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1. 发明授权

EP1954722B1 VERFAHREN ZUR HERSTELLUNG VON HOCHREAKTIVEN ISOBUTENHOMO- ODER -COPOLYMEREN MITTELS METALLHALTIGER KATALYSATORKOMPLEXE 有权
标题翻译：用于生产高活性异丁烯均聚物或共聚物BY金属催化剂络合物
公开(公告)号：EP1954722B1
公开(公告)日：2010-06-30
申请号：EP06819481.0
申请日：2006-11-15
申请人： BASF SE
发明人： HANEFELD, Phillip , SIGL, Marcus , BÖHM, Volker , RÖPER, Michael , WALTER, Hans-Michael , KROSSING, Ingo
IPC分类号： C08F4/12 , C08F10/10
CPC分类号： C07F5/062 , C08F10/10 , C08F110/10 , C08F4/12 , C08F4/14 , C08F2500/03
摘要： The invention relates to the production of highly reactive isobutylene homo- or copolymers with Mn = 500 to 1,000,000 by polymerizing isobutylene in liquid phase in the presence of a dissolved, dispersed or supported metal-containing catalyst complex by using, as a catalyst complex, a compound (I) Zn+ [MXa(OR)b]n- Lx (I), in which: M represents a metal atom from the group consisting of boron, aluminum, gallium, indium and thallium; R represents aliphatic, heterocyclic or aromatic hydrocarbon radicals, which are independent of one another, each have 1 to 18 carbon atoms and which can contain fluorine atoms or have silyl groups containing C1 to C18 hydrocarbon radicals; X represents halogen atoms; Z represents proton (n = 1), optionally substituted ammonia (n=1) or n-valent metal cation; L represents neutral solvent molecules; a represents an integer ranging from 0 to 3; b represents an integer ranging from 1 to 4, a + b being equal to 4, and; x = 0.

2. 发明公开

EP1954728A1 VERFAHREN ZUR HERSTELLUNG VON HOCHREAKTIVEN ISOBUTENHOMO- ODER -COPOLYMEREN AUS TECHNISCHEN C4-KOHLENWASSERSTOFFSTRÖMEN MITTELS PROTONENSAURER KATALYSATORKOMPLEXE 审中-公开
标题翻译：工艺用于生产技术C4烃流高活性异丁烯均聚物或共聚物BY质子酸催化剂络合物
公开(公告)号：EP1954728A1
公开(公告)日：2008-08-13
申请号：EP06819482.8
申请日：2006-11-15
申请人： BASF SE
发明人： HANEFELD, Phillip , BÖHM, Volker , SIGL, Marcus , CHALLAND, Nina , RÖPER, Michael , WALTER, Hans-Michael
IPC分类号： C08F10/10 , C08F4/52
CPC分类号： C08F10/10 , C08F110/10 , C08F4/52 , C08F2500/04
摘要： The invention relates to the production of highly reactive isobutylene homo- or copolymers with Mn = 500 to 1,000,000 by polymerizing isobutylene from technical flows of C4-hydrocarbon having a isobutylene content ranging from 1 to 90 % by weight in liquid phase in the presence of a dissolved, dispersed or supported catalyst complex by using, as a catalyst complex, a Bronsted acid compound (I) [H+]k Yk- Lx (I) Yk- weakly coordinating k-valent anion, which contains at least one carbon-containing grouping; L represents neutral solvent molecules, and; x = 0.

