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1. 发明公开

EP3349895A1 METHOD AND APPARATUS FOR CHEMICAL PROCESS INTENSIFICATION 审中-公开
公开(公告)号：EP3349895A1
公开(公告)日：2018-07-25
申请号：EP16847127.4
申请日：2016-09-13
申请人： University of Wyoming
发明人： LI, Dongmei , TAN, Shuai
IPC分类号： B01J27/02
CPC分类号： B01J27/053 , B01D67/0088 , B01D2325/10 , B01J23/44 , B01J35/0013 , B01J35/065 , B01J35/1014 , B01J35/1019 , B01J37/0203 , B01J37/0207 , B01J37/0213 , B01J37/0244 , B01J37/14 , B01J37/349 , C01B3/16 , C01B3/505
摘要： Embodiments disclosed herein generally relate to methods and apparatus for simultaneous generation and separation processes. The apparatus provides a membrane module including a substrate, a catalytic layer and a membrane layer. The catalytic layer includes nano-sized sulfur-tolerant catalysts and/or particles. As a result, the apparatus can operate in sulfur-free and sulfur-laden (sour gas) environments for water gas shift (WGS) reactions while maintaining high reaction conversion. Methods for forming catalytic films are also disclosed herein. In one embodiment, methods of forming lanthanide containing oxysulfate nanocatalysts are provided.

2. 发明授权

EP2436442B1 METHOD FOR MANUFACTURING AN EXHAUST GAS-PURIFYING CATALYST 有权
标题翻译：制造废气净化催化剂的方法
公开(公告)号：EP2436442B1
公开(公告)日：2018-04-11
申请号：EP10780612.7
申请日：2010-05-27
申请人： Cataler Corporation
发明人： MATSUEDA, Satoshi , HIRAI, Akimasa , TAKI, Kenichi , YABUZAKI, Yuji
IPC分类号： B01J27/053 , B01D53/94 , F01N3/10
CPC分类号： B01D53/944 , B01D53/945 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/204 , B01D2255/2042 , B01D2255/2092 , B01D2255/407 , B01D2255/9022 , B01D2255/908 , B01D2255/9202 , B01J23/58 , B01J27/053 , B01J31/26 , B01J35/023 , B01J37/0215 , B01J37/0219 , B01J37/0244 , F01N2370/02 , F01N2510/06 , F01N2510/0684 , Y02T10/22
摘要： Provided is a technique that makes it possible to achieve a higher performance in purifying an exhaust gas. An exhaust gas-purifying catalyst according to the present invention includes a substrate, and a catalytic layer facing the substrate and including a precious metal, alumina, an oxygen storage material, and a sulfate of an alkaline-earth metal having an average particle diameter falling within a range of 0.01 to 0.70 µm, the average particle diameter being obtained by observation using a scanning electron microscope.

3. 发明公开

EP3285913A1 A PROCESS FOR THE REMOVAL OF SOOT FROM A SULFUROUS GAS STREAM 有权
公开(公告)号：EP3285913A1
公开(公告)日：2018-02-28
申请号：EP16715588
申请日：2016-04-13
申请人： HALDOR TOPSØE AS
发明人： SØRENSEN PER AGGERHOLM , CHRISTENSEN KURT AGERBÆK
IPC分类号： B01D53/86 , B01J21/08 , B01J23/22 , B01J27/055
CPC分类号： B01D53/864 , B01D2255/202 , B01D2255/20723 , B01D2255/30 , B01D2255/707 , B01J21/08 , B01J23/22 , B01J27/053 , B01J27/055
摘要： In a process for the removal of soot from a sulfurous gas stream, a process gas containing O2 and more than 500 ppm SO2 and/or SO3 together with soot is brought into contact with a VK type catalyst in a reactor, said catalyst comprising vanadium pentoxide (V2O5), sulfur in the form of sulfate, pyrosulfate, tri- or tetrasulfate and one or more alkali metals, such as Na, K, Rb or Cs, on a porous carrier, preferably a silicon dioxide carrier.

