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    • 7. 发明公开
    • Electrolytic eluent generator and method of use
    • ELEKTROLYTISCHER发电机ZER HERSTELLUNG VON ELUIERUNGSMITTEL UND DESSEN VERWENDUNG
    • EP2286899A1
    • 2011-02-23
    • EP10009548.8
    • 2003-09-09
    • Dionex Corporation
    • Liu, YanAvdalovic, Nebojsa
    • B01D61/44C25B1/14C25B1/22G01N30/26C02F1/469
    • B01D69/02B01D15/16B01D15/166B01D61/44B01D61/48B01D69/141G01N30/34G01N30/96G01N2030/965Y10T436/25
    • Apparatus comprising:
      (a) a source of first ions in a substantially non-flowing solution (302) adjacent an aqueous liquid in a first acid or base generation zone, said first ion source and first zone being separated by a first barrier portion (306a) substantially preventing liquid flow through the first barrier portion and transporting ions only of the same charge as said first ions,
      (b) a source of second ions of opposite charge to said first ions in a substantially non-flowing solution (302) adjacent an aqueous liquid in a second acid or base generation zone, said second ion source and second zone being separated by a second barrier portion (306b) substantially preventing liquid flow through the second barrier portion and transporting ions only of the same charge as said second ions, said second barrier portion being of opposite charge to said first barrier portion, to form a salt-containing solution therein suitable for use as an eluent for liquid chromatography, and
      (c) a first electrode (312) in electrical communication with said first zone and a second electrode (314) in electrical communication with said second zone, said first and second electrodes being disposed so that, when attached to a power source, current passes between said first and second electrodes through said first and second zones.
    • 一种装置,包括:(a)在第一酸或碱产生区中邻近水性液体的基本不流动的溶液(302)中的第一离子源,所述第一离子源和第一区由第一阻挡部分(306a)分隔开 )基本上防止液体流过第一阻挡部分并仅传输与所述第一离子相同的电荷的离子,(b)相邻电荷的第二离子源与基本上不流动的溶液(302)中的所述第一离子源相邻 所述第二离子源和第二区由第二阻挡部分(306b)隔开,基本上防止液体流过第二阻挡部分并仅传输与所述第二离子相同电荷的离子, 所述第二阻挡部分与所述第一阻挡部分相反,以形成其中适合用作液相色谱的洗脱液的含盐溶液,和(c)第一电极 与所述第一区电连通的第二电极(312)和与所述第二区域电连通的第二电极(314),所述第一和第二电极设置成使得当附接到电源时,电流在所述第一和第二区域之间通过 电极穿过所述第一和第二区域。
    • 9. 发明公开
    • Electrolytic eluent generator and method of use
    • 发电机电机和电动机Verwendungsverfahren
    • EP1867384A1
    • 2007-12-19
    • EP07017726.6
    • 2003-09-09
    • DIONEX CORPORATION
    • Liu, YanAvdalovic, Nebojsa
    • B01D61/44C25B1/14C25B1/22G01N30/26C02F1/469B01D69/02B01D69/14
    • B01D69/02B01D15/16B01D15/166B01D61/44B01D61/48B01D69/141G01N30/34G01N30/96G01N2030/965Y10T436/25
    • An acid or base is generated in an aqueous solution by the steps of: (a) providing a source of first ions (40) adjacent an aqueous liquid in a first acid or base generation zone (50), separated by a first barrier (46) (e.g., anion exchange membrane) substantially preventing liquid flow and transporting ions only of the same charge as said first ions, (b) providing a source of second ions of opposite charge (40) adjacent an aqueous liquid in a second acid or base generation zone (48), separated by a second barrier (44) transporting ions only of the same charge as the second ions, and (c) transporting ions across the first barrier by applying an electrical potential (52, 54) through said first and second zones and a base-containing aqueous solution in the other one which may be combined to form a salt (62). Also electrolytic apparatus for performing the above method. The product solutions can be used as an element for a chromatographic separation medium (70). The element can be regenerated in order to reuse the ions by means of a membrane suppressor (74).
    • 通过以下步骤在水溶液中产生酸或碱:(a)在第一酸或碱产生区(50)中提供邻近水性液体的第一离子源(40),由第一阻挡层(46 )(例如,阴离子交换膜)基本上防止液体流动并仅传输与所述第一离子相同电荷的离子,(b)在第二酸或碱中提供与水性液体相邻的相反电荷(40)的第二离子源 由第二屏障(44)隔开,所述第二屏障(44)仅传输与第二离子相同的电荷的离子,和(c)通过施加电势(52,54)通过所述第一离子和/ 第二区和另一个中的含碱的水溶液,其可以组合形成盐(62)。 还有用于执行上述方法的电解装置。 产品溶液可用作色谱分离介质的一种元素(70)。 可以再生该元件以便通过膜抑制器(74)重新使用离子。