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    • 4. 发明公开
    • A positive type photosensitive image-forming material for an infrared laser and a positive type photosensitive composition for an infrared laser
    • 用于红外激光的红外激光和正性工作组合物的正型光敏记录材料
    • EP1437232A2
    • 2004-07-14
    • EP04008648.0
    • 1998-10-16
    • Fuji Photo Film Co., Ltd.
    • Miyake, HideoKawauchi, Ikuo
    • B41M5/36B41C1/10G03F7/004
    • B41C1/1016B41C1/1008B41C2210/02B41C2210/06B41C2210/22B41C2210/24B41C2210/262Y10S430/106Y10S430/145
    • A positive image-forming material for use with infrared laser comprises: a substrate; a layer(A) containing not less than 50% by weight of a copolymer which contains, as a copolymerization component, not less than 10% by mol of at least one of the following monomers (a-1) to (a-3),wherein (a-1) is a monomer having in the molecule a sulfonamide group wherein at least one hydrogen atom is linked to a nitrogen atom, (a-2) is a monomer having in the molecule an active imino group represented by the following general formula (I):
      and (a-3) is a monomer sel ected from acry l am i de, methacry l am i de, acryl ate, methacrylate and hydroxystyrene, which respective have a phenolic hydroxyl group; and a layer (B) containing not less than 50% by weight of an aqueous alkali solution-soluble resin having a phenolic hydroxyl group. The layer (A) and the layer (B) are laminated on the substrate in that order. At least the layer (B) contains a compound which generates heat upon absorbing light. An image forming material comprises following compound (II) or (III):

              R 1 -SO 2 -SO 2 -R 2      (II)



              R 1 -SO 2 -R 2      (III)

      wherein R 1 and R 2 may be the same or different, and R 1 and R 2 represent a substituted or non-substituted alkyl, alkenyl or aryl group. The photosensitive image-forming material and positive photosensitive composition have excellent stability of sensitivity with regard to concentration of a developing solution, i.e, have excel lent development latitude.
    • 用于红外激光器一起使用的正型成像材料包括:一个基片; 按重量计其中含有共聚物含有不低于50%时,作为共聚成分,而不是由至少一个下面的单体(A-1)的摩尔小于10%的层(A)(A-3) ,worin(A-1)是在分子中具有磺酰胺基worin至少一个氢原子连接到氮原子时,(A-2)的单体是由下式表示活性亚氨基的在分子中具有单体 通式(I):和(a-3)是一种单体SEL从ACRY升ected AM I DE,甲基丙烯升是我去,丙烯酸吃,甲基丙烯酸酯和羟基苯乙烯,其中respectivement具有酚羟基基团; 和按重量计具有酚羟基的碱溶液wässrige可溶性树脂的含有不低于50%的层(B)。 所述层(A)和层(B)层叠在该顺序的基材。 至少所述层(B)含有哪些基因速率加热时吸收光的化合物。 一种图像形成材料包括以下化合物(II)或(III):R <1> -SO 2-SO 2 -R <2> [R <1> -SO 2 -R <2> worin - [R <1>和R <2>可 是相同的或不同的,并且R <1>和R <2>表示substituiertem或非substituiertem烷基,烯基或芳基。 在感光成像材料和正型光敏组合物具有关于显影溶液,即浓度灵敏度的稳定性优异,具有高强借给显影宽容度。
    • 10. 发明公开
    • Positive photosensitive composition for use with an infrared laser
    • 用于红外激光的正性光敏组合物
    • EP0901902A3
    • 1999-03-24
    • EP98117286.9
    • 1998-09-11
    • Fuji Photo Film Co., Ltd.
    • Kawauchi, IkuoKimura, Takeshi
    • B41C1/10B41M5/36
    • B41C1/1008B41C1/1016B41C2201/02B41C2201/04B41C2201/12B41C2201/14B41C2210/02B41C2210/06B41C2210/22B41C2210/24B41C2210/262
    • A positive photosensitive composition for use with an infrared laser comprises one or more alkali aqueous solution soluble polymer compounds (A) having in a molecule at least one group selected from a phenolic hydroxide group (a-1), a sulfonamide group (a-2), and an active imide group (a-3); a compound (B) which has an I/O value (Y) satisfying a relationship 0.05 ≦ | X - Y | ≦ 0.5 wherein X is an I/O value of the polymer compound (A), and which is compatible with the polymer compound (A) thereby lowering solubility of the polymer compound (A) into an alkali aqueous solution, an effect of lowering the solubility being reduced by heating; and a compound (C) which generates heat upon absorbing light. The photosensitive composition does not contain any compound having a thermal decomposition temperature of 150°C or less. Alternatively, the photosensitive composition may comprise a compound which generates heat upon absorbing light; an alkali aqueous solution soluble resin having a phenolic hydroxide group; and a compound represented by R 1 CO-X-R 2 (wherein X represents O, S or NR 3 ; R 1 represents an alkyl group or alkenyl group which has 6 - 32 carbon atoms, R 2 and R 3 represent a hydrogen atom, or an alkyl group or alkenyl group or aryl group each of which has 1 - 18 carbon atoms).
    • 用于红外激光的正型光敏组合物包含一种或多种在分子中具有至少一个选自氢氧化酚基(a-1),磺酰胺基(a-2)的基团的碱性水溶液可溶性聚合物化合物(A) )和活性酰亚胺基团(a-3); 具有满足0.05≤|的关系的I / O值(Y)的化合物(B) X - Y | 其中X是高分子化合物(A)的I / O值,并且其与高分子化合物(A)相容从而降低高分子化合物(A)在碱性水溶液中的溶解度, 通过加热降低溶解度; 和吸收光而发热的化合物(C)。 感光性组合物不含有热分解温度为150℃以下的化合物。 或者,光敏组合物可以包含在吸收光时发热的化合物; 具有酚羟基的碱性水溶液可溶性树脂; 和由R 1 CO-X-R 2表示的化合物(其中X代表O,S或NR 3; R 1代表具有6-32个碳原子的烷基或烯基,R 2和R 3代表氢原子或烷基 基团或烯基或芳基,每个基团具有1-18个碳原子)。