4. 发明公开

EP3277401A1 CATALYST FOR EXHAUST GAS PURIFICATION 审中-公开
标题翻译：催化剂用于废气净化
公开(公告)号：EP3277401A1
公开(公告)日：2018-02-07
申请号：EP16715599.3
申请日：2016-03-31
申请人： Johnson Matthey Catalysts (Germany) GmbH
发明人： BAUER, Jürgen , BISKUPSKI, Diana , DOTZEL, Ralf , JODLAUK, Jörg Walter , LEPPELT, Rainer , MÜNCH, Jörg Werner , PIRAS, Irene , SCHU, Johannes , SMEDLER, Gudmund
IPC分类号： B01D46/00 , B01D53/46 , B01J27/04 , B01J27/053 , B01J35/04 , C04B28/36 , C04B38/00
CPC分类号： B01J35/002 , B01D53/9418 , B01D53/944 , B01D53/945 , B01D2255/2025 , B01D2255/2042 , B01D2255/2045 , B01D2255/20707 , B01D2255/20723 , B01D2255/30 , B01D2255/65 , B01D2255/91 , B01D2255/912 , B01D2258/01 , B01J21/063 , B01J21/16 , B01J23/22 , B01J23/30 , B01J27/053 , B01J29/06 , B01J35/0006 , B01J35/04 , C04B35/46 , C04B35/462 , C04B35/82 , C04B38/0006 , C04B2111/00793 , C04B2111/0081 , C04B2235/3203 , C04B2235/3208 , C04B2235/3215 , C04B2235/3232 , C04B2235/3239 , C04B2235/3258 , C04B2235/3472 , C04B2235/3481 , C04B2235/349 , C04B2235/446 , C04B2235/448 , C04B2235/6021 , C04B2235/77 , C04B2235/80 , C04B2235/9607 , C04B2235/9615 , F01N3/2828 , F01N2330/06 , F01N2350/02 , F01N2350/04 , F01N2370/04 , F01N2510/06 , Y02T10/22
摘要： A honeycomb catalyst for exhaust gas purification comprising a honeycomb body, the honeycomb body comprising: a fraction acting as a pollutant trap and/or having a catalytically active fraction based on a catalytically active system comprising a base metal; and a catalytically inactive fraction, wherein the catalytically inactive fraction comprises at least one thermally stable sulphate or sulphide component for reducing thermally induced shrinkage of the honeycomb body.

5. 发明授权

EP2172266B1 Harnstoff-Hydrolyse-Katalysator 失效转让
标题翻译：尿素水解催化剂
公开(公告)号：EP2172266B1
公开(公告)日：2017-11-15
申请号：EP09011568.4
申请日：2009-09-09
申请人： Süd-Chemie IP GmbH & Co. KG
发明人： Paulus, Markus , Spengler, Jörg , Helmer, Olaf , Berger, Silke
IPC分类号： B01J27/053 , B01J21/08 , B01J21/06 , B01J37/02 , B01J35/04 , B01D53/94 , B01D53/86 , F01N3/20 , B01J31/12
CPC分类号： B01D53/8628 , B01D53/9413 , B01D2255/20707 , B01D2255/30 , B01D2255/808 , B01D2258/012 , B01J21/063 , B01J21/08 , B01J27/053 , B01J31/127 , B01J35/04 , B01J37/0219 , B01J37/0225 , F01N3/2066 , F01N2240/40 , F01N2610/02

