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1. 发明公开

EP2744814A1 AMIDO-FLUOROPHOSPHITE COMPOUNDS AND CATALYSTS 审中-公开
标题翻译：酰胺 - 氟代磷酸酯化合物和催化剂
公开(公告)号：EP2744814A1
公开(公告)日：2014-06-25
申请号：EP12750651.7
申请日：2012-08-03
申请人： Eastman Chemical Company
发明人： PUCKETTE, Thomas, Allen
IPC分类号： C07F9/26 , C07B41/06
CPC分类号： C07F9/26
摘要： Amido-fluorophosphite compounds and catalyst systems comprising at least one amido-fluorophosphite ligand compound in combination with a transition metal are described. Moreover, the use of amido-fluorophosphite containing catalysts for transition metal catalyzed processes, especially to the hydroformylation of various olefins to produce aldehydes are also described.
摘要翻译：描述了包含至少一种酰胺 - 氟代亚磷酸酯配体化合物和过渡金属的酰胺 - 氟代亚磷酸酯化合物和催化剂体系。此外，还描述了使用含酰胺基 - 氟亚磷酸酯的催化剂用于过渡金属催化过程，特别是各种烯烃加氢甲酰化以生产醛。

2. 发明授权

EP2342210B1 ACETYLENE TOLERANT HYDROFORMYLATION CATALYSTS 有权
标题翻译：乙炔容许加氢甲酰化催化剂
公开(公告)号：EP2342210B1
公开(公告)日：2014-07-23
申请号：EP09789277.2
申请日：2009-09-08
申请人： Eastman Chemical Company
发明人： PUCKETTE, Thomas, Allen
IPC分类号： C07F9/50 , C07F9/6574 , C07B41/06 , C07C45/50
CPC分类号： C07F9/5027 , C07B41/06 , C07C45/50 , C07F9/65744 , C07F9/65746 , C07C47/02

3. 发明授权

EP2291387B1 HYDROFORMYLATION CATALYSTS 有权
标题翻译：氢甲酰化
公开(公告)号：EP2291387B1
公开(公告)日：2012-07-11
申请号：EP09766991.5
申请日：2009-05-15
申请人： Eastman Chemical Company
发明人： TOLLESON, Ginette, Struck , PUCKETTE, Thomas, Allen
IPC分类号： C07F9/6574 , C07B41/06
CPC分类号： C07F9/65742 , C07F9/65744 , Y02P20/142
摘要： This invention is directed to a class of compounds that can be both monodentate and bidentate in their association with a transition metal to form a catalyst for reactions such as the hydroformylation of olefins to produce aldehydes. The compounds contain two phosphorus atoms having different steric and/or electronic nature. In hydroformylation catalysts, the compounds advantageously can produce a variable n/iso product mixture of aldehyde products that can be varied by simply changing process variables such as [H
2 ]/[CO] partial pressure gas ratio or temperature/inert gas partial pressure.

4. 发明授权

EP1539667B1 PROCESS FOR REDUCING FLUORIDE IMPURITIES RESULTING FROM USE OF FLUOROPHOSPHITE CATALYSTS 有权
标题翻译：异径FLUORPHOSPHITKATALYSATOREN所产生的氟化物污染，使用方法
公开(公告)号：EP1539667B1
公开(公告)日：2008-05-07
申请号：EP03809519.6
申请日：2003-09-09
申请人： EASTMAN CHEMICAL COMPANY
发明人： TOLLESON, Ginette, Struck , PUCKETTE, Thomas, Allen
IPC分类号： C07C45/50 , C07C47/02 , C07F9/02
CPC分类号： C07C45/50 , C07C47/02
摘要： Disclosed is a process for reducing fluoride content in a process utilizing a fluorophosphite-containing transition metal catalyst.

