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1. 发明公开

EP0226453A2 Polyolefin composition 失效
标题翻译：聚烯烃组合物
公开(公告)号：EP0226453A2
公开(公告)日：1987-06-24
申请号：EP86309610.3
申请日：1986-12-10
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Fukui, Yoshiharu , Koyama, Teruhisa , Kuroda, Kazuhisa
IPC分类号： C08K5/00 , C08L23/02
CPC分类号： C08K5/00 , C08K5/527 , C08L23/02
摘要： A polyolefin composition contains (1) from 0.01 to 1.0 part by weight of tris(3,5-di-t-butyl-4-hydroxybenzyl)-isocyanurate, (2) from 0.01 to 0.5 part by weight of a pentaerythritol diphosphite compound represented by the formula:
where R, represents a methyl group, a tertiary butyl group or a tertiary amyl group, R 2 represents a hydrogen atom, a methyl group, a tertiary butyl group, a tertiary amyl group, a phenyl group or a cyclohexyl group, R 3 represents a hydrogen atom, a methyl group or a tertiary butyl group and R 4 represents a hydrogen atom, a methyl group or a tertiary butyl group, provided that not all of R 2 , R 3 and R 4 simultaneously represent hydrogen atoms, (3) from 0.01 to 1.0 part by weight of one compound selected from phenyl benzoate compounds, benzotriazole compounds and benzophenone compounds and (4) from 0.01 to 1.0 part by weight of a heterocyclic hindered amine compound which are blended with 100 parts by weight of a polyolefin. Extremely excellent light stability, particularly, at high temperature is obtained.
摘要翻译：聚烯烃组合物含有（1）0.01至1.0重量份的三（3,5-二叔丁基-4-羟基苄基） - 异氰脲酸酯，（2）0.01至0.5重量份的代表性的季戊四醇二亚磷酸酯化合物由下式表示：其中R 1代表甲基，叔丁基或叔戊基，R 2代表氢原子，甲基，叔丁基，叔戊基，苯基或环己基， R3表示氢原子，甲基或叔丁基，R4表示氢原子，甲基或叔丁基，条件是R2，R3和R4不全部同时表示氢原子，（3）0.01 1.0重量份的选自苯甲酸苯酯化合物，苯并三唑化合物和二苯甲酮化合物中的一种化合物和（4）0.01-1.0重量份的与100重量份聚烯烃共混的杂环位阻胺化合物。获得极其优异的光稳定性，特别是在高温下。

2. 发明公开

EP0172646A1 Stretched multilayer polypropylene films 失效
标题翻译：聚丙烯多层拉伸膜。
公开(公告)号：EP0172646A1
公开(公告)日：1986-02-26
申请号：EP85304988.0
申请日：1985-07-12
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Kakugo, Masahiro , Fukui, Yoshiharu , Wakatsuki, Kizuku , Ima, Seiichiro , Kimura, Junichi
IPC分类号： C09J3/14 , B32B27/32
CPC分类号： B32B27/32 , B32B27/08 , B32B2307/31 , B32B2307/704 , B32B2323/10 , C09J7/22 , C09J7/35 , C09J123/0815 , C09J123/142 , Y10S428/91 , Y10T428/2826
摘要： A stretched multilayer polypropylene film comprises a stretched crystalline polypropylene layer having laminated on at least one side thereof, a layer comprising a homo- or co-polymer composed mainly of ethylene, propylene or butene-1 and having a melting point of 150°C or less, and 0.05 wt ppm to 10 wt% calculated as vinylcycloalkane units of a vinylcycloalkane polymer, particularly vinylcyclohexane. This composite film has greatly improved optical properties such as transparency without loss of its good heat sealability, and is very useful for wrapping.

3. 发明公开

EP0407198A1 Food container 失效
标题翻译： Nahrungsmittelbehälter。
公开(公告)号：EP0407198A1
公开(公告)日：1991-01-09
申请号：EP90307370.8
申请日：1990-07-05
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Fukui, Yoshiharu , Kuroda, Kazuhisa
IPC分类号： B65D85/00 , C08L23/02 , C08K13/02
CPC分类号： C08K5/17 , C08K5/15 , C08K13/02 , C08L23/02
摘要： Disclosed herein is a food container of a resin composition composed of a polyolefin and an inorganic filler, said resin composition containing (i) a phenolic antioxidant and (ii) a slip agent and/or antistatic agent, said phenolic antioxidant being at least one kind selected from β-(4-hydroxy-3-t-butyl-5-alkylphenyl)propionic acid esters, hindered phenols having an isocyanuric acid ester, 1,3,5-tris(3,5-di-t-butyl-4-hydroxybenzyl)-2,4,6-trimethylbenzene, specific phenol compounds, and 6-hydroxychroman compounds. The food container has a low level of offensive odors and discoloration.
摘要翻译：本发明公开了一种由聚烯烃和无机填料构成的树脂组合物的食品容器，所述树脂组合物含有（i）酚类抗氧化剂和（ii）增滑剂和/或抗静电剂，所述酚类抗氧化剂为至少一种选自β-（4-羟基-3-叔丁基-5-烷基苯基）丙酸酯，具有异氰脲酸酯的受阻酚，1,3,5-三（3,5-二叔丁基-4 - 羟基苄基）-2,4,6-三甲基苯，特异性酚化合物和6-羟基苯并二氢吡喃化合物。食物容器具有低水平的恶臭和变色。

