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    • 1. 发明公开
    • HYDROGENATION METHOD OF PHTHALATE COMPOUND
    • HYDRIERVERFAHRENFÜREINE PHTHALATVERBINDUNG
    • EP3085686A1
    • 2016-10-26
    • EP14872787.8
    • 2014-12-17
    • Hanwha Chemical Corporation
    • JUNG, Ki TaegKIM, Hyo SukYOON, Kyong JunHAN, Kee DoKWAK, Jang YoungKIM, Young JoSEONG, Pil JeLEE, Sang WookZHANG, Ying
    • C07C51/36C07C67/303C07C67/62B01J23/40
    • C07C67/62B01J23/462C07C51/36C07C67/303C07C2601/14C07C69/75
    • There are provided a method for hydrogenation of a phthalate compound. According to the method for hydrogenation of the present invention, a hydrogenation reaction is performed in a multi-pipe type reactor in a state in which a viscosity of only a liquid-phase phthalate based raw material is lowered, such that a yield of a hydrogenation reaction process may be improved, and operation stability and economical efficiency on a commercial scale may be improved by hot spot control. According to another method of the present invention, long-term activity of a catalyst used in a reaction is maintained, and performance of the catalyst may be improved, such that stability and economical efficiency of a hydrogenation process may be improved. Therefore, a total amount of the catalyst required in the reaction may be decreased, and a replacement cycle may be extended, thereby making it possible to improving operation stability of the process and economical efficiency at the time of performing the process on a commercial scale.
    • 提供邻苯二甲酸酯化合物的氢化方法。 根据本发明的氢化方法,在多管型反应器中,仅使邻苯二甲酸酯类基质原料的粘度降低,氢化的收率为氢化反应 可以提高反应过程,通过热点控制可以提高工业规模的操作稳定性和经济性。 根据本发明的另一方法,保持反应中使用的催化剂的长期活性,并且可以提高催化剂的性能,从而提高氢化方法的稳定性和经济性。 因此,可以减少反应所需的催化剂的总量,并且可以延长更换周期,从而可以提高工艺的操作稳定性和在商业规模下进行工艺时的经济性。