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1. 发明公开

EP0731133A2 Rubber composition 失效
标题翻译： Kautschukmischung
公开(公告)号：EP0731133A2
公开(公告)日：1996-09-11
申请号：EP96301599.5
申请日：1996-03-08
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Yamamoto, Keisaku , Wakatsuki, Kizuku , Saba, Hayato
IPC分类号： C08K5/54 , C08L21/00 , C08K3/36
CPC分类号： C08K5/5419 , C08K3/36 , C08K5/548 , C08L9/00 , C08L9/06 , C08L21/00 , C08L83/04 , Y02T10/862 , C08L2666/14
摘要： A rubber composition obtainable by kneading a mixture comprising 100 parts by weight of component (A), from 5 to 100 parts by weight of component (B), from 1 to 15 parts by weight of component (C) and from 1 to 20 parts by weight of component (D) and controlling the temperature during the kneading so that the maximum temperature is 200°C or less, wherein component (A) is a solution polymerized diene rubber, component (B) is silica, component (C) is a silane coupling agent and component (D) is an organic silicon compound having a number average molecular weight of 100-10,000,
is excellent in wear resistance, has a low rolling resistance and is excellent in productivity and is useful, for example, for automobile tires.
摘要翻译：一种橡胶组合物，其通过将含有100重量份组分（A），5-100重量份组分（B），1至15重量份组分（C）和1至20重量份的混合物的组分（D），并且控制捏合过程中的温度使得最高温度为200℃或更低，其中组分（A）是溶液聚合的二烯橡胶，组分（B）是二氧化硅，组分（C）是硅烷偶联剂和组分（D）是数均分子量为100〜10000的有机硅化合物，耐磨性优异，滚动阻力低，生产率优异，例如可用于汽车轮胎。

2. 发明授权

EP0449583B1 Catalyst for olefinic hydrocarbon polymerization and process for producing olefinic hydrocarbon polymer 失效
标题翻译：催化剂的烯烃和方法，用于烯烃聚合的聚合反应。
公开(公告)号：EP0449583B1
公开(公告)日：1995-06-07
申请号：EP91302638.1
申请日：1991-03-26
申请人： SUMITOMO CHEMICAL COMPANY LIMITED
发明人： Saba, Hayato , Yamamoto, Keisaku , Imai, Akio , Sugimori, Kiyoyuki , Wakatsuki, Kizuku
IPC分类号： C08F10/00 , C08F4/68
CPC分类号： C08F10/00 , C08F4/68

3. 发明公开

EP0490672A2 Method of removing catalyst from ethylene-alpha-olefin copolymer 失效
标题翻译： Verfahren zur Entfernung von Katalysator vonÄthylen-Alphaolefincopolymeren。
公开(公告)号：EP0490672A2
公开(公告)日：1992-06-17
申请号：EP91311555.6
申请日：1991-12-12
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Yamamoto, Keisaku , Wakatsuki, Kizuku , Sugimori, Kiyoyuki , Saba, Hayato , Inagaki, Katsunari
IPC分类号： C08F6/08 , C08F6/24
CPC分类号： C08F6/02 , C08L23/00
摘要： After a copolymer of ethylene and an alpha-olefin of at least 3 carbon atoms (e.g. propylene) and optionally also a non-conjugated diene has been prepared with the use of a vanadium catalyst and an organoaluminum (e.g. alkyl) compound, the residual catalyst is removed from the polymerisation reaction mixture in a hydrocarbon solvent (e.g. hexane) by

(a) when the catalyst also includes a halogenated ester compound, mixing the reaction mixture with stirring into an aqueous solution of an alkaline compound (e.g. hydroxide of Li, Na or K) in an amount to give an aqueous phase pH of at least 10; or
(b) the halogenated ester compound being optional, oxidising the reaction mixture with an oxidising agent (preferably O₂), e.g. to convert the vanadium to pentavalent V, in an aqueous alkaline solution as in (a).