3. 发明公开

EP2139837A1 VERFAHREN ZUR HERSTELLUNG VON AMEISENSÄURE 审中-公开
标题翻译： VERFAHREN ZUR HERSTELLUNG VONAMEISENSÄURE
公开(公告)号：EP2139837A1
公开(公告)日：2010-01-06
申请号：EP08717979.2
申请日：2008-03-18
申请人： BASF SE
发明人： CHALLAND, Nina , SAVA, Xavier , RÖPER, Michael
IPC分类号： C07C51/00 , C07C51/02 , C07C53/06 , C07C53/02
CPC分类号： C07C51/00 , B01J31/0202 , B01J31/0237 , B01J31/0271 , B01J31/2404 , B01J2231/625 , B01J2531/821 , C07C51/02 , C07C53/06 , C07C53/02
摘要： The invention relates to a method for producing formic acid by generating the corresponding ammonium formate by means of catalytic hydrogenation of carbon dioxide with hydrogen on a catalyst comprising a metal of groups 8 through 10 of the periodic system, in the presence of a primary, secondary, and/or tertiary amine, and by cleaving the ammonium formate by heating it in formic acid and the amine, characterized in that the primary, secondary, or tertiary amine is selected from the amines of formula I or the mixtures thereof, R1 through R3 being identical or different and being hydrogen, linear or branched alkyl radicals having 1 to 18 carbon atoms, cycloaliphatic radicals having 5 to 7 carbon atoms, aryl radicals and/or aryl alkyl radicals, at least one of the radicals R1 to R3 carrying a hydroxyl group, and that said hydrogenation is performed in a solvent having a boiling point of ≥105°C at normal pressure, and that the formic acid is obtained in the hydrogenation reaction mixture comprising the high-boiling solvent by thermal cleavage of the ammonium formate and distillation of the formic acid.
摘要翻译：本发明涉及一种生产甲酸的方法，该方法通过在含有周期系统第8-10族金属的催化剂上，用二氧化碳用氢催化氢化，在伯，仲，和/或叔胺，并且通过在甲酸和胺中将甲酸铵加热裂解甲酸铵，其特征在于伯胺，仲胺或叔胺选自式I的胺或其混合物，R1至R3 相同或不同并且是氢，具有1至18个碳原子的直链或支链烷基，具有5至7个碳原子的环脂族基团，芳基和/或芳基烷基，至少一个基团R 1至R 3携带羟基并且所述氢化在常压下在沸点≥105℃的溶剂中进行，并且甲酸在氢化反应混合物中获得 e通过甲酸铵的热裂解和甲酸的蒸馏包含高沸点溶剂。

4. 发明公开

EP1954727A1 VERFAHREN ZUR HERSTELLUNG VON HOCHREAKTIVEN ISOBUTENHOMO- ODER -COPOLYMEREN MITTELS BORHALTIGER KATALYSATORKOMPLEXE 审中-公开
标题翻译：用于生产高活性异丁烯均聚物或含硼BY催化剂络合物共聚物
公开(公告)号：EP1954727A1
公开(公告)日：2008-08-13
申请号：EP06807816.1
申请日：2006-11-15
申请人： BASF SE
发明人： HANEFELD, Phillip , BÖHM, Volker , SIGL, Marcus , CHALLAND, Nina , RÖPER, Michael , WALTER, Hans-Michael , VOIT, Brigitte , KUEHN, Fritz, Elmar , HIJAZI, Ahmed , NARAYANAN, Radha, Krishnan
IPC分类号： C08F10/10 , C07F5/02 , C08F4/52
CPC分类号： C07F5/027 , C08F10/10 , C08F110/10 , C08F4/52 , C08F2500/04
摘要： The invention relates to the production of highly reactive isobutylene homo- or copolymers with Mn = 500 to 45,000 by polymerizing isobutylene in liquid phase in the presence of a dissolved, dispersed or supported boron-containing catalyst complex by using, as a catalyst complex, a Bronsted compound (I) [H+]m+1 [R1R2R3B-(-Am+-BR5R6-)n-R4](m+1)- Lx (I), in which: R1 to R6 represent aliphatic, heterocyclic or aromatic fluorine-containing hydrocarbon radicals, which are independent of one another and which each have 1 to 18 carbon atoms or silyl groups containing C1 to C18 hydrocarbon radicals; A represents a bridge member that, via its nitrogen atoms forms bonds which are covalent to the boron atoms; L represents neutral solvent molecules; n = 0 or 1; m = 0 or 1, and; x ≥ 0.

