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1. 发明公开

EP3394010A1 CONVERSION OF ALCOHOLS TO HYDROCARBONS USING A DUAL CATALYST SYSTEM COMPRISING BASIC OXIDE ON MIXED OXIDE OR MESOPOROUS CARRIER AND ETCHED METAL LOADED ZEOLITE CATALYST 审中-实审
公开(公告)号：EP3394010A1
公开(公告)日：2018-10-31
申请号：EP16879487.3
申请日：2016-12-20
申请人： Eco-Oil Miljöbränslen i Sverige AB
发明人： MIKKOLA, Jyri-Pekka , SAMIKANNU, Ajaikumar , VANKLINT, Kent , SILJEBO, William
IPC分类号： C07C1/20 , B01J21/06 , B01J29/42 , B01J29/85 , B01J21/02 , B01J21/10
CPC分类号： C07C2/12 , B01J21/12 , B01J23/78 , B01J29/072 , B01J29/44 , B01J29/46 , B01J29/85 , B01J35/0006 , C07C1/20 , C07C1/24 , C07C2521/08 , C07C2521/10 , C07C2521/12 , C07C2523/755 , C07C2529/44 , C10G3/00 , C10G3/44 , C10G3/45 , C10G3/47 , C10G3/48 , C10G3/49 , C10G3/62 , C10G2400/02 , C10G2400/04 , C10G2400/08 , Y02P20/52 , Y02P30/20 , C07C11/04 , C07C11/167 , C07C9/14 , C07C11/02
摘要： A method for converting an alcohol to hydrocarbons comprises two serially placed catalysts. The fraction of aromatics is reduced to desired levels. The method comprises: a) contacting the alcohol with a first catalyst on a carrier, said carrier is selected from a mixed oxide and a mesoporous carrier, said first catalyst comprises at least one basic oxide and optionally at least one selected from the group consisting of metals and metal oxides, then b) contacting the resulting mixture from step a) with a second catalyst wherein said second catalyst is an etched metal loaded zeolite catalyst wherein the etched metal loaded zeolite catalyst is manufactured with a method comprising etching with subsequent loading of metal onto the catalyst, wherein the metal is in the form of nanoparticles, and wherein at least two different metals are loaded onto the etched zeolite catalyst. The hydrocarbons are recovered and used for instance for fuel including gasoline, kerosene, diesel, and jet propellant, and jet fuel. Naturally, other uses of hydrocarbons should not be excluded.

2. 发明公开

EP3371138A2 PROCESS FOR CONVERSION OF ACYCLIC C5 COMPOUNDS TO CYCLIC C5 COMPOUNDS AND CATALYST COMPOSITION FOR USE THEREIN 审中-实审
公开(公告)号：EP3371138A2
公开(公告)日：2018-09-12
申请号：EP16862666.1
申请日：2016-10-07
申请人： ExxonMobil Chemical Patents Inc.
发明人： IACCINO, Larry, L. , BEDARD, Jeremy, W. , LAI, Wenyih, F. , CARR, Robert, T. , CHENG, Jane, C.
IPC分类号： C07C5/333 , C07C13/15 , C07C9/15 , B01J29/42 , B01J38/10 , C07C2/50
CPC分类号： C07C5/373 , B01J29/44 , B01J29/90 , B01J38/12 , B01J2229/186 , C07C2529/44 , Y02P20/584 , C07C13/15
摘要： Disclosed is a process for the conversion of acyclic C5 feedstock to a product comprising cyclic C5 compounds, such as, for example, cyclopentadiene, and catalyst compositions for use in such process. The process comprises the steps of contacting said feedstock and, optionally, hydrogen under acyclic C5 conversion conditions in the presence of a catalyst composition to form said product. The catalyst composition comprising a microporous crystalline aluminosilicate having a constraint index in the range of 3 to 12, a Group 10 metal, and, optionally, a Group 11 metal, in combination with a Group 1 alkali metal and/or a Group 2 alkaline earth metal.

