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1. 发明授权

EP3033348B1 CATALYST SYSTEM FOR POLYMERISATION OF AN OLEFIN 有权转让
标题翻译：一种烯烃聚合催化剂体系
公开(公告)号：EP3033348B1
公开(公告)日：2017-11-29
申请号：EP14750366.8
申请日：2014-08-11
申请人： Saudi Basic Industries Corporation , SABIC Global Technologies B.V.
发明人： ZUIDEVELD, Martin Alexander , SAINANI, Jaiprakash Brijlal , PATEL, Mahendrabhai Vimalkumar
IPC分类号： C07F7/02 , C08F210/16
CPC分类号： C08F210/06 , C07F7/025 , C08F210/16 , C08F4/6465 , C08F4/6565 , C08F2500/12 , C08F2500/15
摘要： The present invention relates to a catalyst system comprising a procatalyst, a co-catalyst and an external electron donor, wherein the external electron donor comprises a compound having the structure according to Formula I: Si(L)n(OR11)4-n (Formula I), wherein, Si is a silicon atom with valency 4+; O is an oxygen atom with valency 2− and O is bonded to Si via the silicon-oxygen bond; n is 1, 2, 3 or 4; R11 is a selected from the group consisting of linear, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms; L is a group represented by (Formula II), wherein, L is bonded to the silicon atom via the nitrogen-silicon bond; L has a single substituent on the nitrogen atom, where this single substituent is an imine carbon atom; and X and Y are independently selected from the group consisting of a hydrogen atom; a heteroatom selected from group 13, 14, 15, 16 or 17 of the IUPAC Periodic Table of the Elements; a linear, branched and cyclic alkyl having at most 20 carbon atoms, optionally containing a heteroatom selected from group 13, 14, 15, 16 or 17 of the IUPAC Periodic Table of the Elements and an aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms, optionally containing a heteroatom selected from group 13, 14, 15, 16 or 7 of the IUPAC Periodic Table of the Elements.

2. 发明公开

EP3083711A1 CATALYST COMPOSITION FOR POLYMERIZATION OF OLEFINS 有权转让
标题翻译：催化剂组合物聚合烯烃
公开(公告)号：EP3083711A1
公开(公告)日：2016-10-26
申请号：EP14827215.6
申请日：2014-12-19
申请人： Saudi Basic Industries Corporation , SABIC Global Technologies B.V.
发明人： TAFTAF, Mansour , SAINANI, Jaiprakash Brijlal , ZAKHAROV, Vladimir Aleksandrovich , BUKATOV, Gennadii Dimitrievich , PATEL, Vimalkumar Mahendrabhai , SERGEEV, Sergei Andreevich , ZUIDEVELD, Martin Alexander , BATINAS-GEURTS, Aurora Alexandra , GHALIT, Nourdin
IPC分类号： C08F4/651 , C08F110/06 , C07C233/69 , C08F4/656
CPC分类号： C07C233/69 , B01J31/0202 , B01J2231/64 , B01J2531/007 , C07C233/18 , C07C235/48 , C08F110/06 , C08F2410/01 , C08F4/651 , C08F2500/04 , C08F2500/12 , C08F2500/15 , C08F4/6565
摘要： The present invention relates to a catalyst composition comprising the compound represented by Formula (I) as an internal electron donor, Formula I wherein: R1, R2, R3, R4, R5 and R6 are the same or different and are independently selected from a group consisting of hydrogen, straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; R7 is selected from a group consisting of straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; and R8 is selected from a group consisting of aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms; N is nitrogen atom; O is oxygen atom; and C is carbon atom. The present invention also relates to a process for preparing said polymerization catalyst composition and to a polymerization catalyst system comprising said catalyst composition, a co-catalyst and optionally an external electron donor. Furthermore, the present invention relates to a polyolefin obtainable by the process according to the present invention and to the use of the compound of Formula I as in internal electron donor in catalysts for polymerization of olefins.