4. 发明授权

EP0021753B1 Method for production of highly crystalline olefin polymers 失效
标题翻译：生产高粘度烯烃聚合物的方法
公开(公告)号：EP0021753B1
公开(公告)日：1984-03-14
申请号：EP80302004.9
申请日：1980-06-16
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Shiga, Akinobu , Fukui, Yoshiharu , Sasaki, Toshio , Okawa, Masahisa , Matsuura, Hideaki
IPC分类号： C08F10/00 , C08F4/64
CPC分类号： C08F10/00 , C08F4/643 , C08F4/642

5. 发明公开

EP0034935A1 Titanium trichloride catalyst and process for production of alpha-olefin polymers 失效
标题翻译： Titan-trichlorid-Katalysator和Verfahren zur Herstellung von alpha-Olefinpolymeren。
公开(公告)号：EP0034935A1
公开(公告)日：1981-09-02
申请号：EP81300733.3
申请日：1981-02-20
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Shiga, Akinobu , Fukui, Yoshiharu , Sasaki, Toshio , Hideaki, Matsuura , Yoshioka, Hiroshi
IPC分类号： C08F10/00 , C08F4/64
CPC分类号： C08F10/00 , C08F4/655 , C08F4/651
摘要： A component of a catalyst (for polymerizing olefins) is prepared by reacting a mixture of (1) a titanium trichloride hydrocarbon aluminum halide dialkyl ether composition, (2) a halogen, interhalogen compound or halgenated hydrocarbon and (3) a dialkyl ether, as in known from U.K. Patent No. 1,559,447; to increase activity of the catalyst and stereoregu- lanty of the polymer, the mixture also includes (4) an electron donor, namely an organic compound containing a N, O, Si, S and /or P atom, e.g. an amine, imine, nitrile, ether, ketone, ester, sulfide, silane, siloxane, phosphine, phosphite or phosphate, in an amount of 10 -6 to 0.02 mols per gram of titanium trichloride composition (1).
The reaction may be in an inert hydrocarbon solvent at 0° to 150°C for 5 minutes to 6 hours, after which the solid is isolated and washed.
The catalyst also includes a known hydrocarbon aluminum halide or hydride as activator and may include a further stereoregularity improving agent.
Olefins having 2 to 10 carbon atoms are homo- or copolymerized at0°to 100°C to form stereoregular polyolefin using the catalyst in a small amount, e.g. 50 mg per 1.4 Kg of propylene.
摘要翻译：催化剂（用于聚合烯烃）的组分通过使（1）三氯化钛卤化铝卤化物二烷基醚组合物，（2）卤素，卤化氢化合物或卤化烃与（3）二烷基醚的混合物来自英国专利1,559,447; 为了增加催化剂的活性和聚合物的立构规整性，该混合物还包括（4）电子给体，即含有N，O，Si，S和/或P原子的有机化合物，例如。胺，亚胺，腈，醚，酮，酯，硫醚，硅烷，硅氧烷，膦，亚磷酸酯或磷酸酯，其用量为每克三氯化钛组合物（1）的10 -6至0.02摩尔。该反应可以在惰性烃溶剂中在0至150℃下反应5分钟至6小时，然后分离和洗涤固体。催化剂还包括已知的卤化烃卤化物或氢化物作为活化剂，并且可以包括另外的立构规整性改进剂。具有2至10个碳原子的烯烃在0-100℃下均聚或共聚，以形成少量的催化剂，例如，每1.4Kg丙烯50mg。

6. 发明授权

EP0367396B1 Polypropylene molded article 无效
标题翻译：聚丙烯成型品
公开(公告)号：EP0367396B1
公开(公告)日：1996-03-06
申请号：EP89309521.6
申请日：1989-09-19
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Fukui, Yoshiharu , Kuroda, Kazuhisa
IPC分类号： C08L23/12 , C08F6/10
CPC分类号： C08F6/10 , C08L23/10 , C08L23/12 , C08L23/142 , C08L53/00 , C08L2666/02