6. 发明公开

EP3225682A1 USE OF HETEROGENEOUS ACID CATALYSTS BASED ON MIXED METAL SALTS TO PRODUCE BIODIESEL 有权
标题翻译：基于混合金属盐的非均相酸催化剂在生物柴油中的应用
公开(公告)号：EP3225682A1
公开(公告)日：2017-10-04
申请号：EP17164255.6
申请日：2017-03-31
申请人： Instituto Mexicano Del Petróleo
发明人： CRUZ, FEDERICO JESÚS JIMÉNEZ , ROSAS, CELIA MARÍN , LÓPEZ, LUIS CARLOS CASTAÑEDA , SUÁREZ, ROGELIO HERNÁNDEZ , RODRÍGUEZ, JAVIER ESTEBAN RODRÍGUEZ , GUERRERO, MARÍA DEL CARMEN MARTÍNEZ , GUEVARA, FLORENTINO RAFAEL MURRIETA , JACOB, ALICIA DEL RAYO JARAMILLO
IPC分类号： C11C3/00 , B01J23/00 , C11C3/10 , B01J21/06 , B01J21/10 , B01J23/02 , B01J23/06
CPC分类号： C07C67/02 , B01J27/02 , B01J27/053 , B01J27/055 , B01J27/16 , B01J27/18 , B01J27/1802 , B01J27/1806 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1061 , C10L1/026 , C10L2200/0476 , C10L2200/0484 , C10L2270/026 , C11C3/003 , C11C3/10 , Y02E50/13
摘要： SUMMARY OF THE INVENTION
The present invention relates to the use of heterogeneous acid catalysts primarily Lewis in nature to produce biodiesel by the transesterification of triglyceride esters, preferably by transesterification of fresh, refined or wasted vegetable oils or oils and fats of animal origin, with alcohols in heterogeneous phase, in batch reactor or continuous flow systems with yields higher than 80%, at the following operating conditions: temperature from 0 to 300°C, residence time from 20 minutes to 20 h, space velocity of 0.1 to 10 h -1 , pressure of 25-100 kg/cm 2 (24.5-98.07 bar), methanol/oil molar ratio of 10 to 40 and catalyst concentration of 0.001 to 20 weight % based on tri-, di- or monoglyceride.
More specifically, we refer to the use of heterogeneous acidic catalysts primarily Lewis in nature to produce biodiesel in the preparation of alkyl esters of alkyl by transesterification of tri-, di- or mono-glycerides, such as those derived from vegetable oils or animal origin, in particular palm, jatropha, castor, soybean and sunflower oils, wherein the R groups of the alcohoxyls R 1 O, R 2 O and R 3 O of the glycerides are from C 1 to C 24 and a C 1 -C 4 alcohol, such as methanol, in an alcohol ratio:oil from 3:1 to 50:1.
On the other hand, a primary reason for effecting the heterogeneous phase transesterification reaction to produce biodiesel is to avoid loss of catalyst, contaminating liquid effluents and eliminate undesirable side reactions such as the hydrolysis of triglycerides, diglycerides and monoglycerides into free fatty acids; in addition, in the case of catalysts of a basic nature, saponification could generate soaps.
摘要翻译：发明概述本发明涉及非均相酸催化剂主要是通过路易斯性质通过甘油三酯酯交换反应来生产生物柴油，优选通过新鲜，精制或废弃的植物油或油和动物来源的脂肪与醇的酯交换反应在非均相中，在间歇反应器或产率高于80％的连续流动体系中，在以下操作条件下：0至300℃的温度，20分钟至20小时的停留时间，0.1至10h -1的空速，基于三甘油酯，二甘油酯或甘油一酯的25-100kg / cm 2（24.5-98.07巴）的压力，10-40的甲醇/油摩尔比和0.001-20重量％的催化剂浓度。更具体地说，我们指的是使用非均相酸性催化剂，主要是天然路易斯通过三 - ，二 - 或单 - 甘油酯的酯交换制备生物柴油，例如衍生自植物油或动物来源的那些特别是棕榈油，麻风树油，蓖麻油，大豆油和葵花油，其中甘油酯的醇氧基R10，R2O和R3O的R基团为C1-C24和C1-C4醇，如甲醇，醇比为：油从3：1至50：1。另一方面，实现非均相酯交换反应生产生物柴油的主要原因是避免催化剂损失，污染液体流出物并消除不希望的副反应，例如甘油三酯，甘油二酯和甘油一酯水解为游离脂肪酸; 此外，在基本性质的催化剂的情况下，皂化可以产生肥皂。