3. 发明公开

EP3033348A1 CATALYST SYSTEM FOR POLYMERISATION OF AN OLEFIN 有权转让
标题翻译：热塑性聚氨酯润滑油
公开(公告)号：EP3033348A1
公开(公告)日：2016-06-22
申请号：EP14750366.8
申请日：2014-08-11
申请人： Saudi Basic Industries Corporation , SABIC Global Technologies B.V.
发明人： ZUIDEVELD, Martin Alexander , SAINANI, Jaiprakash Brijlal , VIMALKUMAR, Mahendrabhai Patel
IPC分类号： C07F7/02 , C08F210/16
CPC分类号： C08F210/06 , C07F7/025 , C08F210/16 , C08F4/6465 , C08F4/6565 , C08F2500/12 , C08F2500/15
摘要： The present invention relates to a catalyst system comprising a procatalyst, a co-catalyst and an external electron donor, wherein the external electron donor comprises a compound having the structure according to Formula I: Si(L)n(OR11)4-n (Formula I), wherein, Si is a silicon atom with valency 4+; O is an oxygen atom with valency 2− and O is bonded to Si via the silicon-oxygen bond; n is 1, 2, 3 or 4; R11 is a selected from the group consisting of linear, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms; L is a group represented by (Formula II), wherein, L is bonded to the silicon atom via the nitrogen-silicon bond; L has a single substituent on the nitrogen atom, where this single substituent is an imine carbon atom; and X and Y are independently selected from the group consisting of a hydrogen atom; a heteroatom selected from group 13, 14, 15, 16 or 17 of the IUPAC Periodic Table of the Elements; a linear, branched and cyclic alkyl having at most 20 carbon atoms, optionally containing a heteroatom selected from group 13, 14, 15, 16 or 17 of the IUPAC Periodic Table of the Elements and an aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms, optionally containing a heteroatom selected from group 13, 14, 15, 16 or 7 of the IUPAC Periodic Table of the Elements.
摘要翻译：本发明涉及包含前催化剂，助催化剂和外电子给体的催化剂体系，其中外电子给体包括具有式I结构的化合物：Si（L）n（OR 11）4-n 式I），其中Si是价态为4+的硅原子; O是具有2-价的氧原子，O通过硅 - 氧键与Si键合; n为1,2,3或4; R11选自具有至多20个碳原子的直链，支链和环状烷基和具有6至20个碳原子的芳族取代和未取代的烃基; L是由式（II）表示的基团，其中L通过氮 - 硅键与硅原子键合; L在氮原子上具有单个取代基，其中该单个取代基是亚胺碳原子; X和Y独立地选自氢原子; 选自IUPAC元素周期表第13,14,15,16或17族的杂原子; 含有至多20个碳原子的直链，支链和环状烷基，任选地含有选自元素周期表IUPAC元素周期表第13,14,15,16或17族的杂原子和具有6至20个碳原子的芳族取代和未取代的烃基原子，任选地含有选自元素周期表IUPAC的第13,14,15,16或7族的杂原子。

4. 发明公开

EP2951215A1 PROCESS FOR PREPARING A CATALYST COMPONENT FOR POLYMERIZATION OF OLEFINS 有权
标题翻译：一种用于生产催化剂组分的烯烃聚合
公开(公告)号：EP2951215A1
公开(公告)日：2015-12-09
申请号：EP14701555.6
申请日：2014-01-28
申请人： Saudi Basic Industries Corporation
发明人： TAFTAF, Mansour , SAINANI, Jaiprakash Brijlal , ZAKHAROV, Vladimir Aleksandrovich , BUKATOV, Gennadii Dimitrievich , VIMALKUMAR, Mahendrabhai Patel , SERGEEV, Sergei Andreevich , ZUIDEVELD, Martin Alexander , BATINAS-GEURTS, Aurora Alexandra
IPC分类号： C08F10/00 , C08F4/656
CPC分类号： C08F110/06 , C07C233/18 , C07C233/23 , C07C233/69 , C07C2601/14 , C08F4/649 , C08F4/6546 , C08F4/655 , C08F10/06 , C08F10/00 , C08F4/6565 , C08F4/651 , C08F2500/04 , C08F2500/12 , C08F2500/24
摘要： A catalyst composition comprising a monoester, the compound represented by formula (I) as an internal electron donor, and optionally an additional internal electron donor selected from a group consisting of diesters and diethers, wherein: R1, R2, R3, R4, R5 and R6 are hydrogen, straight, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms, R7 is a straight, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms, and R8 is an aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms. Also described is a process for preparing the polymerization catalyst composition, a polymerization catalyst system comprising the catalyst composition, a co-catalyst and optionally an external electron donor; and use of the catalyst system for polymerization of olefins.
摘要翻译：本发明涉及一种用于制备催化剂组分的烯烃，包括以下步骤的聚合：i）使化合物R9zMgXz2-Z worin R9是芳族的，脂族或环脂族含最多20个碳原子基团，X是卤化物，和z是在一个范围内的大于0在烷氧基 - 或硅烷化合物磅到给定的第一中间反应产物含aryloky-以上且小于2，用; ii）将第一中间反应产物与至少一种活化从由式M的电子供体和化合物形成的组中选择的化合物（OR 10）VW（OR 11）瓦特，worin M可以是钛，锆，HI，铝或Si 和M（OR 10）VW（R11）W，worin M为Si，R10和R11各自，unabhängig，代表烷基，烯基或芳基，v是M的化合价，v为3或4，w是较小大于v，得到第二中间反应产物; 和iii）接触与含卤素的钛化合物的第二中间反应产物，单酯作为活化剂，1,3-二醚作为内给电子体，以及任选的二酯作为附加的内部电子供体。

