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2. 发明授权

EP2791188B1 A PROCESS FOR THE PRODUCTION OF BIMODAL POLYETHYLENE IN THE PRESENCE OF THIS CATALYST SYSTEM 有权
标题翻译：在该催化剂体系存在下生产双峰聚乙烯的方法
公开(公告)号：EP2791188B1
公开(公告)日：2018-04-04
申请号：EP12798162.9
申请日：2012-12-06
申请人： Saudi Basic Industries Corporation
发明人： BATINAS-GEURTS, Aurora Alexandra , FRIEDERICHS, Nicolaas Hendrika , SCHOFFELEN, Tom , ZUIDEMA, Erik , GARG, Priya
IPC分类号： C08F210/16 , C08F2/00 , C08F4/651 , C08F4/649 , C08F4/655 , C08F210/08
CPC分类号： C08F110/02 , C08F210/16 , C08F4/651 , C08F4/6494 , C08F4/6555 , C08F2500/04 , C08F2500/12 , C08F2/001 , C08F210/08 , C08F2500/07
摘要： The invention relates to a process for the production of bimodal polyethylene in a two-step polymerization process in the presence of a catalyst system comprising: (I) the solid reaction product obtained by reacting of: a) a hydrocarbon solution containing 1) an organic oxygen containing magnesium compound or a halogen containing magnesium compound and 2) an organic oxygen containing titanium compound and b) an aluminum halogenide having the formula AIRnX3-n in which R is a hydrocarbon radical containing 1-10 carbon atoms, X is halogen and 0

3. 发明公开

EP3083721A1 CATALYST SYSTEM FOR POLYMERISATION OF AN OLEFIN 有权转让
标题翻译：一种烯烃聚合催化剂体系
公开(公告)号：EP3083721A1
公开(公告)日：2016-10-26
申请号：EP14815741.5
申请日：2014-12-19
申请人： Saudi Basic Industries Corporation , SABIC Global Technologies B.V.
发明人： BATINAS-GEURTS, Aurora Alexandra , ZUIDEVELD, Martin Alexander , SMEETS, Bobby Johannes Henricus Hubertus
IPC分类号： C08F210/16 , C08F4/646 , C08F4/656
CPC分类号： C08F210/06 , C08F10/06 , C08F210/16 , C08F4/6495 , C08F4/6465 , C08F4/6565 , C08F2500/12
摘要： The invention relates to a process for preparing a catalyst system suitable for olefin polymerization. The present invention further relates to a catalyst system obtainable by such process. In addition, the invention relates to a polyolefin. The invention also relates to ashaped article. The catalyst system comprises a procatalyst, a co-catalyst and optionally at least one external electron donor.
摘要翻译：本发明涉及制备适用于烯烃聚合的催化剂体系的方法。本发明还涉及通过这种方法可获得的催化剂体系。另外，本发明涉及聚烯烃。本发明还涉及成形物品。该催化剂体系包含前催化剂，助催化剂和任选的至少一种外电子给体。

4. 发明公开

EP2951215A1 PROCESS FOR PREPARING A CATALYST COMPONENT FOR POLYMERIZATION OF OLEFINS 有权
标题翻译：一种用于生产催化剂组分的烯烃聚合
公开(公告)号：EP2951215A1
公开(公告)日：2015-12-09
申请号：EP14701555.6
申请日：2014-01-28
申请人： Saudi Basic Industries Corporation
发明人： TAFTAF, Mansour , SAINANI, Jaiprakash Brijlal , ZAKHAROV, Vladimir Aleksandrovich , BUKATOV, Gennadii Dimitrievich , VIMALKUMAR, Mahendrabhai Patel , SERGEEV, Sergei Andreevich , ZUIDEVELD, Martin Alexander , BATINAS-GEURTS, Aurora Alexandra
IPC分类号： C08F10/00 , C08F4/656
CPC分类号： C08F110/06 , C07C233/18 , C07C233/23 , C07C233/69 , C07C2601/14 , C08F4/649 , C08F4/6546 , C08F4/655 , C08F10/06 , C08F10/00 , C08F4/6565 , C08F4/651 , C08F2500/04 , C08F2500/12 , C08F2500/24
摘要： A catalyst composition comprising a monoester, the compound represented by formula (I) as an internal electron donor, and optionally an additional internal electron donor selected from a group consisting of diesters and diethers, wherein: R1, R2, R3, R4, R5 and R6 are hydrogen, straight, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms, R7 is a straight, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms, and R8 is an aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms. Also described is a process for preparing the polymerization catalyst composition, a polymerization catalyst system comprising the catalyst composition, a co-catalyst and optionally an external electron donor; and use of the catalyst system for polymerization of olefins.
摘要翻译：本发明涉及一种用于制备催化剂组分的烯烃，包括以下步骤的聚合：i）使化合物R9zMgXz2-Z worin R9是芳族的，脂族或环脂族含最多20个碳原子基团，X是卤化物，和z是在一个范围内的大于0在烷氧基 - 或硅烷化合物磅到给定的第一中间反应产物含aryloky-以上且小于2，用; ii）将第一中间反应产物与至少一种活化从由式M的电子供体和化合物形成的组中选择的化合物（OR 10）VW（OR 11）瓦特，worin M可以是钛，锆，HI，铝或Si 和M（OR 10）VW（R11）W，worin M为Si，R10和R11各自，unabhängig，代表烷基，烯基或芳基，v是M的化合价，v为3或4，w是较小大于v，得到第二中间反应产物; 和iii）接触与含卤素的钛化合物的第二中间反应产物，单酯作为活化剂，1,3-二醚作为内给电子体，以及任选的二酯作为附加的内部电子供体。

