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1. 发明公开

EP1445018A1 Catalytic system and process for the production of hydrogen 审中-公开
标题翻译： Katalytische Zusammensetzung und Verfahren zur Herstellung von Wasserstoff
公开(公告)号：EP1445018A1
公开(公告)日：2004-08-11
申请号：EP04075258.6
申请日：2004-01-27
申请人： ENI S.p.A. , SNAMPROGETTI S.p.A.
发明人： Cornaro, Ugo , Sanfilippo, Domenico
IPC分类号： B01J23/745 , B01J23/78 , B01J23/80 , B01J23/83 , C01B3/06
CPC分类号： B01J23/83 , B01J23/005 , B01J23/745 , B01J23/78 , B01J23/80 , B01J35/08 , C01B3/063 , Y02E60/36
摘要： Catalytic system for the production of hydrogen consisting of an active component based on iron and a micro-spheroidal carrier based on alumina and represented by the following formula

[Fe x1 M x2 Q x3 D x4 Al x5 ] O y

wherein

xi with i=1.5 represent the atomic percentages assuming values which satisfy the equation Σxi = 100.
y is the value required by the oxidation number with which the components are present in the formulate,
x1 is the atomic percentage with which Fe is present in the formulate and ranges from 5 to 80, preferably from 20 to 50,
M is Cr and/or Mn,
x2 ranges from 0 to 30, preferably from 0 to 10,
Q is La, Lanthanides (with Ce particularly preferred), Zr or a combination thereof,
x3 ranges from 0 to 30, preferably from 0 to 10,
D is Mg, Ca, Ba, Co, Ni, Cu, Zn or combinations thereof,
x4 ranges from 0 to 35, preferably from 5 to 25,
x5 is the atomic percentage with which A1 is present in the formulate and ranges from 20 to 95, preferably from 50 to 80.
摘要翻译：用于生产由基于氧化铝的活性组分和基于氧化铝的微球形载体组成的氢的催化体系，由下式表示：其中x i与i = 1.5表示原子百分比，假定满足方程式SIGMA xi = 100. y是配方中组分存在的氧化数所需的值，x1是配方中Fe存在的原子百分数，范围为5-80，优选为20〜 50，M为Cr和/或Mn，x2为0〜30，优选为0〜10，Q为La，镧系元素（Ce特别优选），Zr或其组合，x3为0〜30，优选为 0〜10，D为Mg，Ca，Ba，Co，Ni，Cu，Zn或其组合，x4为0〜35，优选为5〜25，x5为配位体中A1存在的原子百分比，范围为20至95，优选为50至80.

2. 发明公开

EP0768290A1 Process for producing mixtures of methanol and higher alcohols 失效
标题翻译： Verfahren zur Herstellung von甲醇和其他Alkohole enthaltenden Gemischen
公开(公告)号：EP0768290A1
公开(公告)日：1997-04-16
申请号：EP96116199.9
申请日：1996-10-10
申请人： SNAMPROGETTI S.p.A.
发明人： Antonelli, Giambattista , Cornaro, Ugo
IPC分类号： C07C29/153 , C10L1/02
CPC分类号： C07C29/153 , C10L1/02 , C07C31/04 , C07C31/12
摘要： Process for producing mixtures of methanol and higher alcohols comprising feeding, into the reaction zone equipped with a catalytic system, H 2 , CO and possibly inert products with a molar ratio H 2 /CO of between 0.2 and 10, at a temperature of between 200 and 460°C, at a pressure of between 2,000 and 30,000 KPa, and at a space velocity of between 1,000 and 40,000 GHSV, wherein the catalytic system corresponds to the following empirical formula:

Zn x Cr y O t + z%M 2 O

wherein the x/y ratio is greater than 0.5 and less than 1,t is what is necessary for satisfying the valence with which the various elements appear in the catalyst, M is an alkaline metal selected from potassium and cesium,
z, representing the percentage of alkaline oxide of the final catalyst, when the metal is potassium, is between 0.01 and 8 and, when the metal is cesium, between 0.01 and 20.6.
摘要翻译：包括制备甲醇和高级醇的混合物的方法，包括在装备有催化体系的反应区中，在200至460℃的温度下，将H 2，CO和可能的惰性产物与H 2 / CO摩尔比为0.2至10 ℃，压力为2,000至30,000KPa，空速为1,000至40,000 GHSV，其中催化体系对应于以下经验式：Zn x CryOt + z％M 2 O其中x / y比大于 0.5和小于1，t是满足各种元素在催化剂中出现的价态所必需的，M是选自钾和铯的碱金属，z表示最终催化剂的碱性氧化物的百分比，当金属为钾，为0.01〜8，金属为铯时为0.01〜20.6。

3. 发明授权

EP0667184B1 Process for the skeleton isomerization of linear olefins 失效
标题翻译：一种用于直链烯烃的Skeletisomerisierung过程
公开(公告)号：EP0667184B1
公开(公告)日：1999-06-23
申请号：EP95200258.2
申请日：1995-02-02
申请人： SNAMPROGETTI S.p.A.
发明人： Miglio, Roberta , Cornaro, Ugo
IPC分类号： B01J21/02 , C07C5/27
CPC分类号： B01J21/02 , C07C5/277 , C07C11/02

4. 发明公开

EP0667184A1 Process for the skeleton isomerization of linear olefins 失效
标题翻译： Verfahren zur Skeletisomerisierung von linearen Olefinen。
公开(公告)号：EP0667184A1
公开(公告)日：1995-08-16
申请号：EP95200258.2
申请日：1995-02-02
申请人： SNAMPROGETTI S.p.A.
发明人： Miglio, Roberta , Cornaro, Ugo
IPC分类号： B01J21/02 , C07C5/27
CPC分类号： B01J21/02 , C07C5/277 , C07C11/02
摘要： Process for the skeleton isomerization of linear olefins, preferably n-butenes or n-pentenes, which consists in putting said olefins in contact with a catalyst comprising alumina on whose surface boron oxide is deposited in a quantity which is lower than 2.1×10 -4 g/m 2 of the surface of the alumina.
摘要翻译：线性烯烃，优选正丁烯或正戊烯骨架异构化的方法，其包括使所述烯烃与包含氧化铝的催化剂接触，其中表面上的氧化硼以低于2.1×10 -3的量沉积， <4g / m 2的氧化铝表面。

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