5. 发明授权

EP1641739B1 VERFAHREN ZUR KONTINUIERLICHEN HERSTELLUNG EINER VERBINDUNG, DIE MINDESTENS ZWEI FUNKTIONELLE GRUPPEN TRÄGT 有权
标题翻译：方法链路的连续生产，至少有两个官能团熊
公开(公告)号：EP1641739B1
公开(公告)日：2014-04-09
申请号：EP04739794.8
申请日：2004-06-11
申请人： BASF SE
发明人： STÜER, Wolfram , SCHEIDEL, Jens , VOSS, Hartwig , BASSLER, Peter , RÖPER, Michael
IPC分类号： C07C67/347 , C07C69/593 , C07C67/56 , C07C67/303 , C07C51/353 , C07C51/47 , C07C57/13 , C07C51/36 , C07C55/14
CPC分类号： C07C51/36 , C07C51/353 , C07C51/47 , C07C67/303 , C07C67/347 , C07C67/56 , C07C57/13 , C07C55/14 , C07C69/44 , C07C69/593

6. 发明授权

EP1802559B1 VERFAHREN ZUR HERSTELLUNG EINES C4-OLEFIN-GEMISCHES DURCH SELEKTIVHYDRIERUNG UND METATHESEVERFAHREN ZUR VERWENDUNG DIESES STROMS 有权转让
标题翻译：生产由选择性复分解并利用这种流的C4烯烃混合物
公开(公告)号：EP1802559B1
公开(公告)日：2012-08-01
申请号：EP05796208.6
申请日：2005-10-13
申请人： BASF SE
发明人： STEPHAN, Jürgen , BRODHAGEN, Andreas , SCHUBERT, Markus , POPLOW, Frank , RÖPER, Michael , HILL, Thomas
IPC分类号： C07C5/05 , C07C11/08 , C07C6/04 , C07C11/10 , C07C11/107
CPC分类号： C07C11/08 , C07C6/04 , C07C2523/44 , C07C11/107 , C07C11/10

7. 发明授权

EP1296992B1 PHOSPHACYCLOHEXANE UND IHRE VERWENDUNG IN DER HYDROFORMYLIERUNG VON OLEFINEN 有权
标题翻译： Phosphacyclohexanes及其用途烯烃氢甲酰化反应
公开(公告)号：EP1296992B1
公开(公告)日：2008-04-23
申请号：EP01960378.6
申请日：2001-06-25
申请人： BASF SE
发明人： MACKEWITZ, Thomas , AHLERS, Wolfgang , ZELLER, Edgar , RÖPER, Michael , PACIELLO, Rocco , KNOLL, Konrad , PAPP, Rainer , VOSS, Hartwig
IPC分类号： C07F9/6568 , C07C45/50 , B01J31/24
CPC分类号： B01J31/2466 , B01J31/20 , B01J31/2423 , B01J31/2433 , B01J2231/321 , B01J2531/80 , B01J2531/822 , C07C45/50 , C07F9/65683 , C07F15/0026 , C07F15/0053 , C07F15/0066 , C07F15/008 , C07F15/045 , C07F15/065 , C07C47/21 , C07C47/02
摘要： The invention relates to phosphacyclohexanes of general formulae I and II, wherein the following designations, among others, apply: R can represent hydrogen, C1-100-alkyl, C7-20-aralkyl, C7-20-alkaryl, and C6-12-aryl; R to R can independently represent hydrogen, C1-20-alkyl, C7-20-aralkyl, C7-20-alkaryl, and C6-12-aryl; W, W' can independently represent single bonds or bridges comprising 1 to 20 carbon atoms, which can form part of a cyclic or aromatic group and can be interrupted by heteroatoms. Said phosphacyclohexanes are used as ligands in transition metal complexes of transition metals belonging to subgroup VIII of the periodic table.

8. 发明授权

EP1868977B1 HERSTELLUNG VON (CO)TENSIDEN DURCH UMSETZUNG VON POLYOLEN MIT OLEFINEN 有权
标题翻译：制备（CO）通过与烯烃反应的多元醇的表面活性剂
公开(公告)号：EP1868977B1
公开(公告)日：2009-10-14
申请号：EP06725585.1
申请日：2006-04-05
申请人： BASF SE
发明人： STEPHAN, Jürgen , RÖPER, Michael , HEIDEMANN, Thomas , TRILLER, Michael , TROPSCH, Jürgen
IPC分类号： C07C43/13 , C07C41/06 , C08G65/00 , C08G65/34 , C11D1/66
CPC分类号： C07C41/06 , C07C43/135 , C08G65/329 , C11D1/72 , C11D1/721 , C11D3/3707 , Y02P20/582
摘要： The invention relates to a method for producing polyolalkylethers by reacting at least three compounds having hydroxy functions with olefins in the presence of acidic catalysts at temperatures of between 20 - 250 °C and pressures of between 0,5 - 10 bar. The olefins correspond to general formula (I), wherein R 1 represents hydrogen and R 2 is linear or branched carbon radicals having 7 - 28 carbon atoms, or R 1 and R 2 respectively represent linear or branched carbon radicals having 1 - 27 carbon atoms, whereby the number of carbon atoms of R 1 and R 2 is, at maximum, 28. The invention also relates to polyolalkylethers which are derived from compounds having at least three hydroxy functions, or all hydroxy functions until one is replaced by a grouping of general formula (VIII). The invention further relates to said polyolalkylethers as surfactants and said washing and cleaning agents containing polyolalkylethers.

