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    • 4. 发明公开
    • CATHODE COMPOSITE MATERIAL WITH IMPROVED ELECTRODE EFFICIENCY AND ENERGY DENSITY CHARACTERISTICS
    • LITHIUM-SEKUNDÄRBATTERIEMIT VERBESSERTEN ELEKTRODENEFFIZIENZ- UND ENERGIEDICHTEEIGENSCHAFTEN
    • EP2339673A2
    • 2011-06-29
    • EP09822198.9
    • 2009-10-21
    • LG Chem, Ltd.
    • CHOY, SanghoonLEE, Yong TaePARK, Hong-KyuPARK, Soo MinKIL, Hyo-shikPARK, Cheol-Hee
    • H01M4/52
    • H01M4/5825C01B25/37H01M4/136H01M10/052H01M2006/5094
    • Provided is a cathode mix for lithium secondary batteries, comprising a cathode active material having a composition represented by the following Formula I: LiFe(P 1-X O 4 ) (I) wherein a molar fraction (1-x) of phosphorus (P) is in the range of 0.910 to 0.999, to allow operational efficiency of the cathode active material to be leveled to a lower operational efficiency of an anode active material and improve energy density of the cathode active material.
      The cathode mix maximizes operational efficiency of batteries, minimizes electrode waste and thus reduces manufacturing costs of batteries. Furthermore, The cathode active material, wherein a molar fraction (1-x) of phosphorus (P) is lower than 1, according to the present invention contains both Fe 2+ and Fe 3+ , thus advantageously causing no structural deformation, improving ionic conductivity, exhibiting superior rate properties, inhibiting IR drop upon charge/discharge, thereby imparting high energy density to batteries.
    • 本发明提供一种锂二次电池用阴极混合物,其特征在于,具有由下式I表示的组成的正极活性物质:磷(P)的摩尔分数(1-x)为LiFe(P 1〜XO 4)(I) 在0.910至0.999的范围内,以使阴极活性材料的操作效率平衡至较低的负极活性材料的操作效率并提高阴极活性材料的能量密度。 阴极混合物最大限度地提高电池的运行效率,最大限度地减少电极浪费,从而降低电池的制造成本。 此外,根据本发明的磷(P)的摩尔分数(1-x)低于1的正极活性材料含有Fe 2+和Fe 3+,因此有利地不引起结构变形,改善离子 电导率,表现出优异的速率特性,抑制充电/放电时的IR降低,从而赋予电池高的能量密度。