7. 发明授权

EP2324903B1 METHOD FOR PURIFYING EXHAUST GAS CONTAINING MERCURY METAL, OXIDATION CATALYST FOR MERCURY METAL IN EXHAUST GAS AND METHOD FOR PRODUCING THE SAME 有权
标题翻译：程序含有水银，氧化催化剂清洗排气装置中汞废气及其制造方法
公开(公告)号：EP2324903B1
公开(公告)日：2017-05-10
申请号：EP09802971.3
申请日：2009-07-29
申请人： Mitsubishi Hitachi Power Systems, Ltd.
发明人： KATO Yasuyoshi
IPC分类号： B01D53/86 , B01J21/06 , B01J21/16 , B01J23/16 , B01J23/20 , B01J23/34 , B01J23/755 , B01J23/88 , B01J27/053 , B01J27/19 , B01J27/185 , B01J27/187 , B01J35/02 , B01J37/00
CPC分类号： B01D53/8665 , B01D2255/20707 , B01D2255/20723 , B01D2255/2073 , B01D2255/20753 , B01D2255/20769 , B01D2255/20776 , B01D2257/602 , B01J21/063 , B01J21/16 , B01J23/20 , B01J23/34 , B01J23/755 , B01J23/88 , B01J23/888 , B01J27/053 , B01J27/1853 , B01J27/187 , B01J27/19 , B01J35/026 , B01J37/0018 , F23J2215/60
摘要： Provided are a catalyst for removing mercury metal, which has high activity for a long time even in an exhaust gas containing SO 2 , and a method for oxidizing mercury metal using the catalyst. A method for purifying exhaust gas, including bringing an exhaust gas containing mercury metal into contact with a catalyst containing titanium oxide as a first component and a sulfate or phosphate of nickel (Ni), manganese (Mn) or vanadium as a second component, at a temperature of from 100°C to 200°C, and thereby oxidizing the mercury metal.
摘要翻译：提供的是用于去除汞金属，其在含SO 2具有长一段时间，即使在废气高活性的催化剂，以及用于氧化使用催化剂金属汞的方法。一种用于净化废气，包括将在含汞的金属废气与催化剂含有氧化钛作为第一组分和镍的硫酸盐或磷酸盐（Ni），锰（Mn）的或钒接触作为第二组分的方法，从100℃至200℃，从而氧化金属汞的温度。

8. 发明公开

EP3160901A1 A CATALYST FOR DIRECT SYNTHESIS OF HYDROGEN PEROXIDE, ITS PREPARATION AND USE 审中-公开
标题翻译：直接合成过氧化氢的催化剂及其制备和使用
公开(公告)号：EP3160901A1
公开(公告)日：2017-05-03
申请号：EP15730788.5
申请日：2015-06-23
申请人： Solvay SA
发明人： DESMEDT, Frédérique , MIQUEL, Pierre , VLASSELAER, Yves
IPC分类号： C01B15/029 , B01J21/08 , B01J23/20 , B01J23/40 , B01J23/56 , B01J27/053
CPC分类号： C01B15/029 , B01J21/066 , B01J23/20 , B01J23/44 , B01J23/464 , B01J23/6484 , B01J23/6486 , B01J27/053 , B01J27/1802 , B01J27/195 , B01J35/008 , B01J37/0201 , B01J37/035
摘要： A catalyst comprising a platinum group metal (group 10) supported on a carrier, said carrier comprising a silica core and a precipitate layer of comprising a metal oxide, sulfate or phosphate on said core; said catalyst also comprising a rhodium group metal (group 9) supported on said carrier.
摘要翻译：一种载体负载在载体上的含有铂族金属（第10族）的催化剂，所述载体包含二氧化硅核和在所述核上含有金属氧化物，硫酸盐或磷酸盐的沉淀层; 所述催化剂还包含负载在所述载体上的铑族金属（第9族）。