5. 发明公开

EP2951214A1 CATALYST COMPOSITION FOR POLYMERIZATION OF OLEFINS 有权
标题翻译：用于烯烃聚合的催化剂组合物
公开(公告)号：EP2951214A1
公开(公告)日：2015-12-09
申请号：EP14701554.9
申请日：2014-01-28
申请人： Saudi Basic Industries Corporation
发明人： TAFTAF, Mansour , SAINANI, Jaiprakash Brijlal , ZAKHAROV, Vladimir Aleksandrovich , BUKATOV, Gennadii Dimitrievich , VIMALKUMAR, Mahendrabhai Patel , SERGEEV, Sergei Andreevich , ZUIDEVELD, Martin Alexander , BATINAS-GEURTS, Aurora Alexandra
IPC分类号： C08F10/00 , C08F4/656 , C08F4/651
CPC分类号： C08F110/06 , C07C233/18 , C07C233/23 , C07C233/69 , C07C2601/14 , C08F4/649 , C08F4/6546 , C08F4/655 , C08F10/06 , C08F10/00 , C08F4/6565 , C08F4/651 , C08F2500/04 , C08F2500/12 , C08F2500/24
摘要： A catalyst composition comprising a monoester, the compound represented by formula (I) as an internal electron donor, and optionally an additional internal electron donor selected from a group consisting of diesters and diethers, wherein: R1, R2, R3, R4, R5 and R6 are hydrogen, straight, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms, R7 is a straight, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms, and R8 is an aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms. Also described is a process for preparing the polymerization catalyst composition, a polymerization catalyst system comprising the catalyst composition, a co-catalyst and optionally an external electron donor; and use of the catalyst system for polymerization of olefins.
摘要翻译：本发明涉及一种催化剂组合物，其包含单酯，由式（I）表示的化合物作为内电子给体，并且任选地包含选自二酯和二醚的另外的内电子给体，式（I）其中：R 1，R 2，R 3，R 4，R 5和R 6相同或不同，并且独立地选自氢，具有至多20个碳原子的直链，支链和环状烷基和芳族取代和未取代的烃基具有6至20个碳原子; R 7选自具有至多20个碳原子的直链，支链和环状烷基和具有6-20个碳原子的芳族取代和未取代的烃基; 并且R 8选自具有6至20个碳原子的芳族取代和未取代的烃基。本发明还涉及制备所述聚合催化剂组合物的方法和涉及包含所述催化剂组合物，助催化剂和任选的外电子给体的聚合催化剂体系。此外，本发明涉及所述催化剂组合物用于烯烃聚合的用途。

