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1. 发明公开

EP1557406A1 Process for the selective (AMM) oxidation of lower molecular weight alkanes and alkenes 审中-公开
标题翻译：氧化铀Niedermolekularen Alkanen und Alkenen
公开(公告)号：EP1557406A1
公开(公告)日：2005-07-27
申请号：EP04257736.1
申请日：2004-12-13
申请人： Rohm and Haas Company
发明人： Bogan, Leonard Edward , Cavalcanti, Fernando A. P. , Chadda, Nitin , Chaturvedi, Sanjay , Gaffney, Anne Mae , Han, Scott , Klugherz, Peter D. , Martenak, Daniel , Silvano, Mark Anthony , Vickery, Elsie Mae , Zolotoroff, Donald L.
IPC分类号： C07C51/215 , C07C51/25 , C07C253/24 , C07C253/26 , C07C57/04 , C07C255/08
CPC分类号： C07C253/26 , C07C51/215 , C07C51/252 , C07C253/24 , Y02P20/52 , Y02P20/582 , C07C57/04 , C07C255/08
摘要： An improved process for the production of unsaturated carboxylic acids and unsaturated nitriles from their corresponding C 3 to C 5 alkanes, or mixtures of C 3 to C 5 alkanes and alkenes, that involves a multi-stage reaction system which employs both separation of the oxidation product from one or more intermediate effluent streams, as well as feeding additional oxygen to reaction zones subsequent to the first reaction zone.
摘要翻译：一种用于从其相应的C3至C5烷烃或C3至C5烷烃和烯烃的混合物生产不饱和羧酸和不饱和腈的改进方法，涉及多级反应体系，该方法采用两步法将氧化产物从一种或更多的中间流出物流，以及在第一反应区之后向反应区供给另外的氧。

2. 发明公开

EP1533029A1 Catalyst systems for converting Alkanes to Alkenes and to their corresponding oxygenated products 审中-公开
标题翻译：催化体系和用于烷烃烯烃的转化方法和相应的含氧化合物
公开(公告)号：EP1533029A1
公开(公告)日：2005-05-25
申请号：EP04257151.3
申请日：2004-11-18
申请人： Rohm and Haas Company
发明人： Benderly, Abraham , Chadda, Nitin , Gaffney, Anne Mae , Han, Scott , Le Dominique Hung Nhu , Silvano, Mark Anthony
IPC分类号： B01J23/648 , B01J23/62 , B01J23/54 , B01J35/04
CPC分类号： B01J35/0006 , B01J23/002 , B01J23/54 , B01J23/62 , B01J23/6484 , B01J23/6525 , B01J27/0576 , B01J35/04 , B01J37/0036 , B01J37/0215 , B01J2523/00 , C07C5/3335 , C07C5/3337 , C07C51/215 , C07C67/39 , C07C2521/04 , C07C2523/62 , C07C2523/648 , C07C11/02 , C07C57/04 , B01J2523/31 , B01J2523/56 , B01J2523/828 , B01J2523/55 , B01J2523/64 , B01J2523/68 , B01J2523/824 , B01J2523/33 , C07C69/54
摘要： Alkenes, unsaturated saturated carboxylic acids, saturated carboxylic acids and their higher analogues are prepared directly from corresponding alkanes utilizing using a mixed bed catalyst at flame temperatures in a short contact time reactor.
摘要翻译：烯烃，饱和羧酸的不饱和的，饱和羧酸和它们的高级类似物直接从相应的烷烃使用在火焰温度的混合床催化剂在短接触时间反应器利用制备。

3. 发明公开

EP1658895A1 Multi-staged catalyst systems and process for converting alkanes to alkenes and to their corresponding oxygenated products 审中-公开
标题翻译：用于烷烃至烯烃的转化的多级催化系统和相应的含氧化合物
公开(公告)号：EP1658895A1
公开(公告)日：2006-05-24
申请号：EP05257047.0
申请日：2005-11-15
申请人： Rohm and Haas Company
发明人： Benderly, Abraham , Gaffney, Anne Mae , Silvano, Mark Anthony
IPC分类号： B01J23/00 , B01J29/42 , C07C253/26
CPC分类号： C07C51/215 , B01J23/002 , B01J23/622 , B01J23/6484 , B01J27/053 , B01J29/44 , B01J29/46 , B01J35/0006 , B01J35/04 , B01J2523/00 , C07C51/252 , Y02P20/128 , Y02P20/588 , C07C57/04 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68 , B01J2523/824
摘要： Alkenes, unsaturated saturated carboxylic acids, saturated carboxylic acids and their higher analogues are prepared cumulatively from corresponding alkanes utilizing using a multi-staged catalyst system and a multi-stage process which comprises steam cracking of alkanes to corresponding alkenes at flame temperatures and at short contact times in combination with one or more oxidation catalysts for catalytically converting the corresponding alkenes to further corresponding oxygenated products using short contact time reactor conditions.
摘要翻译：烯烃，不饱和的饱和羧酸，饱和羧酸和它们的更高的类似物选自相应的烷烃使用多分级催化剂系统和多级方法，它包括烷烃蒸汽裂化以对应于火焰温度和短的接触烯烃利用累积地制备次与用于催化转化的相应的烯烃つweiterer CORRESPONDING使用短接触时间反应器条件氧化产物的一种或多种氧化催化剂。