9. 发明公开

EP3129343A1 SYNTHESIS OF SHORTER CHAIN POLYOLS 审中-公开
标题翻译：合成VONKÜRZERKETTIGENPOLYOLEN
公开(公告)号：EP3129343A1
公开(公告)日：2017-02-15
申请号：EP15776887.0
申请日：2015-04-10
申请人： Archer Daniels Midland Company
发明人： MA, Chicheng , MARTIN, Kevin , SMITH, Brennan , TERRAIN, Josh
IPC分类号： C07C31/18 , C07C31/26 , C07C29/141
CPC分类号： C07C29/76 , B01D1/22 , B01D3/10 , B01D15/1821 , B01D15/361 , B01J27/053 , B01J27/16 , B01J31/0225 , B01J31/0227 , B01J2231/4288 , B01J2531/002 , B01J2531/007 , C07C29/154 , C07D493/04
摘要： Disclosed herein are methods of synthesizing shorter chain polyols. Methods of hydrolyzing polysaccharides are further disclosed. The present invention is also directed towards methods of selectively synthesizing sorbitol.
摘要翻译：从含有HTO和糖醇和/或糖醇的单脱水或二脱水产物的氢化反应的其它副产物的反应混合物中分离和纯化1,2,5,6己糖醇（HTO）的方法是：描述。该方法包括使HTO和其它C 1 -C 6醇和多元醇的混合物与适于层析的树脂材料接触，其中HTO优先与树脂相对于树脂相对于混合物中的其它组分，并用溶剂从所述树脂中洗脱HTO。

10. 发明公开

EP3097074A1 PROCÉDÉ DE SYNTHÈSE DE CARBONATE DE DIMÉTHYLE 有权
标题翻译： VERFAHREN ZUR SYNTHESE VON DIMETHYLCARBONAT
公开(公告)号：EP3097074A1
公开(公告)日：2016-11-30
申请号：EP15700694.1
申请日：2015-01-19
申请人： Charabot SA , Institut National Polytechnique de Toulouse , Institut National De La Recherche Agronomique
发明人： MOULOUNGUI, Zéphirin , MARUEJOULS, Christophe , LAVOINE-HANNEGUELLE, Sophie
IPC分类号： C07C68/00
CPC分类号： C07C68/00 , B01J23/06 , B01J27/053 , B01J27/128 , B01J27/135 , B01J27/138 , B01J35/0006 , B01J37/04 , B01J37/08 , C07C69/96
摘要： The invention relates to a method for synthesising dimethyl carbonate from methanol and urea, in which a saline ureic medium is used that comprises at least one inorganic salt selected from the group made up of zinc (Zn) (II) chloride, tin (Sn) chlorides and iron (Fe) (III) chloride, characterised in that: methanol, in the presence of a catalytic composition, is placed in contact with said saline ureic medium that is at least partially liquid at a temperature referred to as synthesis temperature, which is higher than 140°C, such that reaction vapours are produced; the reaction vapours are condensed, and a condensate of said reaction vapours is collected, comprising dimethyl carbonate; the method is carried out at atmospheric pressure. The invention also relates to a method for enriching and purifying dimethyl carbonate.
摘要翻译：一种从甲醇和尿素合成碳酸二甲酯的方法，其中使用盐水介质，其包含至少一种选自氯化锌（Zn）（II），氯化锡（Sn）和氯化铁（iron） Fe）（III），其特征在于：在催化组合物存在下，将甲醇与盐水脲介质接触，所述盐溶液介质在被称为合成温度的温度下至少部分为液体，其高于140 从而产生反应蒸气; 反应蒸气冷凝，收集反应蒸气的缩合物，包括碳酸二甲酯; 该方法在大气压下进行。还描述了用于富集和纯化碳酸二甲酯的方法。

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