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    • 9. 发明公开
    • Method of reactivating electrode for electrolysis
    • Verfahren zur Wiederherstellung einer Elektrodefürdie Elektrolyse
    • EP1923487A2
    • 2008-05-21
    • EP07021299.8
    • 2007-10-31
    • PERMELEC ELECTRODE LTD.
    • Kato, Akihiro
    • C25B11/00C25B15/00C25C7/02C25C7/06C25C1/12C25B11/04
    • C25B11/0442C23G1/00C23G1/103C23G1/106C25B11/00C25B15/00C25C1/12C25C7/02C25C7/06C25D17/10
    • The present invention provides a method of reactivating an electrode for electrolysis, which includes successively conducting two steps including an acid treatment step of dipping an electrode for electrolysis whose activity has decreased through electrolysis due to deposition of an electrode surface deposit containing a lead compound on a surface of the electrode for electrolysis in an aqueous solution containing from 5 % by mass to 30 % by mass of nitric acid and from 5 % by mass to 20 % by mass of hydrogen peroxide and a high-pressure water washing step of conducting high-pressure water washing under a pressure of from 50 to 100 MPa, or successively conducting three steps including an alkali treatment step of dipping an alkali metal hydroxide aqueous solution of from 5 % by mass to 20 % by mass and the foregoing acid treatment step and the foregoing high-pressure water washing step, to remove an electrode surface deposit containing a lead compound or a lead compound and antimony oxide, thereby reactivating the electrode for electrolysis whose activity has decreased.
    • 本发明提供了一种电解电极的还原方法,其中包括连续进行两步,包括浸渍电解用电极的酸处理步骤,该电解活性由于在含有铅化合物的电极表面沉积物沉积而通过电解而降低活性 在含有5质量%〜30质量%硝酸和5质量%〜20质量%过氧化氢的水溶液中进行电解的电极表面,以及高压水洗步骤, 在50〜100MPa的压力下进行高压水洗,或者依次进行三步法,包括将碱金属氢氧化物水溶液浸渍5质量%〜20质量%的碱处理工序和上述酸处理工序和 前述的高压水洗步骤,以除去含铅化合物或铅化合物和锑氧化物的电极表面沉积物 de,从而使活性降低的电解电极重新激活。