3. 发明公开

EP3110910A4 A NAPHTHA REFORMING PROCESS 审中-公开
公开(公告)号：EP3110910A4
公开(公告)日：2017-11-08
申请号：EP15755310
申请日：2015-02-26
申请人： RELIANCE IND LTD
发明人： SHARMA NAGESH , KUMAR AJAY , METTU ANILKUMAR , KATRAVULAPALLI VEERA VENKATA SAYTA BHASKARA , GOPALAKRISHNAN KALPANA , JASRA RAKSH VIR
IPC分类号： C10G11/05 , B01J29/42 , B01J29/44 , B01J29/48 , B01J35/02 , B01J37/02 , C10G35/09 , C10G35/095
CPC分类号： B01J29/068 , B01J29/072 , B01J29/076 , B01J29/084 , B01J29/18 , B01J29/40 , B01J29/42 , B01J29/44 , B01J29/48 , B01J29/7007 , B01J29/7034 , B01J29/7038 , B01J35/023 , B01J37/0236 , B01J37/0242 , B01J37/0246 , B01J37/06 , B01J37/08 , B01J2229/186 , B01J2229/64 , C10G35/09 , C10G35/095
摘要： The present disclosure relates to a naphtha reforming process for obtaining reformed naphtha comprising contacting naphtha with a catalyst, the catalyst comprising a chloride free zeolite coated alumina support impregnated with 0.01 wt % to 0.5 wt % active metal and 0.01 wt % to 0.5 wt % promoter metal, wherein the thickness of the zeolite coating on the alumina support ranges from 100 μm to 200 μm, which results in formation of reformed products of naphtha and ethylbenzene formed in-situ.

4. 发明公开

EP1867388A1 A CATALYST AND A HYDROCARBON OIL CRACKING METHOD 审中-公开
标题翻译： KATALYSATOR UNDKOHLENWASSERSTOFFÖL-CRACKVERFAHREN
公开(公告)号：EP1867388A1
公开(公告)日：2007-12-19
申请号：EP05824020.1
申请日：2005-12-28
申请人： China Petroleum & Chemical Corporation , RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
发明人： LONG, Jun , JIANG, Wenbin , XU, Mingde , TIAN, Huiping , LUO, Yibin , SHU, Xingtian , ZHANG, Jiushun , CHEN, Beiyan , SONG, Haitao
IPC分类号： B01J29/42 , B01J27/18 , C10G11/05
CPC分类号： C10G11/05 , B01J27/1853 , B01J29/46 , B01J35/0006 , B01J35/002 , B01J2229/42 , C10G11/02 , C10G47/16 , C10G2300/4018 , C10G2400/02
摘要： The invention discloses a catalyst and a method for cracking hydrocarbons. The catalyst comprises, calculated by dry basis, 10~65wt% ZSM-5 zeolite, 0~60wt% clay, 15~60wt% inorganic oxide binder, 0.5~15wt% one or more metal additives selected from the metals of Group VIIIB and 2~25wt% P additive, in which the metal additive is calculated by metal oxide and the P additive is calculated by P 2 O 5 . The method for cracking hydrocarbons using this catalyst increases the yield of FCC liquefied petroleum gas (LPG) and the octane number of FCC gasoline, as well as it increases the concentration of propylene in LPG dramatically.
摘要翻译：本发明公开了一种催化剂和一种裂解烃的方法。该催化剂包括以干基计，10〜65重量％的ZSM-5沸石，0〜60重量％的粘土，15〜60重量％的无机氧化物粘合剂，0.5〜15重量％的一种或多种金属添加剂，其选自ⅦIB族和第ⅦB族的金属〜25wt％P添加剂，其中金属添加剂由金属氧化物计算，P添加剂由P 2 O 5计算。使用该催化剂裂解烃的方法提高了FCC液化石油气（LPG）的产率和FCC汽油的辛烷值，并且显着提高了LPG中丙烯的浓度。

5. 发明公开

EP1762299A1 A CATALYST CONTAINING ZEOLITE FOR HYDROCARBON CONVERTING AND PREPARATION THEREOF, AND A HYDROCARBON OIL CONVERTING METHOD USING SAID CATALYST 有权转让
标题翻译：沸石催化剂的烃转化及其制备和方法将碳氢油使用催化剂
公开(公告)号：EP1762299A1
公开(公告)日：2007-03-14
申请号：EP05733042.5
申请日：2005-03-31
申请人： China Petroleum & Chemical Corporation , RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
发明人： LONG, Jun , DA, Zhijian , TIAN, Huiping , CHEN, Zhenyu , ZHANG, Weilin , SHU, Xingtian , ZHANG, Jiushun , ZHU, Yuxia , LIU, Yujian
IPC分类号： B01J29/42 , C10G11/05
CPC分类号： B01J29/42 , B01J29/084 , B01J29/40 , B01J29/405 , B01J29/48 , B01J29/80 , B01J2229/42 , C10G11/05 , C10G2300/807 , C10G2400/20
摘要： A catalyst for converting hydrocarbons, which catalyst contains, based on the weight of the catalyst, 1-60% by weight of a zeolite, 0.1-10% by weight of an assistant catalytic component, 5-98% by weight of a thermotolerant inorganic oxide, and 0-70% by weight of a clay in terms of the oxide. Said zeolite is a MFI-structured zeolite containing phosphor and transition metal(s) or a mixture of said zeolite and a macroporous zeolite, which comprises, based on the weight of the mixture, 75-100% by weight of said MFI-structured zeolite containing phosphor and transition metal(s) and 0-25% by weight of the macroporous zeolite. In terms of the mass of the oxide, said MFI-structured zeolite containing phosphor and transition metal(s) has the following anhydrous chemical formula:

