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1. 发明公开

EP0926195A1 Polypropylene resin composition 审中-公开
标题翻译：聚丙烯树脂组合物
公开(公告)号：EP0926195A1
公开(公告)日：1999-06-30
申请号：EP98124590.5
申请日：1998-12-23
申请人： Japan Polychem Corporation , TOYOTA JIDOSHA KABUSHIKI KAISHA
发明人： Iwanami, Kunio, c/o Japan Polychem Corp. , Kobayashi, Akira, c/o Japan Polychem Corp. , Murayama, Mitsuhiro, c/o Japan Polychem Corp. , Fujita, Yuji, c/o Japan Polychem Corp. , Nagai, Takayuki , Nomura, Takao , Matsuda, Masatoshi , Kito, Osamu , Iwai, Hisayuki
IPC分类号： C08L53/02 , C08L53/00 , C08K3/34
CPC分类号： C08L53/00 , C08L53/02 , C08L53/025 , C08L2666/24
摘要： This invention provides polypropylene resin compositions exhibiting a strongly improved balance of physical properties in comparison to related polypropylene materials. The materials can be used in both interior and exterior parts of automobiles, have excellent thin-wall moldability and can effectively reduce generation of flow marks. Particularly, it provides a polypropylene resin composition which comprises specified amounts of (A) a specific ethylene-propylene block copolymer, (B) a specific thermoplastic elastomer and (C) talc, wherein it has specified values of physical properties measured by ASTM and has a degree of b-axis orientation of 720 or more which is calculated from the ratio of differential peak intensities measured by wide-angle X-ray diffraction of the central area of an ASTM No. 1 dumbbell prepared by injection molding.
摘要翻译：与有关的聚丙烯材料相比，本发明提供了聚丙烯树脂组合物，其物理性能的平衡显着改善。该材料可用于汽车内外部件，具有优异的薄壁成型性，可有效减少流痕的产生。特别是提供含有特定量的（A）特定的乙烯 - 丙烯嵌段共聚物，（B）特定的热塑性弹性体和（C）滑石的聚丙烯树脂组合物，其特征在于，根据通过注射成型制备的ASTM 1号哑铃的中心区域的广角X射线衍射测量的差分峰值强度的比率计算720或更高的b轴取向度。

2. 发明授权

EP0936248B1 Crystalline propylene block-copolymer composition for use in automobile parts 有权
标题翻译：对于汽车部件结晶性丙烯嵌段共聚物组合物
公开(公告)号：EP0936248B1
公开(公告)日：2003-04-16
申请号：EP99301024.8
申请日：1999-02-12
申请人： Mitsui Chemicals, Inc. , TOYOTA JIDOSHA KABUSHIKI KAISHA
发明人： Sakai, Ikunori , Hashimoto, Mikio , Nagai, Takayuki , Nomura, Takao , Matsuda, Masatoshi , Kito, Osamu , Iwai, Hisayuki
IPC分类号： C08L53/00
CPC分类号： C08L53/00 , C08L2666/24