7. 发明授权

EP0226453B2 Polyolefin composition 失效
标题翻译：聚烯烃组合物。
公开(公告)号：EP0226453B2
公开(公告)日：1995-07-26
申请号：EP86309610.3
申请日：1986-12-10
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Fukui, Yoshiharu , Koyama, Teruhisa , Kuroda, Kazuhisa
IPC分类号： C08K5/00 , C08L23/02
CPC分类号： C08K5/00 , C08K5/527 , C08L23/02

8. 发明授权

EP0407198B1 Food container 失效
标题翻译：食品容器。
公开(公告)号：EP0407198B1
公开(公告)日：1994-10-12
申请号：EP90307370.8
申请日：1990-07-05
申请人： SUMITOMO CHEMICAL COMPANY LIMITED
发明人： Fukui, Yoshiharu , Kuroda, Kazuhisa
IPC分类号： B65D85/00 , C08L23/02 , C08K13/02
CPC分类号： C08K5/17 , C08K5/15 , C08K13/02 , C08L23/02

9. 发明公开

EP0367396A3 Polypropylene molded article 无效
标题翻译：聚丙烯模塑制品
公开(公告)号：EP0367396A3
公开(公告)日：1991-09-04
申请号：EP89309521.6
申请日：1989-09-19
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Fukui, Yoshiharu , Kuroda, Kazuhisa
IPC分类号： C08L23/12 , C08F6/10
CPC分类号： C08F6/10 , C08L23/10 , C08L23/12 , C08L23/142 , C08L53/00 , C08L2666/02
摘要： The invention provides a polypropylene molded article characterised in that the content of hexane and/or heptane therein is less than 5 ppm and the content of 2,4-dimethyl-heptene-1 therein is less than 5 ppm. It has a greatly lowered level of odor and hence is suitable for food packaging.

10. 发明公开

EP0323719A2 Process for producing pre-expanded particles of a polyolefin 失效
标题翻译： Verfahren zur Herstellung vonvorgeschäumtenTeilchen eines Polyolefins。
公开(公告)号：EP0323719A2
公开(公告)日：1989-07-12
申请号：EP88311729.3
申请日：1988-12-12
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Fukui, Yoshiharu
IPC分类号： C08J9/22 , C08L23/00 , C08K5/00
CPC分类号： C08J9/228 , C08J9/0014 , C08J2323/02
摘要： A process for producing pre-expanded particles of a thermoplastic resin, wherein said particles are of a polyolefin obtained by polymerizing an olefin in the presence of a Ziegler-Natta catalyst, and contain not more than 1% by weight of particles of diameter up to 105 µm and having a particle size distribution represented by: R(Dp) = 100exp[-(Dp/De) n ] where Dp is300 or more and represents a particle diameter (µ m); R(Dp) represents a cumulative weight percentage; De represents an absolute size constant that is a particle diameter (µm) corresponding to R(Dp) 36.8% by weight; and n is 25 or more and is a distribution constant.
The process can be carried out by dispersing the particles in a liquid medium (e.g. water) containing a blowing agent (e.g. an aliphatic hydrocarbon) and a phenolic antioxidant, heating to above the softening point of the polymer, and releasing the dispersion into a zone of lower pressure.
Pre-expanded polyolefin particles free from scatters of cell diameter or particle diameter and having a high expansion ratio are obtained, which can be put into a mold for expansion molding to easily provide a uniformly expanded article.
摘要翻译：一种生产热塑性树脂预发泡颗粒的方法，其中所述颗粒是通过在齐格勒 - 纳塔催化剂存在下使烯烃聚合而获得的聚烯烃，并且含有不超过1重量％的直径直到（Dp）= 100exp [ - （Dp / De）]其中，Dp为300以上，表示粒径（μm）。 R（Dp）表示累积重量百分比; De表示绝对尺寸常数，其为对应于36重量％的R（Dp）的粒径（μm） n为25以上，为分布常数。该方法可以通过将颗粒分散在含有发泡剂（例如脂族烃）和酚类抗氧化剂的液体介质（例如水）中，加热至高于聚合物的软化点，并将分散体释放到区域的压力较低。可以获得预先发泡的聚烯烃颗粒，其不含细胞直径或粒径的散射并具有高膨胀率，可以将其放入用于膨胀成型的模具中以容易地提供均匀膨胀的制品。

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