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    • 5. 发明授权
    • CRYSTALLINE NANOMETRIC LIFEPO4
    • KRISTALLINES NANOSKALIGES LIFEPO4
    • EP1899268B1
    • 2012-10-10
    • EP06754362.9
    • 2006-06-15
    • UmicoreCentre National de la Recherche Scientifique
    • DELACOURT, CharlesPOIZOT, PhilippeMASQUELIER, Christian
    • C01B25/37H01M4/13
    • H01M4/5825C01B25/37H01M10/052H01M10/0565Y10T428/2982
    • The present invention relates to lithium secondary batteries and more specifically to positive electrode materials operating at potentials greater than 2.8 V vs. Li+/Li in nonaqueous electrochemical cells. In particular, the invention relates to crystalline nanometric carbon-free olivine-type LiFePO4 powders with enhanced electrochemical properties. A direct precipitation process is described for preparing crystalline LiFePO4powder, comprising the steps of: —providing a water-based mixture having at a pH between 6 and 10, containing a water-miscible boiling point elevation additive, and Li(I), Fe(II) and P(V) as precursor components; —heating said water-based mixture to a temperature less than or equal to its boiling point at atmospheric pressure, thereby precipitating crystalline LiFePO4 powder. An extremely fine 50 to 200 nm particle size is obtained, with a narrow distribution. The fine particle size accounts for excellent high-drain properties without applying any carbon coating. This allows for a significant increase in the active material content of the electrode. The narrow distribution facilitates the electrode manufacturing process and ensures a homogeneous current distribution within the battery.
    • 本发明涉及锂二次电池,更具体地说涉及在非水电化学电池中工作电压大于2.8V的正电极材料,相对于Li + + / Li。 特别地,本发明涉及具有增强的电化学性质的结晶纳米无碳橄榄石型LiFePO 4 N 4 O 3粉末。 描述了用于制备结晶LiFePO 4粉末的直接沉淀方法,其包括以下步骤:提供pH6至10的含有水混溶沸点升高添加剂的水基混合物, 和作为前体成分的Li(I),Fe(II)和(V) 将所述水性混合物加热至大气压下的沸点以下,从而析出结晶LiFePO 4粉末,得到极细微的50〜200nm的粒径,分布窄。 在不施加任何碳涂层的情况下,细颗粒尺寸具有优异的高排水性能。 这允许电极的活性物质含量显着增加。 窄的分布有助于电极制造过程,并确保电池内的均匀电流分布。
    • 8. 发明公开
    • Continuous synthesis of carbon-coated lithium-iron-phosphate
    • 锂离子磷酸盐
    • EP2292557A1
    • 2011-03-09
    • EP09011306.9
    • 2009-09-03
    • Clariant International Ltd.
    • Metz, Hans Joachim, Dr.Waser, OliverBüchel, RobertPratsinis, Sotiris E.
    • C01B25/45
    • H01M4/5825B82Y30/00C01B25/37C01P2002/60C01P2002/82C01P2004/62C01P2004/64C01P2004/86C01P2006/12C01P2006/32C01P2006/40H01M4/136H01M4/366H01M4/625
    • The invention relates to a continuous process for preparing carbon-coated lithium-iron-phosphate particles, wherein the carbon-coated lithium-iron-phosphate particles have a mean (d 50 ) particle size of 10 to 150 nm, and wherein the carbon-coating is an acetylene-black coating, comprising performing in a reactor a flame-spray pyrolysis step (i) in a particle formation zone of the reactor, and a carbon-coating step (ii) in a carbon-coating zone of the reactor, wherein in
      (i) a combustible organic solution containing a mixture of lithium or a lithium compound; iron or an iron compound; and phosphorus or a phosphorous compound in an organic solvent, is fed through at least one nozzle where said organic solution is dispersed, ignited and combusted, to give a flame spray thereby forming an aerosol of lithium iron phosphate particles;
      (ii) acetylene gas is injected into said aerosol thereby forming an acetylene-black coating on the lithium iron phosphate particles;
      (iii) the coated particles are cooled by an inert quench gas and collected on a filter.
    • 本发明涉及制备碳涂覆的磷酸铁锂颗粒的连续方法,其中碳涂覆的磷酸铁锂颗粒的平均(d 50)粒径为10〜150nm,其中,碳 - 涂层是乙炔黑涂层,其包括在反应器中在反应器的颗粒形成区域中进行火焰喷射热解步骤(i)和在反应器的碳涂覆区域中的碳涂覆步骤(ii) 其中在(i)含有锂或锂化合物的混合物的可燃性有机溶液中; 铁或铁化合物; 在有机溶剂中的磷或磷化合物通过分散,点燃和燃烧所述有机溶液的至少一个喷嘴进料,得到火焰喷雾,从而形成磷酸铁锂颗粒的气溶胶; (ii)将乙炔气注入所述气溶胶中,由此在磷酸铁锂颗粒上形成乙炔黑涂层; (iii)涂覆的颗粒通过惰性骤冷气体冷却并收集在过滤器上。