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1. 发明授权

EP2286899B1 Electrolytic eluent generator and method of use 无效
标题翻译：电解发生器用于生产洗脱液和使用
公开(公告)号：EP2286899B1
公开(公告)日：2014-03-05
申请号：EP10009548.8
申请日：2003-09-09
申请人： Dionex Corporation
发明人： Liu, Yan , Avdalovic, Nebojsa
IPC分类号： B01D61/44 , C25B1/14 , C25B1/22 , G01N30/26 , C02F1/469
CPC分类号： B01D69/02 , B01D15/16 , B01D15/166 , B01D61/44 , B01D61/48 , B01D69/141 , G01N30/34 , G01N30/96 , G01N2030/965 , Y10T436/25

2. 发明公开

EP1897601A1 Large capacity acid or base generator and method of use 有权
标题翻译： Säuren-oder Basenerzeuger von hoherKapazitätund Verwendungsverfahren
公开(公告)号：EP1897601A1
公开(公告)日：2008-03-12
申请号：EP07019561.5
申请日：1999-01-28
申请人： DIONEX CORPORATION
发明人： Liu, Yan , Small, Hamish , Avdalovic, Nebojsa
IPC分类号： B01D15/08 , G01N30/02 , B01J47/08 , B01D61/44
CPC分类号： G01N30/96 , C25B1/16 , C25B1/22 , G01N30/02 , G01N30/34 , G01N2030/965 , Y10T436/25 , B01D15/36 , B01D15/426
摘要： A method of generating a base comprising the steps of:
(a) providing a cation source in a cation source reservoir (10),
(b) flowing an aqueous liquid stream through a first base generation chamber (19) separated from said cation source reservoir by a first barrier (14) substantially preventing liquid flow while providing a cation transport bridge,
(c) applying an electric potential between an anode (16) in electrical communication with said cation source reservoir and a cathode (18) in electrical communication with said first base generation chamber to electrolytically generate hydroxide ions in said first base generation chamber and to cause cations in said cation source reservoir to electromigrate toward said first barrier and to be transported across said first barrier toward said cathode to combine with said hydroxide ions generated at the cathode to form cation hydroxide, and
(d) removing the cation hydroxide in an aqueous liquid stream (21) as an effluent from said first base generation chamber.
摘要翻译：一种产生基底的方法，包括以下步骤：（a）在阳离子源储存器（10）中提供阳离子源，（b）使水性液体流流过与所述阳离子源储存器分离的第一基本产生室（19）通过基本上防止液体流动同时提供阳离子输送桥的第一屏障（14），（c）在与所述阳离子源储存器电连通的阳极（16）和与所述阳离子源储存器电连通的阴极（18）之间施加电位，第一碱基产生室，用于在所述第一碱性发生室中电解产生氢氧根离子，并使所述阳离子源储存器中的阳离子电迁移至所述第一屏障，并将所述第一屏障转移到所述阴极，以与所述第一屏障中产生的所述氢氧根离子结合阴极以形成阳离子氢氧化物，和（d）将水性液体流（21）中的阳离子氢氧化物作为来自所述第一碱基的流出物屠房。

3. 发明公开

EP2286899A1 Electrolytic eluent generator and method of use 无效
标题翻译： ELEKTROLYTISCHER发电机ZER HERSTELLUNG VON ELUIERUNGSMITTEL UND DESSEN VERWENDUNG
公开(公告)号：EP2286899A1
公开(公告)日：2011-02-23
申请号：EP10009548.8
申请日：2003-09-09
申请人： Dionex Corporation
发明人： Liu, Yan , Avdalovic, Nebojsa
IPC分类号： B01D61/44 , C25B1/14 , C25B1/22 , G01N30/26 , C02F1/469
CPC分类号： B01D69/02 , B01D15/16 , B01D15/166 , B01D61/44 , B01D61/48 , B01D69/141 , G01N30/34 , G01N30/96 , G01N2030/965 , Y10T436/25
摘要： Apparatus comprising:
(a) a source of first ions in a substantially non-flowing solution (302) adjacent an aqueous liquid in a first acid or base generation zone, said first ion source and first zone being separated by a first barrier portion (306a) substantially preventing liquid flow through the first barrier portion and transporting ions only of the same charge as said first ions,
(b) a source of second ions of opposite charge to said first ions in a substantially non-flowing solution (302) adjacent an aqueous liquid in a second acid or base generation zone, said second ion source and second zone being separated by a second barrier portion (306b) substantially preventing liquid flow through the second barrier portion and transporting ions only of the same charge as said second ions, said second barrier portion being of opposite charge to said first barrier portion, to form a salt-containing solution therein suitable for use as an eluent for liquid chromatography, and
(c) a first electrode (312) in electrical communication with said first zone and a second electrode (314) in electrical communication with said second zone, said first and second electrodes being disposed so that, when attached to a power source, current passes between said first and second electrodes through said first and second zones.
摘要翻译：一种装置，包括：（a）在第一酸或碱产生区中邻近水性液体的基本不流动的溶液（302）中的第一离子源，所述第一离子源和第一区由第一阻挡部分（306a）分隔开）基本上防止液体流过第一阻挡部分并仅传输与所述第一离子相同的电荷的离子，（b）相邻电荷的第二离子源与基本上不流动的溶液（302）中的所述第一离子源相邻所述第二离子源和第二区由第二阻挡部分（306b）隔开，基本上防止液体流过第二阻挡部分并仅传输与所述第二离子相同电荷的离子，所述第二阻挡部分与所述第一阻挡部分相反，以形成其中适合用作液相色谱的洗脱液的含盐溶液，和（c）第一电极与所述第一区电连通的第二电极（312）和与所述第二区域电连通的第二电极（314），所述第一和第二电极设置成使得当附接到电源时，电流在所述第一和第二区域之间通过电极穿过所述第一和第二区域。