5. 发明公开

EP2951214A1 CATALYST COMPOSITION FOR POLYMERIZATION OF OLEFINS 有权
标题翻译：用于烯烃聚合的催化剂组合物
公开(公告)号：EP2951214A1
公开(公告)日：2015-12-09
申请号：EP14701554.9
申请日：2014-01-28
申请人： Saudi Basic Industries Corporation
发明人： TAFTAF, Mansour , SAINANI, Jaiprakash Brijlal , ZAKHAROV, Vladimir Aleksandrovich , BUKATOV, Gennadii Dimitrievich , VIMALKUMAR, Mahendrabhai Patel , SERGEEV, Sergei Andreevich , ZUIDEVELD, Martin Alexander , BATINAS-GEURTS, Aurora Alexandra
IPC分类号： C08F10/00 , C08F4/656 , C08F4/651
CPC分类号： C08F110/06 , C07C233/18 , C07C233/23 , C07C233/69 , C07C2601/14 , C08F4/649 , C08F4/6546 , C08F4/655 , C08F10/06 , C08F10/00 , C08F4/6565 , C08F4/651 , C08F2500/04 , C08F2500/12 , C08F2500/24
摘要： A catalyst composition comprising a monoester, the compound represented by formula (I) as an internal electron donor, and optionally an additional internal electron donor selected from a group consisting of diesters and diethers, wherein: R1, R2, R3, R4, R5 and R6 are hydrogen, straight, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms, R7 is a straight, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms, and R8 is an aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms. Also described is a process for preparing the polymerization catalyst composition, a polymerization catalyst system comprising the catalyst composition, a co-catalyst and optionally an external electron donor; and use of the catalyst system for polymerization of olefins.
摘要翻译：本发明涉及一种催化剂组合物，其包含单酯，由式（I）表示的化合物作为内电子给体，并且任选地包含选自二酯和二醚的另外的内电子给体，式（I）其中：R 1，R 2，R 3，R 4，R 5和R 6相同或不同，并且独立地选自氢，具有至多20个碳原子的直链，支链和环状烷基和芳族取代和未取代的烃基具有6至20个碳原子; R 7选自具有至多20个碳原子的直链，支链和环状烷基和具有6-20个碳原子的芳族取代和未取代的烃基; 并且R 8选自具有6至20个碳原子的芳族取代和未取代的烃基。本发明还涉及制备所述聚合催化剂组合物的方法和涉及包含所述催化剂组合物，助催化剂和任选的外电子给体的聚合催化剂体系。此外，本发明涉及所述催化剂组合物用于烯烃聚合的用途。

6. 发明公开

EP2867264A1 CATALYST COMPOSITION FOR POLYMERIZATION OF OLEFINS 有权
标题翻译：催化剂组合物聚合烯烃
公开(公告)号：EP2867264A1
公开(公告)日：2015-05-06
申请号：EP13730590.0
申请日：2013-06-24
申请人： Saudi Basic Industries Corporation
发明人： TAFTAF, Mansour , ZUIDEVELD, Martin Alexander , BATINAS-GEURTS, Aurora Alexandra , SAINANI, Jaiprakash Brijlal , VIMALKUMAR, Mahendrabhai Patel , ZAKHAROV, Vladimir Aleksandrovich , BUKATOV, Gennadii Dimitrievich , SERGEEV, Sergei Andreevich , GHALIT, Nourdin
IPC分类号： C08F110/06 , C08F10/06 , C08F4/651
CPC分类号： C08F110/06 , C07C233/18 , C07C233/69 , C07C235/48 , C07C2101/14 , C07C2601/14 , C07C2601/16 , C08F10/06 , C08F2500/04 , C08F2500/12 , C08F2500/15 , C08F4/651 , C08F4/6465 , C08F4/6565
摘要： The present invention relates to a catalyst composition comprising the compound represented by the Fischer projection of formula (I) as an internal electron donor, (I) wherein: R
1 , R
2 , R
3 , R
4 , R
5 and R
6 are the same or different and are independently selected from a group consisting of hydrogen, straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; R
7 is selected from a group consisting of straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; and R
8 is selected from a group consisting of aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms; N is nitrogen atom; O is oxygen atom; and C is carbon atom. The present invention also relates to a process for preparing said polymerization catalyst composition and to a polymerization catalyst system comprising said catalyst composition, a cocatalyst and optionally an external electron donor. Furthermore, the present invention relates to a polyolefin obtainable by the process according to the present invention and to the use of the compound of formula (I) as in internal electron donor in catalysts for polymerization of olefins.

