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    • 6. 发明授权
    • METHOD FOR MANUFACTURING FLUOROELASTOMERS
    • VERFAHREN ZUR HERSTELLUNG VON FLUORELASTOMEREN
    • EP2705061B1
    • 2017-02-01
    • EP12717763.2
    • 2012-05-02
    • Solvay Specialty Polymers Italy S.p.A.
    • CHERNYSHEVA, LiubovKENT, Bradley LaneCOMINO, GiovanniKAPELYUSHKO, Valeriy
    • C08F214/22
    • C08F214/28C08F214/22C08F214/222C08F214/225
    • The invention pertains to a process for manufacturing a fluoroelastomer [fluoroelastomer (A)] having a heat of fusion of less than 5 J/g as measured by ASTM D-3418-08, said method comprising emulsion polymerizing vinylidene fluoride (VDF) in the presence of at least one additional fluorinated monomer, in an aqueous polymerization medium, said method comprising polymerizing VDF and said additional fluorinated monomer(s) in the presence of a redox radical initiator system comprising: -at least one organic oxidizing agent [agent (O)]; -at least one organic reducing agent [agent (R)]; wherein agent (O) is fed to said polymerization medium separately from agent (R), so that agent (O) comes in contact with agent (R) exclusively in said polymerization medium comprising VDF and optional additional monomer(s), to fluoroelastomers having low amount of chain defects and low amount of polar end groups, notably obtainable from said process, and to curable compositions therefrom.
    • 本发明涉及通过ASTM D-3418-08测定的具有小于5J / g的熔化热的含氟弹性体[含氟弹性体(A)]的制造方法,所述方法包括将聚偏二氟乙烯(VDF)在 在水性聚合介质中存在至少一种另外的氟化单体,所述方法包括在氧化还原自由基引发剂体系存在下聚合VDF和所述另外的氟化单体,其包含: - 至少一种有机氧化剂[试剂(O )]; - 至少一种有机还原剂[agent(R)]; 其中将试剂(O)与试剂(R)分开地进料到所述聚合介质中,使得试剂(O)仅在包含VDF和任选的另外的单体的所述聚合介质中与试剂(R)接触,具有含氟弹性体 少量的链缺陷和少量的极性端基,特别可从所述方法获得,以及可固化组合物。