ZUR HERSTELLUNG VON ZINNOXID,ZINNOXID,VERFAHREN ZUR HERSTELLUNG VON SN-PLATTIERUNGSLÖSUNGUND VERFAHREN ZUR BESEITIGUNG VON VERUNREINIGUNGEN AUS EINER SN-PLATTIERUNGSLÖSUNG
    • EP3070055A4
    • 2017-05-31
    • EP15758801
    • 2015-03-02
    • MITSUBISHI MATERIALS CORP
    • KATASE TAKUMAHIRANO HIROTAKA
    • C01G19/02C23C18/16
    • C09D1/00C01G19/02C01P2006/80C23C18/1617C23C18/1692C23C18/31C25D21/18
    • The method of producing stannous oxide includes: a Sn ion-containing acid solution forming step (S01); a first neutralizing step (S02), which is a step of forming Sn precipitates by adding one or more of alkaline solutions of ammonium carbonate, ammonium bicarbonate, and aqueous ammonia to the Sn ion-containing acid solution to retain pH at 3-6 therein; a Sn precipitate separating step (S03); a Sn precipitate dispersing step (S04), which is a step of dispersing the separated Sn precipitates in a solvent liquid to obtain a dispersion liquid; and a second neutralizing step (S06), which is a step of forming SnO by adding an alkaline solution to the dispersion liquid of the Sn precipitates and then by heating, wherein Na, K, Pb, Fe, Ni, Cu, Zn, Al, Mg, Ca, Cr, Mn, Co, In, and Cd reside in the Sn ion-containing acid solution in the first neutralizing step (S02).
    • 生成氧化亚锡的方法包括:含Sn离子酸溶液形成步骤(S01); 第一中和步骤(S02),其是通过将一种或多种碳酸铵,碳酸氢铵和氨水的碱性溶液添加到含Sn离子酸溶液中以将pH保持在其中3-6而形成Sn沉淀物的步骤 ; Sn沉淀物分离步骤(S03); 将析出的Sn析出物分散于溶剂液中,得到分散液的工序即Sn沉淀分散工序(S04) 以及第二中和步骤(S06),其是通过向所述Sn沉淀物的分散液中加入碱性溶液然后加热来形成SnO的步骤,其中Na,K,Pb,Fe,Ni,Cu,Zn,Al ,在第一中和步骤(S02)中,Mg,Ca,Cr,Mn,Co,In和Cd留在含Sn离子酸溶液中。
    • 10. 发明公开
    • INORGANIC MESOPOROUS MATERIALS WITH CHIRAL NEMATIC STRUCTURES AND PREPARATION METHOD THEREOF
    • ANORGANISCHEMESOPORÖSEMATERIALIEN麻醉师CHIRALEN NEMATISCHEN STRUKTUREN SOWIE HERSTELLUNGSVERFAHRENDAFÜR
    • EP2556019A4
    • 2016-12-14
    • EP11764971
    • 2011-03-30
    • FPINNOVATIONS
    • MACLACHLAN MARK JOHNSHOPSOWITZ KEVIN ERICHAMAD WADOOD YASSERQI HAO
    • C01B33/12B01D67/00B01D71/02C01B33/16C01B37/00C01G17/02C01G19/02C08J9/28C08K3/36C08L1/02C09K19/02C09K19/52
    • C09K19/02B01D67/0048B01D67/0058B01D71/027B01D2325/025B01D2325/44C01B33/12C01B37/00C01G17/02C01G19/02C09K19/52
    • The present invention describes a composition and a method for producing mesoporous silica materials with a chiral organization. In the method, a polymerizable inorganic monomer is reacted in the presence of nanocrystalline cellulose (NCC) to give a material of inorganic solid with cellulose nanocrystallites embedded in a chiral nematic organization. The NCC can be removed to give a stable porous structure that retains the chiral organization of the NCC template. The new materials may be obtained as iridescent free-standing films with high surface area. Through control of the reaction conditions, the color of the films can be varied across the entire visible spectrum. These are the first materials to combine mesoporosity with long-range chiral ordering that leads to photonic properties. Examples of possible applications of the materials are: lightweight reinforcement materials, low k dielectric materials, tunable reflective filters, adsorbents, stationary phases for chromatography of chiral or achiral substances, supports for catalysts (e.g., for asymmetric synthetic transformations), and as a template to generate other new porous materials (e.g., porous carbon or porous metals), preferably with chiral nematic structures.
    • 本发明描述了一种具有手性组织的制备介孔二氧化硅材料的组合物和方法。 在该方法中,可聚合无机单体在纳米晶体纤维素(NCC)的存在下反应,得到嵌入手性向列组织中的纤维素纳米晶的无机固体材料。 可以去除NCC以产生保持NCC模板的手性组织的稳定的多孔结构。 新材料可以作为具有高表面积的彩虹色自立膜获得。 通过控制反应条件,可以在整个可见光谱范围内改变膜的颜色。 这些是将介孔与长距离手性排序结合起来产生光子性质的第一种材料。 材料可能应用的例子有:轻质增强材料,低k电介质材料,可调谐反射滤光片,吸附剂,手性或非手性物质层析固定相,催化剂载体(例如,用于不对称合成转化)和作为模板 以产生其它新的多孔材料(例如,多孔碳或多孔金属),优选具有手性向列结构。