The organic phase is then separated and washed with water and the polymer is recovered therefrom.
The catalyst residue is thus reduced to very low levels, so that the copolymer is not affected thereby.
摘要翻译：在使用钒催化剂和有机铝（例如烷基）化合物制备乙烯和至少3个碳原子的α-烯烃（例如丙烯）和任选还有非共轭二烯的共聚物之后，残余催化剂在烃溶剂（例如己烷）中从聚合反应混合物中除去（a）当催化剂还包含卤代酯化合物时，将反应混合物搅拌混合到碱性化合物（例如Li，Na的氢氧化物）的水溶液中或K），其量使得水相pH至少为10; 或（b）任选的卤代酯化合物，用氧化剂（优选O 2）氧化反应混合物，例如以如（a）那样在碱性水溶液中将钒转化成五价V。然后分离有机相并用水洗涤并从中回收聚合物。因此，催化剂残余物降低到非常低的水平，使得共聚物不受其影响。

4. 发明公开

EP0449583A2 Catalyst for olefinic hydrocarbon polymerization and process for producing olefinic hydrocarbon polymer 失效
标题翻译：聚合反应的聚合反应。
公开(公告)号：EP0449583A2
公开(公告)日：1991-10-02
申请号：EP91302638.1
申请日：1991-03-26
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Saba, Hayato , Yamamoto, Keisaku , Imai, Akio , Sugimori, Kiyoyuki , Wakatsuki, Kizuku
IPC分类号： C08F10/00 , C08F4/68
CPC分类号： C08F10/00 , C08F4/68
摘要： An inert hydrocarbon catalyst is a mixture of 1 mol of (A) a reaction product obtained by reacting in an inert hydrocarbon solvent (a) 1 mol of at least one V compound VO(OR) m X 3-m wherein R is a hydrocarbon group, X a halogen atom and m a real number of from 0 to 3 (preferably 0), and (b) 0.5 to 1.4 mols of a dihydroxy hydrocarbon compound constituted of a C2-12 straight chain hydrocarbon skeleton having a hydroxyl group at each end terminal and at least one hydrocarbon branch bonded to said hydrocarbon skeleton, and 2 to 500 mols of (B) at least one organoaluminum compound represented by R′ n AℓX′ 3-n wherein R′ is a hydrocarbon group, X′ a halogen atom; and n a real number more than 0 and less than 3.
The catalyst is dissolved in an aliphatic or alicyclic hydrocarbon solvent (e.g. hexane) to which is added an olefin (e.g. α-olefin alone or with ethylene and/or a polyene), to polymerise, at 0- 100°C under pressure of 5-50 kg/cm² to produce olefinic hydrocarbon polymers having narrow distributions of molecular weight and composition with high efficiency and high polymerization activity, without obstruction or contamination of equipment due to precipitation of catalyst.
摘要翻译：惰性烃催化剂是1摩尔（A）通过在惰性烃溶剂（a）中反应获得的反应产物的混合物，（a）1摩尔至少一种V化合物VO（OR）mX3-m，其中R是烃基， X为卤素原子，实数为0〜3（优选为0），（b）0.5〜1.4摩尔由末端具有羟基的C2-12直链烃骨架构成的二羟基烃化合物和至少一个与所述烃骨架结合的烃支链，和2-500摩尔的（B）至少一种由R min nA 1 X min 3-n表示的有机铝化合物，其中R min是烃基，Xmin是卤素原子; 和大于0且小于3的实数。催化剂溶解在脂肪族或脂环族烃溶剂（例如己烷）中，向其中加入烯烃（例如单独的或与乙烯和/或多烯的α-烯烃），向在0-100℃，5-50kg / cm 2的压力下聚合，得到具有分子量和组成分布窄，分子量高，聚合活性高的烯烃聚合物，不会因沉淀物而阻塞或污染设备的催化剂。

