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    • 7. 发明公开
    • SECONDARY METAL CHALCOGENIDE BATTERIES
    • METALL-CHALCOGENID-SEKUNDÄRBATTERIEN
    • EP3090457A4
    • 2017-09-20
    • EP14876898
    • 2014-12-31
    • DYNANTIS CORP
    • SAMMELLS ANTHONY F
    • H01M10/39H01M4/02H01M4/38H01M4/58
    • H01M4/02H01M4/381H01M4/581H01M10/39H01M2300/002
    • Cell and batteries containing them employing a transition metal chalcogenide positive electrode (cathode) in combination with a liquid alkali metal haloaluminate. At operating temperatures, the positive electrode (cathode) of the invention comprises a solid matrix comprising electroactive cathode material permeated with and in physical and electrical contact with liquid alkali metal haloaluminate electrolyte. The positive and negative electrodes are separated with a solid alkali metal conducting electrolyte. The transition metal chalcogenide is not in direct physical contact with the solid electrolyte. Electric and ionic conductivity between the solid electrolyte and the positive electrode is mediated by the liquid alkali metal haloaluminate electrolyte. More specifically, the cells are sodium/iron sulfide cells. Batteries of the invention are useful for bulk energy storage, particularly for electric utility grid storage, as well as for electric vehicle propulsion.
    • 使用过渡金属硫族化合物正极(阴极)和液态碱金属卤铝酸盐的电池和含有它们的电池。 在操作温度下,本发明的正电极(阴极)包含固体基质,该固体基质包含渗透液体碱金属卤铝酸盐电解质并与其物理和电接触的电活性阴极材料。 正极和负极用固体碱金属导电电解质分开。 过渡金属硫族化合物不与固体电解质直接物理接触。 固体电解质和正极之间的电和电导率由液态碱金属卤铝酸盐电解质介导。 更具体地说,细胞是钠/铁硫化物细胞。 本发明的电池可用于散装能量存储,特别是用于公用电网存储以及电动车辆推进。