会员体验
专利管家(专利管理)
工作空间(专利管理)
风险监控(情报监控)
数据分析(专利分析)
侵权分析(诉讼无效)
联系我们
交流群
官方交流:
QQ群: 891211   
微信请扫码    >>>
现在联系顾问~
热词
    • 4. 发明公开
    • Process for preparing fluorohalogenethers
    • 制备氟卤代醚的方法
    • EP1801091A2
    • 2007-06-27
    • EP06026268.0
    • 2006-12-19
    • Solvay Solexis S.p.A.
    • Tortelli, VitoCalini, PierangeloZompatori, AlbertoAntenucci, Emanuela
    • C07C41/24C07C41/06C07C43/17
    • C07C41/06C07C41/22C07C41/24C07C43/123C07C43/17
    • A process for preparing fluorovinylethers having general formula:

               R f O-CF=CF 2 ,     (IA)

      wherein R f is a fluorinated or perfluorinated alkyl or cycloalkyl substituent;
      comprising the following reaction steps:
      1) reaction of a hypofluorite of formula RfOF, wherein Rf is as above, with an olefin of formula:

               CY"Y=CY'Cl     (II)

      wherein Y, Y' and Y", equal to or different from each other, are H, Cl, Br, with the proviso that Y, Y' and Y" are not contemporaneously hydrogen;
      2) dehalogenation or dehydrohalogenation of the fluorohalogenethers obtained in step 1) and obtainment of vinyl ethers of formula:

               RfO-CY I =CY II F     (IV)

      wherein Y I and Y II , equal to or different from each other, have the meaning of H, Cl, Br with the proviso that Y I and Y II are not both H;
      3) fluorination with fluorine of the vinyl ethers (IV) and obtainment of fluorohalogenethers of formula:

               RfO-CFY I -CF 2 Y II      (I)

      wherein Y I , Y II , equal to or different from each other, are Cl, Br, H with the proviso that Y I and Y II cannot be contemporaneously equal to H;
      4) dehalogenation or dehydrohalogenation of the fluorohalogenethers (I) and obtainment of the fluorovinylethers (IA).
    • 制备具有以下通式的氟乙烯基醚的方法:RfO-CF = CF 2,(IA)其中R f是氟化或全氟化的烷基或环烷基取代基; 包括以下反应步骤:1)式RfOF的次氟酸(其中Rf如上所述)与下式的烯烃反应:其中Y,Y'和Y“等于 相互不同的是H,Cl,Br,条件是Y,Y'和Y“不同时为氢; 2)步骤1)中得到的氟卤代醚的脱卤或脱卤化氢和得到式RfO的乙烯基醚 -CYI = CYIIF(IV)其中Y1和YII彼此相同或不同,具有H,Cl,Br的含义,条件是Y1和YII不都是H; 3)用氟乙烯基醚氟化 (IV)的化合物和得到下式的氟卤代醚:RfO-CFYI-CF2YII(I)其中Y1,YII彼此相同或不同,为Cl,Br,H,条件是Y1和YII不能同时等于H ; 4)脱卤或脱水 氟卤代醚(I)的卤代卤代和氟乙烯基醚(IA)的获得。