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1. 发明授权

EP1384699B1 Process for the production of synthesis gas from heavy charges such as heavy crude oils and distillation residues by means of partial oxidation 有权
标题翻译：一种用于通过重质原料如原油或Distillationsrückständen的部分氧化制备合成气的过程。
公开(公告)号：EP1384699B1
公开(公告)日：2005-04-13
申请号：EP03077221.4
申请日：2003-07-15
申请人： SNAMPROGETTI S.p.A.
发明人： Sanfilippo, Domenico , Miracca, Ivano
IPC分类号： C01B3/36 , C10K1/06
CPC分类号： B01J19/0013 , B01J2219/00123 , B01J2219/00243 , C01B3/36 , C10K1/06

2. 发明授权

EP0885654B1 Catalytic system and process for dehydrogenating ethylbenzene to styrene 失效
标题翻译：催化体系和方法用于乙苯脱氢为苯乙烯
公开(公告)号：EP0885654B1
公开(公告)日：2000-09-06
申请号：EP98111212.1
申请日：1998-06-18
申请人： SNAMPROGETTI S.p.A.
发明人： Buonomo, Franco , Sanfilippo, Domenico , Iezzi, Rodolfo , Micheli, Emilio
IPC分类号： B01J23/26 , C07C5/333 , C07C15/46
CPC分类号： B01J23/26 , B01J8/0055 , B01J8/26 , B01J2208/00274 , B01J2208/00548 , C07C5/3332 , C07C2521/04 , C07C2523/04 , C07C2523/14 , C07C2523/26 , C07C15/46

3. 发明公开

EP1134187A3 Process for the production of hydrogen 审中-公开
标题翻译：一种生产氢的过程
公开(公告)号：EP1134187A3
公开(公告)日：2009-11-18
申请号：EP01201044.3
申请日：2001-03-15
申请人： SNAMPROGETTI S.p.A.
发明人： Sanfilippo, Domenico , Paggini, Alberto , Piccoli, Valerio , Miglio, Roberta , Rossini, Stefano
IPC分类号： C01B3/38
CPC分类号： C01B3/386 , C01B3/063 , C01B2203/0261 , C01B2203/0805 , C01B2203/1058 , C01B2203/1064 , C01B2203/1241 , Y02E60/36
摘要： Process for the production of hydrogen consisting in subjecting a solid to oxidation and treating, in a different zone, the oxidized form thus produced with a reducing stream, preferably a hydrocarbon.

4. 发明公开

EP0441430A1 Catalytic dehydrogenation of C2-C5 paraffins 失效
标题翻译： Katalytische Dehydrierung von C2-C5-石蜡。
公开(公告)号：EP0441430A1
公开(公告)日：1991-08-14
申请号：EP91200187.2
申请日：1991-01-30
申请人： SNAMPROGETTI S.p.A.
发明人： Iezzi, Rodolfo , Buonomo, Franco , Sanfilippo, Domenico
IPC分类号： B01J23/42 , B01J23/62 , C07C5/32
CPC分类号： B01J23/626 , B01J23/42 , B01J37/0209 , C07C5/325
摘要： A catalytic composition for the dehydrogenation of C₂-C₅ paraffins, constituted by:

* platinum, in an amount comprised within the range of from 0.01 to 3% by weight,
* optionally tin, in an amount comprised within the range of from 0 to 1.5% by weight,
* a support selected from:

titanated alumina,
titanated silica and/or
titanium silicalite in which the titanium amount in the same support is comprised within the range of from 0.05 to 3% by weight

is disclosed.
摘要翻译：用于由以下组成的C 2 -C 5链烷烃脱氢的催化组合物：由铂组成，其量为0.01-3重量％，任选的锡，其含量范围为0-1.5％公开了一种载体，其选自钛化氧化铝，钛酸二氧化硅和/或钛硅沸石，其中相同载体中的钛含量在0.05-3重量％的范围内。 Ø

5. 发明公开

EP1445018A1 Catalytic system and process for the production of hydrogen 审中-公开
标题翻译： Katalytische Zusammensetzung und Verfahren zur Herstellung von Wasserstoff
公开(公告)号：EP1445018A1
公开(公告)日：2004-08-11
申请号：EP04075258.6
申请日：2004-01-27
申请人： ENI S.p.A. , SNAMPROGETTI S.p.A.
发明人： Cornaro, Ugo , Sanfilippo, Domenico
IPC分类号： B01J23/745 , B01J23/78 , B01J23/80 , B01J23/83 , C01B3/06
CPC分类号： B01J23/83 , B01J23/005 , B01J23/745 , B01J23/78 , B01J23/80 , B01J35/08 , C01B3/063 , Y02E60/36
摘要： Catalytic system for the production of hydrogen consisting of an active component based on iron and a micro-spheroidal carrier based on alumina and represented by the following formula