3. 发明公开

EP0936248A1 Crystalline propylene block-copolymer composition for use in automobile parts 有权
标题翻译： Kristalline BlockcopolymerzusammensetzungenfürKraftfahrzeugteile
公开(公告)号：EP0936248A1
公开(公告)日：1999-08-18
申请号：EP99301024.8
申请日：1999-02-12
申请人： Grand Polymer Co., Ltd. , TOYOTA JIDOSHA KABUSHIKI KAISHA
发明人： Sakai, Ikunori , Hashimoto, Mikio , Nagai, Takayuki , Nomura, Takao , Matsuda, Masatoshi , Kito, Osamu , Iwai, Hisayuki
IPC分类号： C08L53/00
CPC分类号： C08L53/00 , C08L2666/24
摘要： A crystalline propylene block-copolymer composition exhibiting superior flowability upon molding for use in automobile parts, which composition comprises 41 to 71% by weight of a crystalline propylene block-copolymer composed of a propylene homopolymer portion (Fp) and an ethylene/propylene random copolymer portion (Fc) and having an ethylene content of 1 to 10% by weight and a melt flow rate (MFR) of 20 to 100 g/10 min.; 12 to 22% by weight of a first hydrogenated product of a block-copolymer having a lower styrene content; 2 to 12% by weight of a second hydrogenated product of a block-copolymer having a higher styrene content; and 15 to 25% by weight of talc, wherein the propylene homopolymer portion (Fp) contains 20 to 50% by weight of a low molecular weight propylene homopolymer having an MFR of 400 to 1,000 g/10 min., the average MFR being 100 to 350 g/10 min. and the isotactic pentad fraction being at least 98%, and wherein the random copolymer portion (Fc) has an intrinsic viscosity of 7 dl/g or higher.
摘要翻译：一种结晶丙烯嵌段共聚物组合物，其成型用于汽车部件时具有优异的流动性，该组合物包含41至71重量％的由丙烯均聚物部分（Fp）和乙烯/丙烯无规共聚物组成的结晶丙烯嵌段共聚物部分（Fc），乙烯含量为1〜10重量％，熔体流动速率（MFR）为20〜100g / 10分钟。 12至22重量％的具有较低苯乙烯含量的嵌段共聚物的第一氢化产物; 2至12重量％的具有较高苯乙烯含量的嵌段共聚物的第二加氢产物; 和15〜25重量％的滑石，其中丙烯均聚物部分（Fp）含有20〜50重量％的MFR为400〜1000g / 10分钟的低分子量丙烯均聚物，平均MFR为100 至350g / 10min。所述全同立构五单元组比例为98％以上，所述无规共聚物部分（Fc）的特性粘度为7dl / g以上。

6. 发明授权

EP0574114B1 Resin composition having excellent paint coatability 有权
标题翻译：与exellenter涂料涂覆性树脂组合物
公开(公告)号：EP0574114B1
公开(公告)日：1997-09-17
申请号：EP93302604.9
申请日：1993-04-01
申请人： Tonen Chemical Corporation , TOYOTA JIDOSHA KABUSHIKI KAISHA
发明人： Saito, Yoshiharu, c/o Tech. Devel. Center of , Sakaizawa, Masao, c/o Tech. Devel. Center of , Iwanami, Kunio, c/o Tech. Devel. Center of , Kitano, Kitsusho, c/o Tech. Devel. Center of , Tasaka, Michihisa , Kawazu, Kenji , Miyazaki, Shizuo , Nomura, Takao , Nishio, Takeyoshi , Iwai, Hisayuki
IPC分类号： C08L53/00 , C08K3/34
CPC分类号： C08L53/00 , C08K3/013 , C08K3/34 , C08L23/06 , C08L23/0815 , C08L23/10 , C08L23/16 , C08L2666/24 , C08L2666/04
摘要： A resin composition having excellent paint coatability containing (a) 50-80 weight % of a multi-stage polymerized propylene-ethylene block copolymer consisting essentially of (i) a propylene homopolymer portion, (ii) a propylene-ethylene random copolymer portion, and (iii) an ethylene homopolymer portion, (b) 20-40 weight % of an ethylene- alpha -olefin copolymer elastomer, and (c) 20 weight % or less of an inorganic filler, components in the components (a) and (b), which are soluble in p-xylene at a room temperature, having a number-average molecular weight of 4 x 10 or more and a weight-average molecular weight of 20 x 10 or more.