5. 发明授权

EP0206515B1 Production of injection molded polypropylene articles 失效
标题翻译：注射成型聚丙烯制品的生产
公开(公告)号：EP0206515B1
公开(公告)日：1990-09-19
申请号：EP86303836.0
申请日：1986-05-20
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Kakugo, Masahire , Wakatsuki, Kizuku , Tanaka, Shigeo , Wakamatsu, Kazuki , Tanaka, Kazuo
IPC分类号： C08L23/10 , C08L53/00
CPC分类号： C08L23/142 , C08L23/20 , C08L53/00 , C08L23/10 , C08L2666/06

6. 发明公开

EP0148621A1 Stretched polypropylene film 失效
标题翻译：取向聚丙烯薄膜。
公开(公告)号：EP0148621A1
公开(公告)日：1985-07-17
申请号：EP84308901.2
申请日：1984-12-19
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Okada, Takayuki , Kakugo, Masahiro , Fukui, Yoshiharu , Wakatsuki, Kizuku , Ima, Seiichiro , Kimura, Junichi
IPC分类号： C08J5/18 , C08F10/06
CPC分类号： C08J5/18 , C08J2323/10 , C08L23/12 , C08L23/142 , C08L23/20 , C08L2314/02 , Y10S428/91 , Y10T428/31913 , C08L2666/06
摘要： A stretched polypropylene film having excellent see-through characteristics, which is prepared by stretching in at leastone direction a polypropylene resin sheet containing 0.05 ppm to 1 % by weight of a polymer of a 3-position branched a-olelfin having at least 6 carbon atoms or a polymer of a vinyl cycloalkane.
The olefin or cycloalkane (A) can simbly be mixed with a homo- or co-polymer of propylene; or the mixture of (A) and catalyst used in its production can be used for catalytically polymerizing propylene alone or with another a-olefin, and then more polypropylene can be admixed.
Other additives, e.g. a filler, can be included.
The polymer is pelletized and formed into a sheet and usually biaxially stretched; the streching areal ratio can be 1.2 to 100 times.

7. 发明授权

EP0708117B1 Process for producing copolymer rubber 失效
标题翻译：一种制备共聚物橡胶的过程
公开(公告)号：EP0708117B1
公开(公告)日：1999-08-11
申请号：EP95115561.3
申请日：1995-10-02
申请人： SUMITOMO CHEMICAL COMPANY LIMITED
发明人： Yamamoto, Keisaku , Wakatsuki, Kizuku , Hozumi, Hidetake , Furusawa, Atsuko
IPC分类号： C08F210/16 , C08F4/645 , C08F210/18
CPC分类号： C08F210/18 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65927 , C08F210/16 , C08F210/06 , C08F2500/08 , C08F2500/17 , C08F2500/03 , C08F2500/21 , C08F2500/25

8. 发明公开

EP0718323A3 Ethylene type quaternary copolymer rubber 失效
标题翻译： Quanternärer乙烯共聚物
公开(公告)号：EP0718323A3
公开(公告)日：1998-01-14
申请号：EP95119967.8
申请日：1995-12-18
申请人： SUMITOMO CHEMICAL COMPANY LIMITED
发明人： Yamamoto, Keisaku , Wakatsuki, Kizuku , Hozumi, Hidetake
IPC分类号： C08F210/18 , C08F4/642
CPC分类号： C08F210/18 , C08F210/06 , C08F212/08 , C08F2500/25 , C08F2500/03 , C08F2500/01 , C08F2500/17 , C08F2500/21
摘要： The present invention provides an ethylene type quaternary copolymer rubber which is formed when ethylene, an α-olefin, a non-conjugated diene, and a vinylidene aromatic monomer are polymerized. More specifically, it relates to an ethylene type quaternary copolymer having a low crystallinity which can be easily bonded and blended with a diene type rubber and to which such properties as mechanical strength, abrasion resistance, and resistance to dynamic fatigue can be effectively imparted. The quaternary copolymer rubber in accordance with the present invention has characteristics that (1) the non-conjugated diene has a content of 0.1 to 10 mol%; (2) the vinylidene aromatic monomer has a content of 0.1 to 45 mol%; (3) the limiting viscosity [η] measured at 70°C in xylene is 0.5 to 10 dl/g; (4) the glass transition temperature (Tg) measured by a differential scanning calorimeter (DSC) is a single value and not higher than 0°C; and (5) the portion soluble to methyl ethyl ketone is not greater than 2% by weight.