6. 发明公开

EP2867264A1 CATALYST COMPOSITION FOR POLYMERIZATION OF OLEFINS 有权
标题翻译：催化剂组合物聚合烯烃
公开(公告)号：EP2867264A1
公开(公告)日：2015-05-06
申请号：EP13730590.0
申请日：2013-06-24
申请人： Saudi Basic Industries Corporation
发明人： TAFTAF, Mansour , ZUIDEVELD, Martin Alexander , BATINAS-GEURTS, Aurora Alexandra , SAINANI, Jaiprakash Brijlal , VIMALKUMAR, Mahendrabhai Patel , ZAKHAROV, Vladimir Aleksandrovich , BUKATOV, Gennadii Dimitrievich , SERGEEV, Sergei Andreevich , GHALIT, Nourdin
IPC分类号： C08F110/06 , C08F10/06 , C08F4/651
CPC分类号： C08F110/06 , C07C233/18 , C07C233/69 , C07C235/48 , C07C2101/14 , C07C2601/14 , C07C2601/16 , C08F10/06 , C08F2500/04 , C08F2500/12 , C08F2500/15 , C08F4/651 , C08F4/6465 , C08F4/6565
摘要： The present invention relates to a catalyst composition comprising the compound represented by the Fischer projection of formula (I) as an internal electron donor, (I) wherein: R
1 , R
2 , R
3 , R
4 , R
5 and R
6 are the same or different and are independently selected from a group consisting of hydrogen, straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; R
7 is selected from a group consisting of straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; and R
8 is selected from a group consisting of aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms; N is nitrogen atom; O is oxygen atom; and C is carbon atom. The present invention also relates to a process for preparing said polymerization catalyst composition and to a polymerization catalyst system comprising said catalyst composition, a cocatalyst and optionally an external electron donor. Furthermore, the present invention relates to a polyolefin obtainable by the process according to the present invention and to the use of the compound of formula (I) as in internal electron donor in catalysts for polymerization of olefins.

7. 发明公开

EP3083711A1 CATALYST COMPOSITION FOR POLYMERIZATION OF OLEFINS 有权转让
标题翻译：催化剂组合物聚合烯烃
公开(公告)号：EP3083711A1
公开(公告)日：2016-10-26
申请号：EP14827215.6
申请日：2014-12-19
申请人： Saudi Basic Industries Corporation , SABIC Global Technologies B.V.
发明人： TAFTAF, Mansour , SAINANI, Jaiprakash Brijlal , ZAKHAROV, Vladimir Aleksandrovich , BUKATOV, Gennadii Dimitrievich , PATEL, Vimalkumar Mahendrabhai , SERGEEV, Sergei Andreevich , ZUIDEVELD, Martin Alexander , BATINAS-GEURTS, Aurora Alexandra , GHALIT, Nourdin
IPC分类号： C08F4/651 , C08F110/06 , C07C233/69 , C08F4/656
CPC分类号： C07C233/69 , B01J31/0202 , B01J2231/64 , B01J2531/007 , C07C233/18 , C07C235/48 , C08F110/06 , C08F2410/01 , C08F4/651 , C08F2500/04 , C08F2500/12 , C08F2500/15 , C08F4/6565
摘要： The present invention relates to a catalyst composition comprising the compound represented by Formula (I) as an internal electron donor, Formula I wherein: R1, R2, R3, R4, R5 and R6 are the same or different and are independently selected from a group consisting of hydrogen, straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; R7 is selected from a group consisting of straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; and R8 is selected from a group consisting of aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms; N is nitrogen atom; O is oxygen atom; and C is carbon atom. The present invention also relates to a process for preparing said polymerization catalyst composition and to a polymerization catalyst system comprising said catalyst composition, a co-catalyst and optionally an external electron donor. Furthermore, the present invention relates to a polyolefin obtainable by the process according to the present invention and to the use of the compound of Formula I as in internal electron donor in catalysts for polymerization of olefins.