7. 发明公开

EP0778314A1 Polypropylene resin composition 有权
标题翻译： Polypropylenmassen
公开(公告)号：EP0778314A1
公开(公告)日：1997-06-11
申请号：EP96119550.0
申请日：1996-12-05
申请人： JAPAN POLYOLEFINS CO., LTD. , TOYOTA JIDOSHA KABUSHIKI KAISHA
发明人： Washiyama, Junichiro, Kawasaki Dev. Cent., Japan , Maeda, Hiroyuki, Kawasaki Plastics Lab. , Takenouchi, Hiroshi, Kawasaki Dev. Cent., Japan , Beppu, Takayuki, Kawasaki Dev. Cent., Japan , Moteki, Yoshihiro, Kawasaki Dev. Cent., Japan , Sakai, Kazuhiko, Kawasaki Dev. Cent., Japan , Jagawa, Yasutoshi , Nomura, Takao , Nishio, Takeyoshi
IPC分类号： C08L23/10
CPC分类号： C08L53/025 , C08K3/34 , C08L23/10 , C08L23/12 , C08L53/00 , C08L53/02 , C08L2205/03 , C08L2205/035 , C08L2666/02 , C08L2666/24 , C08L2666/04
摘要： A polypropylene resin composition comprising: a polypropylene, 50∼70% by weight; a polystyrene-ethylene/propylene-polystyrene tri-block copolymer containing 15∼40% by weight styrene, 3∼15% by weight; a polystyrene-ethylene/butene-polystyrene tri-block copolymer containing 15∼40% by weight styrene, 3∼15% by weight; and a talc, 10∼30% by weight; wherein the proportion of the above-mentioned polystyrene-ethylene/propylene-polystyrene tri-block copolymer with respect to the total amount of the above-mentioned polystyrene-ethylene/propylene-polystyrene tri-block copolymer and the above-mentioned polystyrene-ethylene/butene-polystyrene tri-block copolymer is 20∼80% by weight; is a material with a superior balance of physical properties, having high rigidity, superior impact resistance and tensile elongation, and in particular, being excellent for use as a material for solid molded articles such as parts for automobiles, and the like.
摘要翻译：一种聚丙烯树脂组合物，其包含：50重量％的70重量％的聚丙烯; 含有15〜40重量％苯乙烯，3重量％以上15重量％的聚苯乙烯 - 乙烯/丙烯 - 聚苯乙烯三嵌段共聚物; 含有15〜40重量％苯乙烯，3重量％以上15重量％的聚苯乙烯 - 乙烯/丁烯 - 聚苯乙烯三嵌段共聚物; 和10-30重量％的滑石粉; 其中上述聚苯乙烯 - 乙烯/丙烯 - 聚苯乙烯三嵌段共聚物的比例相对于上述聚苯乙烯 - 乙烯/丙烯 - 聚苯乙烯三嵌段共聚物和上述聚苯乙烯 - 乙烯/ 丁烯 - 聚苯乙烯三嵌段共聚物为20〜80重量％是具有优异的物理平衡的材料，具有高刚性，优异的抗冲击性和拉伸伸长率，特别优选用作汽车用零件等固体成形品的材料。

