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    • 2. 发明授权
    • ALLYL-BEARING FLUORINATED IONOMERS
    • 含烯烃氟化离聚物
    • EP2882705B1
    • 2018-02-21
    • EP13747991.1
    • 2013-07-30
    • Solvay Specialty Polymers Italy S.p.A.
    • MERLO, LucaTORTELLI, VitoWLASSICS, IvanOLDANI, Claudio
    • C07C209/00C08J5/22C08F216/14
    • C07C217/46C07C41/30C07C43/17C07C213/02C08F216/1466C08G65/007C08J5/2237C08F214/262C08F216/125
    • The present invention provides a fluorinated ionomer [polymer (I)] comprising recurring units derived from at least the following monomers: (i) 5 to 50% by weight of a fluorinated monomer [monomer (A)] containing at least one —SO2X functionality, preferably having the formula of CF2═CF—O—(CF2CF(CF3)O)m—(CF2)mSO2X (I) wherein m is 0 or 1, n is an integer between 0-10, and X is selected from F, OH, and O−Me+, wherein Me+ indicates an alkali metal ion or an ammonium cation of formula NR4− where each R independently represents a hydrogen atom or a monovalent organic radical selected from aliphatic radicals having from 1 to 8 carbon atoms and arylic or alicyclic radicals having from 3 to 8 carbon atoms; (ii) a non-functional fluorinated monomer [monomer (B)] having at least one ethylene unsaturation; and (iii) a fluorinated polyfunctional compound having the general formula: (CR1R2═CFCF2—O)a—Rf—((O)c—CF═CR3R4)b (II) wherein: a is an integer equal to or larger than 1, preferably a is 1, 2, or 3; b is 0 or 1 and the sum of a and b is an integer equal to or larger than 2; c is 0 or 1; R1, R2, R3 and R4 are independently selected from F, H, alkyl, alkoxy, polyoxy alkyl, perfluoroalkyl, perfluoroalkoxy or perfluoropolyoxy alkyl, preferably F; and Rf represents a hydrocarbon or fluorocarbon group having at least two carbon atoms. The low-EW perfluorinated ionomers made of polymer (I) are adapted to be processed into thin films, which are found to have superior physical stability than the existing products and are thus well suited for low humidity or high temperature electrochemical applications. Moreover, these low-EW ionomers are melt processable and have limited loss of volatile substances at their melt processing temperatures.
    • 6. 发明公开
    • FLEXIBLE PIPE
    • 灵活的管道
    • EP3208508A1
    • 2017-08-23
    • EP15850649.3
    • 2015-10-06
    • Daikin Industries, Ltd.
    • MURAKAMI, ShinyaINABA, TakeshiKITAHARA, TakahiroKUWAJIMA, Yuuki
    • F16L11/08C08J5/00E21B17/01
    • F16L11/08C08F214/182C08F214/22C08F214/26C08F214/262C08G2650/40C08J5/00C08J2327/18E21B17/01
    • The present invention provides a flexible pipe having excellent blister resistance in a high-temperature and high-pressure environment even though including a thick resin pipe. The flexible pipe includes a resin pipe having a thickness of greater than 5 mm. The resin pipe is formed from a resin having a CO 2 permeability coefficient P(CO 2 ) of 20 × 10 -9 cm 3 ·cm/cm 2 ·s·cmHg or lower at 150°C, a CH 4 permeability coefficient P(CH 4 ) of 10 × 10 -9 cm 3 ·cm/cm 2 ·s·cmHg or lower at 150°C, a ratio D(CO 2 )/S(CO 2 ) between a CO 2 diffusion coefficient D(CO 2 ) and a CO 2 solubility coefficient S(CO 2 ) of 3 × 10 -5 Pa·m 2 /s or higher at 150°C, and a ratio D(CH 4 )/S(CH 4 ) between a CH 4 diffusion coefficient D(CH 4 ) and a CH 4 solubility coefficient S(CH 4 ) of higher than 15 × 10 -5 Pa·m 2 /s at 150°C.
    • 本发明提供即使包括厚的树脂管,也能够在高温高压环境下具有优异的耐起泡性的挠性管。 柔性管包括厚度大于5mm的树脂管。 树脂管由150℃下的CO 2渗透系数P(CO 2)为20×10 -9 cm 3·cm / cm 2·s·cmHg以下的树脂,10×的CH 4渗透系数P(CH 4) 在150℃下为10-9cm3·cm / cm2·s·cmHg以下,CO2扩散系数D(CO2)与CO2溶解度系数S(CO2)之比为D(CO2)/ S(CO2) 在150℃时为10 -5 Pa·m 2 / s以上,CH 4扩散系数D(CH 4)与CH 4溶解度系数S(CH 4)的比D(CH 4)/ S(CH 4) 在150℃下×10 -5 Pa·m 2 / s。