4. 发明公开

EP1867384A1 Electrolytic eluent generator and method of use 有权
标题翻译：发电机电机和电动机Verwendungsverfahren
公开(公告)号：EP1867384A1
公开(公告)日：2007-12-19
申请号：EP07017726.6
申请日：2003-09-09
申请人： DIONEX CORPORATION
发明人： Liu, Yan , Avdalovic, Nebojsa
IPC分类号： B01D61/44 , C25B1/14 , C25B1/22 , G01N30/26 , C02F1/469 , B01D69/02 , B01D69/14
CPC分类号： B01D69/02 , B01D15/16 , B01D15/166 , B01D61/44 , B01D61/48 , B01D69/141 , G01N30/34 , G01N30/96 , G01N2030/965 , Y10T436/25
摘要： An acid or base is generated in an aqueous solution by the steps of: (a) providing a source of first ions (40) adjacent an aqueous liquid in a first acid or base generation zone (50), separated by a first barrier (46) (e.g., anion exchange membrane) substantially preventing liquid flow and transporting ions only of the same charge as said first ions, (b) providing a source of second ions of opposite charge (40) adjacent an aqueous liquid in a second acid or base generation zone (48), separated by a second barrier (44) transporting ions only of the same charge as the second ions, and (c) transporting ions across the first barrier by applying an electrical potential (52, 54) through said first and second zones and a base-containing aqueous solution in the other one which may be combined to form a salt (62). Also electrolytic apparatus for performing the above method. The product solutions can be used as an element for a chromatographic separation medium (70). The element can be regenerated in order to reuse the ions by means of a membrane suppressor (74).
摘要翻译：通过以下步骤在水溶液中产生酸或碱：（a）在第一酸或碱产生区（50）中提供邻近水性液体的第一离子源（40），由第一阻挡层（46 ）（例如，阴离子交换膜）基本上防止液体流动并仅传输与所述第一离子相同电荷的离子，（b）在第二酸或碱中提供与水性液体相邻的相反电荷（40）的第二离子源由第二屏障（44）隔开，所述第二屏障（44）仅传输与第二离子相同的电荷的离子，和（c）通过施加电势（52,54）通过所述第一离子和/ 第二区和另一个中的含碱的水溶液，其可以组合形成盐（62）。还有用于执行上述方法的电解装置。产品溶液可用作色谱分离介质的一种元素（70）。可以再生该元件以便通过膜抑制器（74）重新使用离子。

5. 发明授权

EP1867384B1 Electrolytic eluent generator and method of use 有权
标题翻译：发生器，用于导电洗脱液和相关的使用方法
公开(公告)号：EP1867384B1
公开(公告)日：2010-11-17
申请号：EP07017726.6
申请日：2003-09-09
申请人： DIONEX CORPORATION
发明人： Liu, Yan , Avdalovic, Nebojsa
IPC分类号： B01D61/44 , C25B1/14 , C25B1/22 , G01N30/26 , C02F1/469 , B01D69/02 , B01D69/14
CPC分类号： B01D69/02 , B01D15/16 , B01D15/166 , B01D61/44 , B01D61/48 , B01D69/141 , G01N30/34 , G01N30/96 , G01N2030/965 , Y10T436/25

6. 发明公开

EP1851533A2 ION CHROMATOGRAPHY SYSTEM WITH CATALYTIC GAS ELIMINATION 有权
标题翻译：与催化气体分离IONENCHROMATOGRAFIESYSTEM
公开(公告)号：EP1851533A2
公开(公告)日：2007-11-07
申请号：EP06734823.5
申请日：2006-02-10
申请人： DIONEX CORPORATION
发明人： Liu, Yan , Pohl, Christopher A. , Avdalovic, Nebojsa , Riviello, John M. , Siriraks, Archava
IPC分类号： G01N30/96
CPC分类号： G01N30/96 , G01N30/62 , G01N2030/965
摘要： A liquid chromatographic system is provided including catalytically combining hydrogen and oxygen gases in the chromatography eluent stream in a catalytic gas elimination chamber (31), to form water and thereby reduce the gas content in the eluent stream. Also, a liquid ion chromatographic system in which the effluent from the detector (14) is recycled to a membrane suppressor (12) and then is mixed with a source of eluent (18) for recycle to the chromatographic column (10).

7. 发明授权

EP1851533B1 ION CHROMATOGRAPHY SYSTEM WITH CATALYTIC GAS ELIMINATION 有权
标题翻译：与催化气体分离IONENCHROMATOGRAFIESYSTEM
公开(公告)号：EP1851533B1
公开(公告)日：2015-10-28
申请号：EP06734823.5
申请日：2006-02-10
申请人： DIONEX CORPORATION
发明人： Liu, Yan , Pohl, Christopher A. , Avdalovic, Nebojsa , Riviello, John M. , Siriraks, Archava
IPC分类号： G01N30/96
CPC分类号： G01N30/96 , G01N30/62 , G01N2030/965

8. 发明授权

EP1897601B1 Large capacity acid or base generator and method of use 有权
标题翻译：的高容量和使用的方法的酸或碱产生
公开(公告)号：EP1897601B1
公开(公告)日：2012-04-25
申请号：EP07019561.5
申请日：1999-01-28
申请人： DIONEX CORPORATION
发明人： Liu, Yan , Small, Hamish , Avdalovic, Nebojsa
IPC分类号： C25B1/16 , C25B1/22 , G01N30/34
CPC分类号： G01N30/96 , C25B1/16 , C25B1/22 , G01N30/02 , G01N30/34 , G01N2030/965 , Y10T436/25 , B01D15/36 , B01D15/426

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