8. 发明公开

EP0739941A1 Thermoplastic resin composition 失效
标题翻译：热塑性树脂组合物
公开(公告)号：EP0739941A1
公开(公告)日：1996-10-30
申请号：EP96106780.8
申请日：1996-04-29
申请人： SUMITOMO CHEMICAL COMPANY LIMITED , TOYOTA JIDOSHA KABUSHIKI KAISHA
发明人： Sadatoshi, Hajime , Suzuki, Haruyuki , Miyake, Yuichi , Nomura, Takao , Nishio, Takeyoshi
IPC分类号： C08L23/16 , C08L23/10 , C08L53/00
CPC分类号： C08L23/12 , C08K3/013 , C08L23/0815 , C08L23/16 , C08L53/00 , C08L2205/02 , C08L2205/035 , C08L2205/22 , C08L2310/00 , C08L2312/00 , C08L2666/02 , C08L2666/06 , C08L2666/04 , C08L23/10
摘要： A thermoplastic resin composition with improved low-temperature impact strength and rigidity against heat, comprising (I) 10-40% by weight of a mixture of (a) 10-50% by weight of a propylene homopolymer and/or an ethylene-propylene block copolymer (an isotactic pentad fraction of a propylene homopolymer portion being 0.98 or above) and (b) 50-90% by weight of an olefin-based copolymer rubber, said mixture having been dynamically heat treated in the presence of an organic peroxide and a crosslinking agent, (II) 20-85% by weight of a propylene homopolymer and/or an ethylene-propylene block copolymer (an isotactic pentad fraction of a propylene homopolymer portion being 0.98 or above and a melt index of the propylene homopolymer portion being 30-150 g/10 min), and (III) 5-40% by weight of an inorganic filler.
摘要翻译：一种具有改进的低温冲击强度和耐热刚性的热塑性树脂组合物，其包含（I）10-40重量％的（a）10-50重量％的丙烯均聚物和/或乙烯丙烯嵌段共聚物（丙烯均聚物部分的全同立构五元组分数为0.98或更高）和（b）50-90％（重量）的烯烃基共聚物橡胶，所述混合物在有机过氧化物存在下进行动态热处理，和（II）20-85重量％的丙烯均聚物和/或乙烯 - 丙烯嵌段共聚物（丙烯均聚物部分的全同立构五元组分数为0.98或更高，丙烯均聚物部分的熔体指数为 30-150克/ 10分钟）和（III）5-40重量％的无机填料。

9. 发明公开

EP0580069A1 Thermoplastic resin composition and injection-molded article thereof 失效
标题翻译： Thermoplastische Harzzusammensetzung und Spritzgussfaserteile daraus。
公开(公告)号：EP0580069A1
公开(公告)日：1994-01-26
申请号：EP93111287.4
申请日：1993-07-14
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED , TOYOTA JIDOSHA KABUSHIKI KAISHA
发明人： Abe, Hiroomi , Fujii, Takeshi , Yamamoto, Masashi , Nishio, Takeyoshi , Nomura, Takao
IPC分类号： C08L53/00
CPC分类号： C08L53/00 , C08L2666/02
摘要： A thermoplastic resin composition which contains a resin composition containing a crystalline polypropylene component, an ethylene-butene-1 copolymer rubber and an ethylene-propylene copolymer rubber; a modified polypropylene; a saturated polyester resin; and an epoxy group-containing copolymer; and optionally talc exhibits high low-temperature impact strength, stiffness and Rockwell hardness and a small coefficient of linear expansion, which composition gives an injection-molded article suitably used for a bumper for automobile.
摘要翻译：一种含有结晶聚丙烯组分，乙烯 - 丁烯-1共聚物橡胶和乙烯 - 丙烯共聚物橡胶的树脂组合物的热塑性树脂组合物; 改性聚丙烯; 饱和聚酯树脂; 和含环氧基的共聚物; 并且任选的滑石显示出高的低温冲击强度，刚度和洛氏硬度和较小的线膨胀系数，该组合物给出适合用于汽车保险杠的注塑制品。

10. 发明授权

EP0335394B1 Thermoplastic resin composition 失效
标题翻译：一种热塑性树脂组合物。
公开(公告)号：EP0335394B1
公开(公告)日：1993-11-10
申请号：EP89105627.7
申请日：1989-03-30
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED , TOYOTA JIDOSHA KABUSHIKI KAISHA
发明人： Okada, Takayuki , Mitsuno, Tatsuyuki , Fujii, Takeshi , Yamaguchi, Kentaro , Okada, Mitsuyuki , Tsuji, Mitsuji , Nishio, Takeyoshi , Yokoi, Toshio , Nomura, Takao
IPC分类号： C08L51/06 , C08L23/12 , C08L67/00 , C08L63/00 , C08L23/16 , C08L51/00
CPC分类号： C08L23/10 , C08K7/14 , C08L23/0884 , C08L23/12 , C08L23/16 , C08L51/06 , C08L53/00 , C08L63/00 , C08L67/00 , C08L67/02 , C08L2205/03 , C08L2205/035 , C08L2666/24 , C08L2666/18 , C08L2666/06 , C08L2666/02

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