4. 发明授权

EP2036879B1 Process For Converting A Hydroxy Carboxylic Acid Or Salts Thereof, To An Unsaturated Carboxylic Acid And/Or Its Esters 有权
标题翻译：一种用于在不饱和羧酸和/或其酯转化羟基羧酸或其盐处理
公开(公告)号：EP2036879B1
公开(公告)日：2010-06-16
申请号：EP08164021.1
申请日：2008-09-10
申请人： Rohm and Haas Company
发明人： Bogan, JR, Leonard Edward , Silvano, Mark Anthony , Zolotorofe, Donald Lee
IPC分类号： C07C51/02 , C07C59/01 , C07C59/10 , C07C59/08 , C07C57/065 , C07C67/08 , C07C69/54
CPC分类号： C07C51/02 , C07C51/377 , C07C59/08 , C07C59/01 , C07C59/10 , C07C57/04

5. 发明公开

EP2036879A1 Process For Converting A Hydroxy Carboxylic Acid Or Salts Thereof, To An Unsaturated Carboxylic Acid And/Or Its Esters 有权
标题翻译：一种用于在不饱和羧酸和/或其酯转化羟基羧酸或其盐处理
公开(公告)号：EP2036879A1
公开(公告)日：2009-03-18
申请号：EP08164021.1
申请日：2008-09-10
申请人： Rohm and Haas Company
发明人： Bogan, JR, Leonard Edward , Silvano, Mark Anthony , Zolotorofe, Donald Lee
IPC分类号： C07C51/02 , C07C59/01 , C07C59/10 , C07C59/08 , C07C57/065 , C07C67/08 , C07C69/54
CPC分类号： C07C51/02 , C07C51/377 , C07C59/08 , C07C59/01 , C07C59/10 , C07C57/04
摘要： A process for converting a salt of a hydroxycarboxylic acid to an unsaturated carboxylic acid, or esters thereof. The process involves converting an ammonium salt of a hydroxycarboxylic acid in aqueous solution to a corresponding hydroxycarboxylic acid and ammonium cation in aqueous solution; and separating the ammonium cation from the aqueous solution, leaving the hydroxycarboxylic acid in aqueous solution. The converting and separating steps may be accomplished by employing a hydrophobic acid or an acid ion exchange resin, each of which must have an acid dissociation constant, i.e., pK a , at least 0.5 less that that of the salt of the hydroxycarboxylic acid. Where a hydrophobic acid is used, it must be immiscible in water, and its salt must also be immiscible in water, and the resulting multi-phase solution comprises an aqueous phase comprising the corresponding hydroxycarboxylic acid, as well as a non-aqueous phase comprising a neutralized acid. Alternatively, where the ion exchange resin is used, the aqueous solution of the ammonium salt of a hydroxycarboxylic acid is contacted with the resin, thereby converting the salt to a hydroxycarboxylic acid and capturing the ammonium cations on the resin. In either case, the aqueous solution is treated, such as by heating, to separate and recover the hydroxycarboxylic acid. The non-aqueous phase or resin is treated to separate and recover ammonia useful for preparing additional ammonium salt of a hydroxycarboxylic acid.
摘要翻译：一种用于在不饱和羧酸的羟基羧酸的盐转化为或其酯的方法。该过程涉及转换成在wässrige溶液的羟基羧酸的铵盐在wässrige溶液中的相应的羟基羧酸和铵阳离子; 和分离从wässrige溶液中的铵阳离子，留下wässrige溶液中的羟基羧酸。转换和分离步骤可通过采用疏水性酸或酸离子交换树脂来实现，其每一个必须具有酸离解常数，即，pK a的，小至少0.5 thatthat的羟基羧酸的盐。当使用疏水性酸，它必须是在水不混溶的，因此，其盐必须在与水不混溶，并且wässrige相包含相应的羟基羧酸的所得多相溶液包含，以及非水相包含中和的酸。可替代地，使用离子交换树脂，其中，羟基羧酸的铵盐的wässrige溶液与树脂接触，从而将盐转化为羟基羧酸和捕获在树脂上的铵阳离子。在任一种情况下，溶液是wässrige治疗,:例如通过加热，以分离和回收羟基羧酸。非水相或树脂经处理以分离和回收氨用于制备羟基羧酸的附加铵盐是有用的。

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