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1. 发明公开

EP0402207A3 Process for producing nitro-benzenes 失效
标题翻译：生产硝基苯的方法
公开(公告)号：EP0402207A3
公开(公告)日：1991-09-04
申请号：EP90401462.8
申请日：1990-05-31
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Sato, Hiroshi , Nagai, Koichi , Yoshioka, Hiroshi , Nagaoka, Yoshihiko
IPC分类号： C07C201/08
CPC分类号： C07C201/08 , C07C205/06 , C07C205/12
摘要： Nitrobenzenes are prepared by nitrating benzenes in vapor phase using nitric acid as a nitrating agent and under continuous or intermittent feeding of sulfuric acid as a catalyst in the presence of a catalyst comprising sulfuric acid supported on a carrier or in the presence of only a carrier. This process can provide very high and prolonged nitration activity.

2. 发明公开

EP0343048A1 Process for producing nitrobenzenes 失效
标题翻译： Verfahren zur Herstellung von Nitrobenzolen。
公开(公告)号：EP0343048A1
公开(公告)日：1989-11-23
申请号：EP89401325.9
申请日：1989-05-12
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Sato, Hiroshi , Hirose, Kenichi , Nagai, Koichi , Yoshioka, Hiroshi , Nagaoka, Yoshihiko
IPC分类号： C07C201/08 , C07C205/06 , C07C205/07
CPC分类号： C07C201/08 , C07C205/06 , C07C205/12
摘要： Nitrobenzenens are prepared by nitrating benzenes in a vapor phase with dilute or concentrated nitric acid wherein the following (A) or (B) is used as a catalyst:

(A) acidic sheet clay minerals ion-exchanged with polyvalent metals, or
(B) acidic composite oxides comprising oxides of metals belonging to Group IVA of the Mendeleefs' periodic table and tungsten oxide, molybdenum oxide, niobium oxide or zinc oxide.

These catalysts have high catalyst activity and selectivity for vapor phase nitration reaction of benzenes with nitric acid and besides the activity is retained for a long time.
摘要翻译：硝基苯是通过用稀硝酸或浓硝酸在蒸气相中硝化苯来制备的，其中使用以下（A）或（B）作为催化剂：（A）与多价金属离子交换的酸性片状粘土矿物，或（B）酸性复合氧化物，其包含属于门多德尔周期表第IVA族的金属的氧化物和氧化钨，氧化钼，氧化铌或氧化锌。这些催化剂对苯与硝酸的气相硝化反应具有高催化剂活性和选择性，此外活性长时间保留。

3. 发明公开

EP0214530A1 A method for producing cycloolefins 失效
标题翻译：一种生产环烯烃的过程。
公开(公告)号：EP0214530A1
公开(公告)日：1987-03-18
申请号：EP86111594.7
申请日：1986-08-21
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Ichihashi, Hiroshi , Yoshioka, Hiroshi
IPC分类号： C07C5/11 , C07C13/20
CPC分类号： B01J27/053 , C07C5/11 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/46 , C07C2523/50 , C07C2523/72 , C07C2523/745 , C07C2523/75 , C07C2523/89 , C07C2527/053
摘要： A method for producing cycloolefins, useful as an intermediate for lysine, caprolactam, adipic acid etc., by the partial hydrogenation of corresponding aromatic hydrocarbons with a hydrogen gas in the presence of water and a catalyst comprising barium sulfate as a carrier and ruthenium and one or more metals selected from the group consisting of iron, cobalt, silver and copper supported on the carrier, characterized by incorporating one or more metal oxides selected from the group consisting of silicon dioxide, titanium dioxide and aluminum oxide in the reaction system.

4. 发明公开

EP0121011A1 Method for the production of solid titanium trichloride catalyst 失效
标题翻译： Verfahren zur Herstellung eines festen Titantrichloridkatalysators。
公开(公告)号：EP0121011A1
公开(公告)日：1984-10-10
申请号：EP83301816.1
申请日：1983-03-30
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Shiga, Akinobu , Naito, Yukio , Sasaki, Toshio , Kojima, Junpei , Yoshioka, Hiroshi , Nunose, Akira
IPC分类号： C08F10/00 , C08F4/64
CPC分类号： C08F10/00 , C08F4/655
摘要： A known method of producing solid titanium trichloride catalyst is to reduce TiCl 4 with a hydrocarbyl aluminium or hydrocarbyl aluminum halide in an inert aliphatic hydrocarbon solvent, optionally heat-treating the product at up to 150°C, reacting the product in an aromatic hydrocarbon solvent with a halogen or interhalogen compound and a dialkyl ether, separating the solid catalyst from the liquid medium, and washing it with an inert solvent such as toluene and drying it.
To prevent clogging of a glass filter used in the separating step and aggregation of the catalyst into tough masses during the drying, the washing liquid is an aliphatic hydrocarbon such as n-hexane, n-heptane, n-octane, isooctane or n-decane; subsequent washing can be with an aromatic or aliphatic hydrocarbon. 1.5 to 20 ml of washing liquid are used per gram of solid catalyst. The washings are rapidly filtered on a glass filter; the product is dried in vacuo to a powder.
The catalyst is useful, together with an organo aluminum activator, in polymerizing an olefin, e.g. propylene, optionally with another olefin as comonomer, to form powder largely of size >1,000 microns.
摘要翻译：制备固体三氯化钛催化剂的已知方法是用惰性脂族烃溶剂中的烃基铝或烃基铝卤化物还原TiCl 4，任选地在高达150℃下热处理该产物，使产物在芳族烃溶剂中与卤素或间卤化合物和二烷基醚，将固体催化剂与液体介质分离，并用惰性溶剂如甲苯洗涤并干燥。为了防止在分离步骤中使用的玻璃过滤器堵塞并且在干燥期间将催化剂聚集成坚韧的质量，洗涤液体是正己烷，正庚烷，正辛烷，异辛烷或正癸烷等脂族烃 ; 随后的洗涤可以是芳族或脂族烃。每克固体催化剂使用1.5至20ml洗涤液。洗涤液在玻璃过滤器上快速过滤; 将产物真空干燥成粉末。催化剂与有机铝活化剂一起在烯烃聚合中是有用的。丙烯，任选地与另一种烯烃作为共聚单体，以形成大小大于1,000微米的粉末。

