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    • 2. 发明公开
    • HEAT-SHRINKABLE POLYESTER FILM ROLL
    • EP4039446A1
    • 2022-08-10
    • EP20873198.4
    • 2020-09-23
    • TOYOBO CO., LTD.
    • INOUE, MasafumiHARUTA, Masayuki
    • B29C55/06B29C55/14B29C61/02C08J5/18B65H18/28B65H75/10
    • In order to reduce the occurrence of wrinkling on a winding core part for a film roll formed by winding a heat-shrinkable polyester film for which a thinned longitudinal direction is a primary shrinkage direction, this heat-shrinkable polyester film roll is obtained by winding a heat-shrinkable polyester film on a paper tube, the film having a primary shrinkage direction that is the longitudinal direction and having a shrinkage rate in the primary film shrinkage direction of 40% or more following treatment in hot water at 90°C for 10 seconds, wherein the heat-shrinkable polyester film and the film roll satisfy the following conditions (1) to (7):
      (1) The film winding length is 1000 to 30000 m;
      (2) The film width is 50 to 1500 mm;
      (3) The film thickness is 5-30 pm;
      (4) The thickness irregularity at a surface layer part of the film roll in the entire film width direction is 20% or less;
      (5) The paper tube has an inner diameter of 3 inches, the difference in clearance of the paper tube in the width direction after the film is removed from the film roll is 0.5 mm or less, and the flat compressive strength of the paper tube after the film is removed is 1700 N/100mm or more;
      (6) The mean value of the winding hardness of the surface layer part of the film roll in the width direction is 500-850; and
      (7) The natural shrinkage rate in the longitudinal direction is 2.0% or less after 28 consecutive days of exposing the film in an atmosphere at a temperature of 40°C and relative humidity of 85%.
    • 5. 发明公开
    • HEAT-SHRINKABLE POLYESTER-BASED FILM
    • EP3778727A1
    • 2021-02-17
    • EP19777270.0
    • 2019-03-25
    • TOYOBO CO., LTD.
    • ISHIMARU, ShintaroHARUTA, Masayuki
    • C08J5/18B29C55/08B29C61/02B65D65/02B65D77/20C08L67/02G09F3/04B29K67/00B29K105/02B29L7/00
    • [Problem] An object is to provide a heat-shrinkable polyester-based film using biomass and/or containing recycled PET preferably containing a high ratio of recycled PET, and the film does not substantially contain amorphous component where the heat-shrinkage ratio in the width direction is high and the irregularity of thickness is small. An object is also to provide a process for producing the film.
      [Solution] A heat-shrinkable polyester-based film comprising ethylene terephthalate unit by 90 mol% or more out of whole ester unit 100 mol%,
      wherein,
      at least a part of ethylene glycol and/or terephthalic acid constituting the ethylene terephthalate unit is derived from biomass resource or the heat-shrinkable polyester-based film comprises polyester resin recycled from PET bottles, and
      the heat-shrinkable polyester-based film satisfies the following requirements (1) to (4):
      (1) heat-shrinkage ratio in a width direction measured by shrinking the film for 10 seconds in 90°C hot water is 50% or more and 75% or less,
      (2) heat-shrinkage ratio in a longitudinal direction measured by shrinking the film for 10 seconds in 90°C hot water is -6% or more and 14% or less,
      (3) heat-shrinkage ratio in the longitudinal direction measured by shrinking the film for 10 seconds in 70°C hot water is -6% or more and 6% or less, and
      (4) irregularity of thickness in the width direction is 1% or more and 20% or less.