[Fe x1 M x2 Q x3 D x4 Al x5 ] O y

wherein

xi with i=1.5 represent the atomic percentages assuming values which satisfy the equation Σxi = 100.
y is the value required by the oxidation number with which the components are present in the formulate,
x1 is the atomic percentage with which Fe is present in the formulate and ranges from 5 to 80, preferably from 20 to 50,
M is Cr and/or Mn,
x2 ranges from 0 to 30, preferably from 0 to 10,
Q is La, Lanthanides (with Ce particularly preferred), Zr or a combination thereof,
x3 ranges from 0 to 30, preferably from 0 to 10,
D is Mg, Ca, Ba, Co, Ni, Cu, Zn or combinations thereof,
x4 ranges from 0 to 35, preferably from 5 to 25,
x5 is the atomic percentage with which A1 is present in the formulate and ranges from 20 to 95, preferably from 50 to 80.
摘要翻译：用于生产由基于氧化铝的活性组分和基于氧化铝的微球形载体组成的氢的催化体系，由下式表示：其中x i与i = 1.5表示原子百分比，假定满足方程式SIGMA xi = 100. y是配方中组分存在的氧化数所需的值，x1是配方中Fe存在的原子百分数，范围为5-80，优选为20〜 50，M为Cr和/或Mn，x2为0〜30，优选为0〜10，Q为La，镧系元素（Ce特别优选），Zr或其组合，x3为0〜30，优选为 0〜10，D为Mg，Ca，Ba，Co，Ni，Cu，Zn或其组合，x4为0〜35，优选为5〜25，x5为配位体中A1存在的原子百分比，范围为20至95，优选为50至80.

6. 发明授权

EP0640559B1 Process of catalytic partial oxidation of natural gas in order to obtain synthesis gas and formaldehyde 失效
标题翻译：一种用于天然气的部分氧化过程中产生的合成气和甲醛
公开(公告)号：EP0640559B1
公开(公告)日：2001-09-12
申请号：EP94202270.8
申请日：1994-08-06
申请人： SNAMPROGETTI S.p.A.
发明人： Sanfilippo, Domenico , Basini, Luca , Marchionna, Mario
IPC分类号： C01B3/38 , C01B3/40 , C07C1/04 , C07C29/151 , C07C31/04
CPC分类号： C07C29/1518 , C01B3/386 , C01B3/40 , C01B2203/0261 , C01B2203/04 , C01B2203/0475 , C01B2203/048 , C01B2203/0495 , C01B2203/06 , C01B2203/061 , C01B2203/062 , C01B2203/1023 , C01B2203/1064 , C01B2203/1082 , C01B2203/1241 , C01B2203/148 , C07C1/0485 , C07C45/33 , Y02P20/582 , C07C47/04 , C07C31/04

7. 发明公开

EP0640559A1 Process of catalytic partial oxidation of natural gas in order to obtain synthesis gas and formaldehyde 失效
标题翻译：一种用于天然气的部分氧化过程中产生的合成气和甲醛。
公开(公告)号：EP0640559A1
公开(公告)日：1995-03-01
申请号：EP94202270.8
申请日：1994-08-06
申请人： SNAMPROGETTI S.p.A.
发明人： Sanfilippo, Domenico , Basini, Luca , Marchionna, Mario
IPC分类号： C01B3/38 , C01B3/40 , C07C1/04 , C07C29/151 , C07C31/04
CPC分类号： C07C29/1518 , C01B3/386 , C01B3/40 , C01B2203/0261 , C01B2203/04 , C01B2203/0475 , C01B2203/048 , C01B2203/0495 , C01B2203/06 , C01B2203/061 , C01B2203/062 , C01B2203/1023 , C01B2203/1064 , C01B2203/1082 , C01B2203/1241 , C01B2203/148 , C07C1/0485 , C07C45/33 , Y02P20/582 , C07C47/04 , C07C31/04
摘要： Process of catalytic partial oxidation of natural gas in order to obtain synthesis gas and formaldehyde, integrated with processes of hydrogenation of the resulting CO, such as Fischer-Tropsch and methanol syntheses. Such an oxidation is carried out by means of a catalyst constituted by one or more compounds of metals form Platinum Group, which is given the shape of wire meshes, or is deposited on a carrier made from inorganic compounds, in such a way that the level of metal or metals from Platinum Group, as percent by weight, is comprised within the range of from 0.1 to 20% of the total weight of catalyst and carrier, by operating at temperatures comprised within the range of from 300 to 950°C, under pressures comprised within the range of from 0.5 to 50 Atm, at space velocities comprised within the range of from 20,000 to 1,500,000 h⁻¹.
摘要翻译：如费 - 托和甲醇合成：为了获得合成气和甲醛，与所得的CO的氢化过程集成天然气的催化部分氧化的过程。氧化的搜索是通过由金属中的一种或多种化合物构成的催化剂来进行的形式铂族，所有这一切都被赋予金属丝网的形状，或者被沉积由无机化合物制成的载体上，在寻求一种方式并水平金属或从铂族金属，如重量％，是的范围内由来自催化剂和载体的总重量的0.1至20％，通过在300〜950℃的范围内包含的温度下操作，下压力为0.5至50个大气压的范围内包括，在空间速度的范围内包含从20000到1500000ħ< - > <1>。