9. 发明公开

EP2817344A1 CATALYST COMPONENT FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译： KATALYSATORFÜRDIE POLYMERISIERUNG VON OLEFINEN
公开(公告)号：EP2817344A1
公开(公告)日：2014-12-31
申请号：EP13706429.1
申请日：2013-02-21
申请人： Saudi Basic Industries Corporation
发明人： TAFTAF, Mansour , GHALIT, Nourdin , BUKATOV, Gennadii Dimitrievich , SERGEEV, Sergei Andreevich , ZAKHAROV, Vladimir Aleksandrovich , SAINANI, Jaiprakash Brijlal , BATINAS-GEURTS, Aurora Alexandra
IPC分类号： C08F110/06 , C08F4/651 , C08F4/656 , C08F10/00
CPC分类号： C08F110/06 , C08F10/00 , C08F4/651 , C08F4/6565
摘要： The present invention relates to a catalyst component for polymerization of an olefin comprising a compound represented by the Fischer projection of: wherein R
5 is substituted or unsubstituted hydrocarbyl having 1 to 20 carbon atoms; R
6 and R
7 are different and independently selected from the group consisting of hydrogen, halogen and substituted or unsubstituted hydrocarbyl having 1 to 20 carbon atoms; R
5 -R
7 optionally containing one or more hetero-atoms replacing one or more carbon atoms, one or more hydrogen atom or both, wherein said hetero-atom is selected from the group consisting of nitrogen, oxygen, sulfur, silicon, phosphorus and halogen; and wherein the compound of Formula (I) is the only internal electron donor in the catalyst component. The present invention also relates to a process for preparing a polymerization catalyst component comprising the steps of i) contacting a compound R
4
z MgX
2-z wherein R
4 is aromatic, aliphatic or cyclo-aliphatic group containing 1 to 20 carbon atoms, X is a halide, and z is in a range of larger than 0 and smaller than 2, with an alkoxy- or aryloxy-containing silane compound to give a first intermediate reaction product; ii) contacting the first intermediate reaction product with at least one activating compound selected from the group formed by internal electron donors and compounds of formula M(OR
2 )
v-w (R
3 )
w , wherein M can be Ti, Zr, Hf, Al or Si, each R
2 and R
3 , independently, represent an alkyl, alkenyl or aryl group, v is the valency of M and w is smaller than v and iii) contacting the second intermediate reaction product with a halogen-containing Ti- compound and an internal electron donor represented by the Fischer projection of formula (I); and optionally with at least one compound selected from a group comprising a monoester, a diester and a 1,3-diether.
摘要翻译：本发明涉及一种用于聚合烯烃的催化剂组分，其包含由Fischer投影表示的化合物：其中R5是取代或未取代的具有1至20个碳原子的烃基; R6和R7不同且独立地选自氢，卤素和取代或未取代的具有1至20个碳原子的烃基; 任选地含有一个或多个取代一个或多个碳原子的杂原子，一个或多个氢原子或两者的R 5 -R 7，其中所述杂原子选自氮，氧，硫，硅，磷和卤素; 并且其中式（I）的化合物是催化剂组分中唯一的内电子给体。本发明还涉及一种制备聚合催化剂组分的方法，包括以下步骤：i）使化合物R4zMgX2-z与其中R4是芳族的，含有1至20个碳原子的脂族或环脂族基团，X是卤化物，和 z为大于0且小于2的范围，与含烷氧基或芳氧基的硅烷化合物反应得到第一中间反应产物; ii）使第一中间反应产物与至少一种活化化合物接触，所述活化化合物选自内电子给体和式M（OR2）vw（R3）w化合物，其中M可以是Ti，Zr，Hf，Al或Si 每个R 2和R 3独立地表示烷基，烯基或芳基，v是M的化合价，w小于v，和iii）使第二中间反应产物与含卤素的Ti化合物和内部电子由式（I）的费舍尔投影表示的供体; 和任选地与至少一种选自包含单酯，二酯和1,3-二醚的化合物。

10. 发明授权

EP2951215B1 PROCESS FOR PREPARING A CATALYST COMPONENT FOR POLYMERIZATION OF OLEFINS 有权
公开(公告)号：EP2951215B1
公开(公告)日：2018-10-10
申请号：EP14701555.6
申请日：2014-01-28
申请人： Saudi Basic Industries Corporation
发明人： TAFTAF, Mansour , SAINANI, Jaiprakash Brijlal , ZAKHAROV, Vladimir Aleksandrovich , BUKATOV, Gennadii Dimitrievich , VIMALKUMAR, Mahendrabhai Patel , SERGEEV, Sergei Andreevich , ZUIDEVELD, Martin Alexander , BATINAS-GEURTS, Aurora Alexandra
IPC分类号： C08F10/00 , C08F4/656
CPC分类号： C08F110/06 , C07C233/18 , C07C233/23 , C07C233/69 , C07C2601/14 , C08F4/649 , C08F4/6546 , C08F4/655 , C08F10/06 , C08F10/00 , C08F4/6565 , C08F4/651 , C08F2500/04 , C08F2500/12 , C08F2500/24
摘要： A catalyst composition comprising a monoester, the compound represented by formula (I) as an internal electron donor, and optionally an additional internal electron donor selected from a group consisting of diesters and diethers, wherein: R1, R2, R3, R4, R5 and R6 are hydrogen, straight, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms, R7 is a straight, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms, and R8 is an aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms. Also described is a process for preparing the polymerization catalyst composition, a polymerization catalyst system comprising the catalyst composition, a co-catalyst and optionally an external electron donor; and use of the catalyst system for polymerization of olefins.

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