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    • 7. 发明公开
    • RADICAL POLYMERIZATION METHOD AND POLYMERIZATION REACTION APPARATUS
    • 自由基聚合法和聚合反应装置
    • EP3187513A1
    • 2017-07-05
    • EP15836898.5
    • 2015-08-24
    • Japan Agency for Marine-Earth Science and Technology
    • DEGUCHI, ShigeruKINOSHITA, Keigo
    • C08F2/04C08F2/01
    • C08F2/001B01J19/1812B01J19/26B60H1/00885C08F2/01C08F2/04C08F4/04C08F4/34C08F4/46F16K17/02G05D23/1333
    • The present invention provides a radical polymerization method that enables synthesis, at a high conversion rate, of polymers having a relatively uniform molecular weight and is applicable to various monomers that are generally available, and an apparatus used for the method. The present invention relates to a method for producing a polymerization product by continuously or intermittently circulating, within a flow path of the radical polymerization apparatus, a reaction solution containing a monomer and a radical polymerization initiator. Heating of the reaction solution that has flowed into a heating-initiation unit to a predetermined temperature is performed in a condition in which the radical polymerization initiator, contained in a volume obtained when the reaction solution that has flowed into the heating-initiation unit is temporally sliced, is cleaved all at once (a condition in which the radical polymerization initiator contained in the volume is heated to the predetermined temperature simultaneously across the radial direction of a cross section of the flow path). The present invention relates to a radical polymerization reaction apparatus including a heating medium production unit 10, a heating medium-reaction solution mixing unit 20, a cooling unit 30, and a recovery unit 40 for a reaction mixture, all of which are communicatively connected by the flow path. The present invention relates to a radical polymerization reaction apparatus including a heating reaction unit 60, a cooling unit 70, and a recovery unit 80 for a reaction mixture, wherein all of which are communicatively connected by the flow path.
    • 本发明提供一种能够以高转化率合成具有相对均匀分子量的聚合物并且适用于通常可用的各种单体的自由基聚合方法以及用于该方法的设备。 本发明涉及在自由基聚合装置的流路内使含有单体和自由基聚合引发剂的反应溶液连续或间歇循环来制造聚合物的方法。 已经流入加热启动单元的反应溶液加热到预定温度是在包含在流入加热启动单元的反应溶液临时获得的体积中的自由基聚合引发剂的条件下进行的 切断后立即切断(体积内所含的自由基聚合引发剂在流路截面的半径方向上同时被加热至规定温度的状态)。 自由基聚合反应装置技术领域本发明涉及一种自由基聚合反应装置,其包括加热介质生成单元10,加热介质 - 反应液混合单元20,冷却单元30和反应混合物回收单元40,它们全部通过 流动路径。 自由基聚合反应装置技术领域本发明涉及具有加热反应部60,冷却部70和反应混合物回收部80的自由基聚合反应装置,其全部通过流路连通。