(0-0.3)Na 2 O · (0.3-5.5)Al 2 O 3 · (1.0-10)P 2 O 5 · (0.7-15)M1 x O y · (0.01-5)M2 m O n · (0-10)RE 2 O 3 · (70-97)SiO 2 I

or

(0-0.3)Na 2 O · (0.3-5)Al 2 O 3 · (1.0-10)P 2 O 5 · (0.7-15)M p O q · (0-10)RE 2 O 3 · (70-98)SiO 2 II

Said assistant catalytic component is one or more selected from the group consisting of the alkali earth metals, Group IVB metals, non-noble metals of Group VIII, and rare earth metals of the Periodic Table of the Elements. This catalyst has a higher ability to convert petroleum hydrocarbons and higher yields for propylene, ethylene, and light aromatics.
摘要翻译：一种用于烃转化催化剂，其催化剂含有，基于催化剂的重量，按重量计的沸石的1-60％（重量）的辅助催化剂成分的0.1-10％（重量）的耐热无机的5-98％氧化物，并且在氧化物换算为0-70重量％的粘土。所述沸石是MFI结构的沸石含磷和过渡金属（S）或所述沸石的混合物和大孔沸石，其包括，基于所述混合物的重量，重量的所述MFI结构沸石的75-100％按重量计大孔沸石的含有磷和过渡金属（S）和0-25％。在该氧化物的质量换算，说MFI结构沸石含磷和过渡金属（一个或多个）具有以下无水化学式：€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ（0-0.3）的Na 2 O·（0.3-5.5）的Al 2 O 3·（1.0-10）P 2 O 5·（0.7-15）米1×○ÿ·（0.01-5）M2 M O对N·（0-10）RE 2 O 3·（70-97）的SiO 2€€ƒƒƒ€€€ƒƒi或ƒ€€€ƒƒƒ€€€ƒƒƒ€€ƒ（0-0.3）的Na 2 O·（0.3- 5）的Al 2 O 3·（1.0-10）p 2 O 5·（0.7-15）M p 2 O q·（0-10）RE 2 O 3·（70-98）的SiO 2€€ƒƒƒ€ €ƒ€ƒII说帮手催化成分是一种或选自碱土金属的多个所选择的，IVB族金属，第VIII族的非贵金属，和元素周期表的稀土金属。该催化剂具有转换石油烃和更高的产量为丙烯，乙烯和轻质芳烃更高的能力。

6. 发明公开

EP1204478A1 METHOD FOR IMPREGNATION OF MOLECULAR SIEVE-BINDER EXTRUDATES 有权
标题翻译：方法用于浸渍分子七粘合剂挤出
公开(公告)号：EP1204478A1
公开(公告)日：2002-05-15
申请号：EP00953097.3
申请日：2000-07-25
申请人： SHELL INTERNATIONALE RESEARCHMAATSCHAPPIJ B.V.
发明人： REMANS, Thomas, Joris , VAN VEGCHEL, Ingrid, Maria
IPC分类号： B01J37/00 , B01J37/02 , B01J29/064 , B01J29/42 , B01J29/66 , B01J29/72 , C10G45/64
CPC分类号： C10G45/64 , B01J29/064 , B01J29/44 , B01J37/0009 , B01J37/0201 , B01J2229/16 , B01J2229/26 , B01J2229/32 , B01J2229/42
摘要： Method for impregnating a Group VIII metal on a molecular sieve- binder extrudate wherein the binder comprises a low acidity refractory oxide binder material, which is essentially free of alumina, by: a) contacting the molecular sieve-binder extrudate with an aqueous solution of a corresponding Group VIII metal nitrate salt having a pH of below 8, wherein the molar ratio between the Group VIII metal cations in the solution and the number of sorption sites present in the extrudate is equal to or larger than 1; b) drying the molecular sieve-binder extrudate obtained from step a).