9. 发明授权

EP1539666B1 VERFAHREN ZUR HERSTELLUNG VON DIALDEHYDEN UND/ODER ETHYLENISCH UNGESÄTTIGTEN MONOALDEHYDEN DURCH HYDROFORMYLIERUNG ETHYLENISCH UNGESÄTTIGTER VERBINDUNGEN 有权
标题翻译：用于生产二醛和/或烯属不饱和一元醛通过氢甲酰化的烯属不饱和化合物的
公开(公告)号：EP1539666B1
公开(公告)日：2009-01-07
申请号：EP03748014.2
申请日：2003-09-12
申请人： BASF SE
发明人： VOLLAND, Martin , AHLERS, Wolfgang , EBEL, Klaus , PACIELLO, Rocco , RÖPER, Michael , MACKEWITZ, Thomas , BÖHM, Volker , SAVA, Xavier , LÖBER, Oliver , BEY, Oliver , STEPHAN, Jürgen , HAESE, Frank
IPC分类号： C07C45/50 , C07C47/21 , C07C47/12 , C07F9/6558
CPC分类号： C07F9/6596 , C07C45/50 , C07F9/5721 , C07F9/5728 , C07F9/65522 , C07F9/65586 , C07F9/65842 , C07F9/65848 , C07C47/12 , C07C47/21
摘要： The invention relates to a method for producing dialdehydes and/or ethylenically unsaturated monoaldehydes by reacting at least one compound with at least two ethylenically unsaturated double bonds with carbon monoxide and hydrogen in the presence of a hydroformylating catalyst with at least one complex of a metal of subgroup VIII. The subgroup comprises at least pnicogen chelate ligands.

10. 发明公开

EP1954722A1 VERFAHREN ZUR HERSTELLUNG VON HOCHREAKTIVEN ISOBUTENHOMO- ODER -COPOLYMEREN MITTELS METALLHALTIGER KATALYSATORKOMPLEXE 有权
标题翻译：用于生产高活性异丁烯均聚物或共聚物BY金属催化剂络合物
公开(公告)号：EP1954722A1
公开(公告)日：2008-08-13
申请号：EP06819481.0
申请日：2006-11-15
申请人： BASF SE
发明人： HANEFELD, Phillip , SIGL, Marcus , BÖHM, Volker , RÖPER, Michael , WALTER, Hans-Michael , KROSSING, Ingo
IPC分类号： C08F4/12 , C08F10/10
CPC分类号： C07F5/062 , C08F10/10 , C08F110/10 , C08F4/12 , C08F4/14 , C08F2500/03
摘要： The invention relates to the production of highly reactive isobutylene homo- or copolymers with Mn = 500 to 1,000,000 by polymerizing isobutylene in liquid phase in the presence of a dissolved, dispersed or supported metal-containing catalyst complex by using, as a catalyst complex, a compound (I) Zn+ [MXa(OR)b]n- Lx (I), in which: M represents a metal atom from the group consisting of boron, aluminum, gallium, indium and thallium; R represents aliphatic, heterocyclic or aromatic hydrocarbon radicals, which are independent of one another, each have 1 to 18 carbon atoms and which can contain fluorine atoms or have silyl groups containing C1 to C18 hydrocarbon radicals; X represents halogen atoms; Z represents proton (n = 1), optionally substituted ammonia (n=1) or n-valent metal cation; L represents neutral solvent molecules; a represents an integer ranging from 0 to 3; b represents an integer ranging from 1 to 4, a + b being equal to 4, and; x = 0.

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