5. 发明公开

EP0446106A3 Process for producing organic carboxylic acid esters 失效
标题翻译：生产有机羧酸酯的方法
公开(公告)号：EP0446106A3
公开(公告)日：1993-10-06
申请号：EP91400551.7
申请日：1991-02-28
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Sato, Hiroshi , Yoshioka, Hiroshi
IPC分类号： C07C67/08 , C07C69/54
CPC分类号： C07C67/08 , C07C69/54
摘要： Disclosed is a process for producing an organic carboxylic acid ester from an organic carboxylic acid corresponding to said organic carboxylic acid ester and an alcohol by esterification reaction in gas phase which comprises carrying out the reaction with continuously or intermittently feeding sulfuric acid as a catalyst component in the presence of a catalyst carrier. The sulfuric acid may be previously supported on the catalyst carrier.

6. 发明授权

EP0515063B1 Process for producing amide by liquid phase rearrangement of oxime 失效
标题翻译：一种用于在液相中制备由肟重排酰胺过程。
公开(公告)号：EP0515063B1
公开(公告)日：1995-10-25
申请号：EP92304140.4
申请日：1992-05-08
申请人： SUMITOMO CHEMICAL COMPANY LIMITED , Izumi, Yusuke
发明人： Izumi, Yusuke , Sato, Hiroshi , Yoshioka, Hiroshi , Nomura, Yoshisaburou
IPC分类号： C07C231/10 , C07D201/04
CPC分类号： C07D201/04 , C07C231/10

7. 发明授权

EP0402207B1 Process for producing nitro-benzenes 失效
标题翻译：一种用于生产硝基苯的过程。
公开(公告)号：EP0402207B1
公开(公告)日：1994-04-27
申请号：EP90401462.8
申请日：1990-05-31
申请人： SUMITOMO CHEMICAL COMPANY LIMITED
发明人： Sato, Hiroshi , Nagai, Koichi , Yoshioka, Hiroshi , Nagaoka, Yoshihiko
IPC分类号： C07C201/08
CPC分类号： C07C201/08 , C07C205/06 , C07C205/12

8. 发明授权

EP0308719B1 Method for production of hydroxylammonium salt 失效
标题翻译：生产羟基磺酸盐的方法
公开(公告)号：EP0308719B1
公开(公告)日：1991-12-27
申请号：EP88114540.3
申请日：1988-09-06
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Ichihashi, Hiroshi , Takeda, Kikuo , Yoshioka, Hiroshi
IPC分类号： B01J23/42 , C01B21/14
CPC分类号： C01B21/1418 , B01J23/42

9. 发明授权

EP0214530B1 A method for producing cycloolefins 失效
标题翻译：一种生产环孢菌素的方法
公开(公告)号：EP0214530B1
公开(公告)日：1990-01-17
申请号：EP86111594.7
申请日：1986-08-21
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Ichihashi, Hiroshi , Yoshioka, Hiroshi
IPC分类号： C07C5/11 , C07C13/20
CPC分类号： B01J27/053 , C07C5/11 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/46 , C07C2523/50 , C07C2523/72 , C07C2523/745 , C07C2523/75 , C07C2523/89 , C07C2527/053

10. 发明授权

EP0170915B1 A method for producing cycloolefins 失效
标题翻译：一种生产环烯烃的方法
公开(公告)号：EP0170915B1
公开(公告)日：1989-04-05
申请号：EP85108530.8
申请日：1985-07-09
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Ichihashi, Hiroshi , Yoshioka, Hiroshi
IPC分类号： C07C5/11 , B01J27/053
CPC分类号： B01J27/055 , B01J27/053 , C07C5/11 , C07C2523/50 , C07C2523/72 , C07C2523/745 , C07C2523/75 , C07C2523/89 , C07C2527/053

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