7. 发明公开

EP1027930A4 EXHAUST EMISSION CONTROL CATALYST 有权
标题翻译：排放物控制催化剂
公开(公告)号：EP1027930A4
公开(公告)日：2001-05-23
申请号：EP98941804
申请日：1998-09-09
申请人： TOYOTA MOTOR CO LTD
发明人： TAKAHASHI HIROAKI , TAKADA TOSHIHIRO , KURACHI SAEKO
IPC分类号： B01D53/94 , B01J29/068 , B01J29/18 , B01J29/65 , B01J29/80 , B01J35/04 , B01J37/02 , F01N3/08 , B01J29/064 , B01J29/06 , B01J29/10 , B01J29/20 , B01J29/42 , B01J29/66
CPC分类号： B01D53/945 , B01D53/9418 , B01D2255/1021 , B01D2255/2022 , B01D2255/2025 , B01D2255/2042 , B01D2255/2047 , B01D2255/50 , B01D2255/912 , B01J29/068 , B01J29/084 , B01J29/18 , B01J29/22 , B01J29/40 , B01J29/44 , B01J29/65 , B01J29/67 , B01J29/80 , B01J35/04 , B01J37/0246 , B01J37/0248 , F01N3/0814 , F01N3/0835 , F01N3/0842 , F01N3/206 , Y02T10/22
摘要： An exhaust emission control catalyst comprising a first zeolite supporting a catalyst metal and a second zeolite not supporting a catalyst metal. Hydrocarbon (HC) poisoning of the catalyst metal supported by the first zeolite can be restricted by causing HC to be positively adsorbed onto the second zeolite and HC can be adsorbed sufficiently. Because, HC adsorption performance can be improved and HC poisoning of the catalyst metal is restricted, NOx emission control performance and catalyst durability can be improved.

8. 发明公开

EP4352186A1 MESOPOROUS ZEOLITES AND USES THEREOF IN DEWAXING HYDROCARBON FEEDS 审中-公开
公开(公告)号：EP4352186A1
公开(公告)日：2024-04-17
申请号：EP22732510.7
申请日：2022-06-07
申请人： Zeopore Technologies NV
发明人： VERBOEKEND, Danny , D'HALLUIN, Martin
IPC分类号： C10G45/64 , B01J29/40 , B01J29/42 , B01J29/44 , B01J29/72 , B01J29/76 , C01B39/02
CPC分类号： C10G45/64 , B01J29/44 , B01J29/7692 , C01B39/026 , B01J29/46 , B01J29/7492 , B01J29/7484 , B01J29/7684 , B01J29/67 , B01J29/68

9. 发明授权

EP2771101B1 AN ENDOTHERMIC DEHYDROGENATION PROCESS UNSING A CATALYST BED SYSTEM 有权
公开(公告)号：EP2771101B1
公开(公告)日：2019-08-21
申请号：EP12790440.7
申请日：2012-10-22
申请人： Borealis AG
发明人： WEYNE, Kristof , MATHIVANAN, Guhan
IPC分类号： B01J8/02 , B01J29/42 , C07C5/333

10. 发明公开

EP3172167A4 INTERZEOLITE TRANSFORMATION AND METAL ENCAPSULATION IN THE ABSENCE OF A SDA 有权
标题翻译：在ABWESENHEIT EINES SDA中的INTERZEOLITHTRANSFORMATION和METALLVERKAPSELUNG
公开(公告)号：EP3172167A4
公开(公告)日：2017-05-31
申请号：EP15824528
申请日：2015-07-22
申请人： UNIV CALIFORNIA , CHEVRON USA INC
发明人： GOEL SARIKA , ZONES STACEY I , IGLESIA ENRIQUE
IPC分类号： C01B39/02 , B01J29/10 , B01J29/42 , B01J29/44 , B01J29/67 , B01J29/74 , C01B39/38 , C01B39/40 , C01B39/42 , C01B39/46
CPC分类号： C01B39/46 , B01J29/061 , B01J29/126 , B01J29/40 , B01J29/44 , B01J29/67 , B01J29/74 , B01J29/743 , B01J29/80 , B01J35/002 , B01J2229/18 , B01J2229/186 , B01J2229/40 , C01B39/026 , C01B39/38 , C01B39/40 , C01B39/42 , C01B39/44
摘要： Provided is a method of encapsulating a metal in a zeolite. The method comprises inserting a metal precursor into a parent zeolite, and then converting the parent zeolite to a zeolite having a higher framework density than the parent zeolite. The conversion is achieved without the need of an organic structure directing agent.
摘要翻译：提供了一种将金属包封在沸石中的方法。该方法包括将金属前体插入母体沸石中，然后将母体沸石转化为具有比母体沸石更高的骨架密度的沸石。转换是在不需要有机结构导向剂的情况下实现的。

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