5. 发明授权

EP1133356B1 HYDROFORMYLATION PROCESS USING CHLOROPHOSPHITE-METAL CATALYST SYSTEM 有权
标题翻译：氢甲酰化使用一个氯化亚金属的催化剂系统
公开(公告)号：EP1133356B1
公开(公告)日：2004-03-17
申请号：EP99955036.1
申请日：1999-10-15
申请人： EASTMAN CHEMICAL COMPANY
发明人： TOLLESON, Ginette, Struck , PUCKETTE, Thomas, Allen
IPC分类号： B01J31/18 , C07C45/50 , C07F13/00 , C07F15/00
CPC分类号： C07F15/008 , B01J31/185 , B01J2231/321 , B01J2531/822 , C07C45/50 , C07C47/02
摘要： Disclosed are catalyst systems comprising one or more transition metals selected from the Group VIII metals and rhenium and one or more chlorophosphite compounds having general Formula (I), wherein R and R are aromatic hydrocarbyl radicals. Also disclosed are catalyst solutions comprising one or more the above chlorophosphite compounds, rhodium and a hydroformylation solvent, and hydroformylation processes wherein olefins are contacted with carbon monoxide, hydrogen and the catalyst solution to produce aldehydes.

6. 发明授权

EP0446301B1 PREPARATION OF BIARYL COMPOUNDS 失效
标题翻译：连接操作的联芳。
公开(公告)号：EP0446301B1
公开(公告)日：1994-11-23
申请号：EP90901266.8
申请日：1989-11-13
申请人： EASTMAN CHEMICAL COMPANY
发明人： PUCKETTE, Thomas, Allen
IPC分类号： C07B37/04 , C07C15/14 , C07C25/18 , C07C43/164 , C07C43/205 , C07D213/22 , C07C1/26 , C07C17/26 , C07C41/30 , C07D213/127 , B01J31/26
CPC分类号： C07C255/51 , B01J31/181 , B01J31/1815 , B01J31/2295 , B01J31/24 , B01J31/2409 , B01J31/2414 , B01J31/2452 , B01J2231/4205 , B01J2531/0205 , B01J2531/0266 , B01J2531/842 , B01J2531/847 , C07C1/26 , C07C17/269 , C07C41/30 , C07C45/72 , C07C253/30 , C07C2527/128 , C07C2531/24 , C07C2531/30 , C07C15/14 , C07C15/24 , C07C22/08 , C07C25/18 , C07C43/2055
摘要： A method for the preparation of biaryl compounds is disclosed which comprises contacting an aromatic halide in the presence of a catalyst comprising zerovalent nickel, a bidentate phosphorus-containing coordinating ligand and a reducing metal in a polar, aprotic solvent system for a time and under conditions suitable for the formation of biaryl compound.

7. 发明公开

EP2291387A2 HYDROFORMYLATION CATALYSTS 有权
标题翻译： HYDROFORMYLIERUNGSKATALYSATOREN
公开(公告)号：EP2291387A2
公开(公告)日：2011-03-09
申请号：EP09766991.5
申请日：2009-05-15
申请人： Eastman Chemical Company
发明人： TOLLESON, Ginette, Struck , PUCKETTE, Thomas, Allen
IPC分类号： C07F9/6574 , C07B41/06
CPC分类号： C07F9/65742 , C07F9/65744 , Y02P20/142
摘要： This invention is directed to a class of compounds that can be both monodentate and bidentate in their association with a transition metal to form a catalyst for reactions such as the hydroformylation of olefins to produce aldehydes. The compounds contain two phosphorus atoms having different steric and/or electronic nature. In hydroformylation catalysts, the compounds advantageously can produce a variable n/iso product mixture of aldehyde products that can be varied by simply changing process variables such as [H
2 ]/[CO] partial pressure gas ratio or temperature/inert gas partial pressure.

