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    • 9. 发明公开
    • MIXED CARBON MATERIAL AND NEGATIVE ELECTRODE FOR NONAQUEOUS SECONDARY BATTERY
    • 不伦瑞克独立独裁者EÜKTRODEFÜREINENICHTWÄSSRIGESEKUNDÄRBATTERIE
    • EP2416413A1
    • 2012-02-08
    • EP10758555.6
    • 2010-03-26
    • Sumitomo Metal Industries, Ltd.Chuo Denki Kogyo Co., Ltd.
    • YAMAMOTO HiroshiNAGATA TatsuoFUJIWARA Tooru
    • H01M4/587C01B31/04H01M4/36
    • H01M4/587C01B32/05C01B32/20H01M4/131H01M4/1393H01M4/364H01M10/0525
    • The present invention provides a mixed carbon material which comprises carbon material A and carbon material B and which is a carbon material suitable for a negative electrode material which can provide a nonaqueous secondary battery having a low irreversible capacity and having a negative electrode with a high capacity and high charge acceptance. Carbon material A and carbon material B both have cores made of graphite powder and a surface carbon material in the form of at least one of amorphous carbon and turbostratic carbon adhered to or coated on at least a portion of the surface of the graphite powder. The compressed density is 1.80 - 1.90 g/cm 3 for carbon material A alone, 1.45 - 1.65 g/cm 3 for carbon material B alone, and 1.75 - 1.84 g/cm 3 for the mixed carbon material. The average particle diameter of carbon material B is at most 14 µm and is smaller than the average particle diameter of carbon material A. The specific surface areas of carbon material A and carbon material B are at most 4 m 2 /g and at most 6 m 2 /g, respectively.
    • 本发明提供一种混合碳材料,其包含碳材料A和碳材料B,它是适用于能够提供具有低不可逆容量的非水二次电池并具有高容量负极的负极材料的碳材料 和高充电接受度。 碳材料A和碳材料B都具有由石墨粉末制成的芯和附着在石墨粉末表面的至少一部分上的至少一种无定形碳和无机碳的形式的表面碳材料。 对于单独的碳材料A,压缩密度为1.80-1.90g / cm 3,单独碳材料B的压缩密度为1.45-1.65g / cm 3,混合碳材料的压缩密度为1.75-1.84g / cm 3。 碳材料B的平均粒径为14μm以下,比碳材A的平均粒径小。碳材料A和碳材料B的比表面积为4m 2 / g以下,6以下 m 2 / g。