7. 发明授权

EP2951215B1 PROCESS FOR PREPARING A CATALYST COMPONENT FOR POLYMERIZATION OF OLEFINS 有权
公开(公告)号：EP2951215B1
公开(公告)日：2018-10-10
申请号：EP14701555.6
申请日：2014-01-28
申请人： Saudi Basic Industries Corporation
发明人： TAFTAF, Mansour , SAINANI, Jaiprakash Brijlal , ZAKHAROV, Vladimir Aleksandrovich , BUKATOV, Gennadii Dimitrievich , VIMALKUMAR, Mahendrabhai Patel , SERGEEV, Sergei Andreevich , ZUIDEVELD, Martin Alexander , BATINAS-GEURTS, Aurora Alexandra
IPC分类号： C08F10/00 , C08F4/656
CPC分类号： C08F110/06 , C07C233/18 , C07C233/23 , C07C233/69 , C07C2601/14 , C08F4/649 , C08F4/6546 , C08F4/655 , C08F10/06 , C08F10/00 , C08F4/6565 , C08F4/651 , C08F2500/04 , C08F2500/12 , C08F2500/24
摘要： A catalyst composition comprising a monoester, the compound represented by formula (I) as an internal electron donor, and optionally an additional internal electron donor selected from a group consisting of diesters and diethers, wherein: R1, R2, R3, R4, R5 and R6 are hydrogen, straight, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms, R7 is a straight, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms, and R8 is an aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms. Also described is a process for preparing the polymerization catalyst composition, a polymerization catalyst system comprising the catalyst composition, a co-catalyst and optionally an external electron donor; and use of the catalyst system for polymerization of olefins.

8. 发明公开

EP2800752A1 METHOD FOR PREPARING DI-ORGANO-DIALKOXYSILANES 有权
标题翻译：制备二有机二烷氧基硅烷的方法
公开(公告)号：EP2800752A1
公开(公告)日：2014-11-12
申请号：EP12813282.6
申请日：2012-12-20
申请人： Saudi Basic Industries Corporation
发明人： SAINANI, Jaiprakash Brijlal , VIMALKUMAR, Mahendrabhai Patel , DAVADRA, Mahesh
IPC分类号： C07F7/18
CPC分类号： C07F7/1876 , C07F7/1888
摘要： The present invention relates to a method for preparing di-organo-dialkoxysilanes, in particular di-organo-dialkoxysilanes wherein one or both of the organic substituents are bulky. The method comprises reacting a tetraalkoxysilane compound with a first Grignard reagent to form a mono-organo-tri-alkoxysilane compound, which is then reacted with a chlorinating agent to form a chlorinated mono-organo-di-alkoxysilane which is then reacted with a second Grignard reagent to form the di-organo-di-alkoxysilane compound.
摘要翻译：本发明涉及制备二有机二烷氧基硅烷的方法，特别是其中一个或两个有机取代基体积庞大的二有机二烷氧基硅烷。该方法包括使四烷氧基硅烷化合物与第一格利雅试剂反应以形成单有机三烷氧基硅烷化合物，然后使其与氯化剂反应形成氯化单有机二烷氧基硅烷，然后使其与第二格利雅试剂以形成二有机二烷氧基硅烷化合物。

10. 发明授权

EP2751059B1 PROCESS FOR PREPARING DI-SUBSTITUTED SUCCINATES 有权
标题翻译：用于生产二取代丁二酸
公开(公告)号：EP2751059B1
公开(公告)日：2015-09-16
申请号：EP12753071.5
申请日：2012-08-23
申请人： Saudi Basic Industries Corporation
发明人： SAINANI, Jaiprakash Brijlal , DAVADRA, Mahesh
IPC分类号： C07C51/38 , C07C55/02 , C07C57/34 , C07C51/09 , C07C55/22 , C07C67/343 , C07C69/34 , C07C69/612 , C07C67/08 , C07C69/40
CPC分类号： C08F4/76 , C07C51/09 , C07C67/08 , C07C67/343 , C07C69/34 , C07C69/618 , C07C57/34 , C07C55/02

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