8. 发明公开

EP1542956A1 PROCESS FOR REDUCING FLUORIDE IMPURITIES RESULTING FROM USE OF FLUOROPHOSPHITE CATALYSTS 有权
标题翻译：一种用于减少FLUORPHOSPHITKATALYSATOREN RESULTING氟化物污染的用途
公开(公告)号：EP1542956A1
公开(公告)日：2005-06-22
申请号：EP03795666.1
申请日：2003-09-09
申请人： EASTMAN CHEMICAL COMPANY
发明人： TOLLESON, Ginette, Struck , PUCKETTE, Thomas, Allen
IPC分类号： C07C45/50
CPC分类号： C07C45/50 , C07C47/02
摘要： Described is a process for reducing the fluoride content of products prepared in a process utilizing a fluorophosphite-containing transition metal complex catalyst, involving contacting the products with an adsorbent.

9. 发明公开

EP1133356A1 HYDROFORMYLATION PROCESS USING CHLOROPHOSPHITE-METAL CATALYST SYSTEM 有权
标题翻译：氢甲酰化使用一个氯化亚金属的催化剂系统
公开(公告)号：EP1133356A1
公开(公告)日：2001-09-19
申请号：EP99955036.1
申请日：1999-10-15
申请人： EASTMAN CHEMICAL COMPANY
发明人： TOLLESON, Ginette, Struck , PUCKETTE, Thomas, Allen
IPC分类号： B01J31/18 , C07C45/50 , C07F13/00 , C07F15/00
CPC分类号： C07F15/008 , B01J31/185 , B01J2231/321 , B01J2531/822 , C07C45/50 , C07C47/02
摘要： Disclosed are catalyst systems comprising one or more transition metals selected from the Group VIII metals and rhenium and one or more chlorophosphite compounds having general Formula (I), wherein R?1 and R2¿ are aromatic hydrocarbyl radicals. Also disclosed are catalyst solutions comprising one or more the above chlorophosphite compounds, rhodium and a hydroformylation solvent, and hydroformylation processes wherein olefins are contacted with carbon monoxide, hydrogen and the catalyst solution to produce aldehydes.

10. 发明授权

EP0386105B1 A PROCESS FOR THE PREPARATION OF BIDENTATE LIGANDS 失效
标题翻译：用于生产双齿配体。
公开(公告)号：EP0386105B1
公开(公告)日：1993-12-29
申请号：EP88910206.7
申请日：1988-10-31
申请人： EASTMAN CHEMICAL COMPANY
发明人： PUCKETTE, Thomas, Allen
IPC分类号： C07F9/50
CPC分类号： C07F9/5027 , C07F9/5063
摘要： A process is disclosed for preparing bidentate ligands of formula (I), wherein: each Ar is independently selected from aromatic ring compounds having 6 up to 14 carbon atoms, e.g., phenyl, naphthyl, phenanthryl and anthracenyl; the x bonds and the y bonds are attached to adjacent carbon atoms on the ring structures; each R, when present as a substituent, is independently selected from alkyl, alkoxy, aryloxy, aryl, aralkyl, alkaryl, alkoxyalkyl, cycloaliphatic, halogen, alkanoyl, alkanoyloxy, alkoxycarbonyl, carboxyl, cyano or formyl radicals; n is a whole number in the range of 0-4 where Ar is phenyl; 0-6 where Ar is naphthyl; and 0-8 where Ar is phenanthryl or anthracenyl; each R1 and R2 is independently selected from alkyl, aryl, aralkyl, alkaryl or cycloaliphatic radicals, or substituted derivatives thereof; each R3 and R4 is independently selected from hydrogen and the R1 substituents; each of the above alkyl groups or moieties is straight or branched chain of 1-20 carbons; each aryl group contains 6-10 ring carbons; each cycloaliphatic group contains from 4-8 ring carbons; each Y is independently selected from the elements N, P, As, Sb and Bi; and substituted derivatives include others, amines, amides, sulfonic acids, esters, hydroxyl groups and alkoxy groups. The invention process comprises coupling two molecules of a reactant of formula (II) by maintaining a redox reaction system comprising said reactant, a polar aprotic solvent, a nickel compound and a reducing agent at a temperature and for a time sufficient to form the desired bidentate ligand.

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