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    • 10. 发明授权
    • Method of forming a lattice-mismatched semiconductor layer
    • 形成晶格失配半导体层的方法
    • EP1386348B9
    • 2012-07-04
    • EP02750893.6
    • 2002-05-07
    • Innolume GmbH
    • Ledentsov, Nikolai Nikolaevich
    • H01L21/20H01L21/308
    • C30B25/18B82Y10/00B82Y20/00H01L21/0237H01L21/02395H01L21/02439H01L21/02463H01L21/02507H01L21/02521H01L21/02546H01L21/3245H01L33/0062H01S5/22H01S5/3201H01S2301/173H01S2304/12Y10S438/902Y10S438/962
    • The method produces coherent dislocation-free regions from initially dislocated and/or defect-rich lattice mismatched layer grown on top of the substrate having a different lattice constant, which does not contain any processing steps before of after the lattice-mismatched layer growth. The process preferably uses in situ formation of a cap layer on top of a dislocated layer. The cap layer preferably has a lattice parameter close to that in the underlying substrate, and different from that in the lattice mismatched layer in no strain state. Under these conditions, the cap layer undergoes elastic repulsion from the regions in the vicinity of the dislocations, where the lattice parameter is the most different from that in the substrate. The cap layer is absent in these regions. When the cap layer has a lower thermal evaporation rate than the underlying lattice-mismatched layer, the regions of this lattice-mismatched layer containing dislocations are selectively evaporated at high enough temperatures, and only the coherent defect-free regions of the initially defect-rich lattice-mismatched layer remain on the substrate. In one embodiment of the invention, the defect-free regions are formed on the substrate with a size preferably tuned in the range of 30-1000 nm, depending on the annealing conditions, thickness of the cap layer, and the lattice mismatch. A device created by this method is also disclosed.
    • 该方法从在具有不同晶格常数的衬底上生长的初始位错和/或缺陷富集的晶格失配层产生无关位错无区域,其在晶格失配层生长之前不包含任何处理步骤。 该方法优选使用在位错层顶部原位形成覆盖层。 盖层优选具有接近于下层基板中的晶格参数,并且在无应变状态下与晶格失配层中的晶格参数不同。 在这些条件下,帽层从位错附近的区域经历弹性排斥,其中晶格参数与衬底中的晶格参数最不同。 这些区域中没有盖层。 当盖层具有比下面的晶格失配层更低的热蒸发速率时,包含位错的晶格失配层的区域在足够高的温度下被选择性地蒸发,并且只有最初富含缺陷的相干缺陷区域 晶格失配的层保留在衬底上。 在本发明的一个实施例中,取决于退火条件,覆盖层的厚度和晶格失配,在衬底上形成无缺陷区域,其尺寸优选调整在30-1000nm的范围内。 还公开了由该方法创建的设备。