9. 发明公开

EP0708117A1 Process for producing copolymer rubber 失效
标题翻译： Verfahren zur Herstellung von einem Copolymerkautschuk
公开(公告)号：EP0708117A1
公开(公告)日：1996-04-24
申请号：EP95115561.3
申请日：1995-10-02
申请人： SUMITOMO CHEMICAL COMPANY LIMITED
发明人： Yamamoto, Keisaku , Wakatsuki, Kizuku , Hozumi, Hidetake , Furusawa, Atsuko
IPC分类号： C08F210/16 , C08F4/645 , C08F210/18
CPC分类号： C08F210/18 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65927 , C08F210/16 , C08F210/06 , C08F2500/08 , C08F2500/17 , C08F2500/03 , C08F2500/21 , C08F2500/25
摘要： A process of producing an ethylene-α-olefin copolymer rubber is provided, in which ethylene and an α-olefin are polymerized in the presence of a catalyst system containing catalyst constitutional components (A), (B), and (C), to form a copolymer rubber having such characteristics as an ethylene content of 30-90% by weight and a density (d) of 0.840-0.900 g/cm³. Also, a process of producing an ethylene-α-olefin-nonconjugated terpolymer rubber is provided, in which ethylene, an α-olefin, and a nonconjugated diene are polymerized in the presence of the same catalyst system, to form a terpolymer rubber having such characteristics as an ethylene content of 30-90% by weight, a density (d) of 0.840-0.900 g/cm³, and an iodine value of 0.5-40.
摘要翻译：提供了一种生产乙烯-α-烯烃共聚物橡胶的方法，其中乙烯和α-烯烃在含有催化剂结构组分（A），（B）和（C）的催化剂体系存在下聚合，形成具有乙烯含量为30-90重量％，密度（d）为0.840-0.900g / cm 3的特性的共聚物橡胶。此外，提供了一种生产乙烯-α-烯烃 - 非共轭三元共聚物橡胶的方法，其中乙烯，α-烯烃和非共轭二烯在相同的催化剂体系的存在下聚合，以形成具有这样的三元共聚物橡胶乙烯含量为30-90重量％，密度（d）为0.840-0.900g / cm 3，碘值为0.5-40的特性。

10. 发明公开

EP0316187A3 High-strength polypropylene fiber 失效
标题翻译：高强度聚丙烯纤维
公开(公告)号：EP0316187A3
公开(公告)日：1990-03-28
申请号：EP88310623.9
申请日：1988-11-10
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Wakatsuki, Kizuku , Yamaguchi, Norboru , Watamatsu, Kazuki , Kakugo, Masahiro , Ohmae, Tadayuki
IPC分类号： D01F6/06 , C08L23/10
CPC分类号： C08L23/10 , C08L23/12 , C08L23/20 , C08L2203/12 , C08L2314/02 , D01F6/06 , C08L2666/06
摘要： Crystalline polypropylene homopolymer or a copolymer with up to 5 mol% of other α-olefin or optionally containing a grafted vinyl compound, preferably of intrinsic viscosity 1.1 to 3.5 dl/g, has incorporated, during polymerization or by blending, 0.05 to 10,000 ppm of a polymer of a vinylcycloalkane, which may be a copolymer with up to 20 mol% of an α-olefin or styrene, preferably obtained with a Ziegler-Natta catalyst. The resultant polypropylene can be spun and stretched.

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