8. 发明授权

EP0441430B1 Catalytic dehydrogenation of C2-C5 paraffins 失效
标题翻译： C2-C5烷烃催化脱氢。
公开(公告)号：EP0441430B1
公开(公告)日：1994-03-23
申请号：EP91200187.2
申请日：1991-01-30
申请人： SNAMPROGETTI S.p.A.
发明人： Iezzi, Rodolfo , Buonomo, Franco , Sanfilippo, Domenico
IPC分类号： B01J23/42 , B01J23/62 , C07C5/32
CPC分类号： B01J23/626 , B01J23/42 , B01J37/0209 , C07C5/325

9. 发明公开

EP0470655A1 Process for preparing tertiary alkyl ethers and apparatus for reactive distillation 失效
标题翻译：威尔法罕zur Herstellung von Tert-Alkylethern und Vorrichtung zur reaktiven Destillation。
公开(公告)号：EP0470655A1
公开(公告)日：1992-02-12
申请号：EP91201838.9
申请日：1991-07-13
申请人： ENIRICERCHE S.p.A. , SNAMPROGETTI S.p.A. , ECOFUEL S.p.A.
发明人： Sanfilippo, Domenico , Lupieri, Maria , Ancillotti, Francesco
IPC分类号： C07C41/06 , B01D3/00 , B01J8/02 , C07C41/42
CPC分类号： H01H35/405 , B01D3/009 , B01J8/0207 , C07C41/06 , C07C41/42 , Y02P20/127 , C07C43/046
摘要： A process for the preparation of tertiary alkyl ethers, in particular methyl-tert.-butyl-ether (MTBE), from iso-olefins and aliphatic alcohols by means of a fractionation tower is disclosed, in which the main characteristic of the fractionation tower consists in that the reaction mixture is caused to flow through the catalytic trays in transversal direction relatively to the axis of the same fractionation tower.
摘要翻译：公开了通过分馏塔从异烯烃和脂族醇制备叔烷基醚，特别是甲基叔丁基醚（MTBE）的方法，其中分馏塔的主要特征包括因为使反应混合物相对于相同分馏塔的轴线在横向上流过催化塔板。

10. 发明公开

EP1580162A3 Process for the production of hydrogen and the co-production of carbon dioxide 审中-公开
标题翻译：一种用于生产氢气和二氧化碳的方法
公开(公告)号：EP1580162A3
公开(公告)日：2010-12-01
申请号：EP05102195.4
申请日：2005-03-18
申请人： ENI S.p.A. , ENITECNOLOGIE S.p.A. , SNAMPROGETTI S.p.A.
发明人： Sanfilippo, Domenico , Mizia, Franco , Malandrino, Alberto , Rossini, Stefano
IPC分类号： C01B3/06
CPC分类号： C01B3/063 , Y02E60/36
摘要： Process for the production of hydrogen and the co-production of carbon dioxide in separate streams comprising the following operations:
- feeding of a solid (7) to a first reaction zone (R1) in which a liquid or gaseous hydrocarbon (1), preferably natural gas or methane, is also fed, which reacts with said solid fed at its maximum oxidation degree (over-reduced form), leading to the formation of the combustion products (2) carbon dioxide and water and the solid (8) at its minimum oxidation degree (reduced form);
- feeding of the solid in reduced form (8) to a second reaction zone (R2) into which water (3) is also fed, which reacts with said reduced form of the solid, producing hydrogen, steam (4) and the solid at an intermediate oxidation degree (oxidized form) (9);
- feeding of the solid in oxidized form (9) to a third reaction zone (R3) into which air (5) is also fed, obtaining, from the further oxidation of the solid, heat (6) and the solid in over-oxidized form (7) to be recycled to the first reaction zone (R1),
wherein said solid contains at least one element selected from elements which, in addition to the metallic state, have at least three different oxidation states and are therefore capable of producing two redox pairs, in order of the oxidation state,
characterized in that in the first reaction zone (R1) the solid in over-oxidized form and the liquid or gaseous hydrocarbon are fed in countercurrent.

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