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1. 发明公开

EP0827516A1 POLYMERE AUS OLEFINISCH UNGESÄTTIGTEN MONOMEREN 失效
标题翻译：烯属不饱和单体的聚合物
公开(公告)号：EP0827516A1
公开(公告)日：1998-03-11
申请号：EP96919746.0
申请日：1996-05-09
申请人： BASF AKTIENGESELLSCHAFT
发明人： LIPPERT, Ferdinand , HÖHN, Arthur , SCHAUSS, Eckard
IPC分类号： C08F4 , C08F10
CPC分类号： C08F10/00 , C08F4/80
摘要： Polymers are obtained by polymerising olefinically unsaturated monomers in the presence of a catalyst system that contains as active elements (a) a salt of a metal of group VIIIB of the periodic system; (b) one or several compounds selected in the group of protonic acids and Lewis acids; (c) a chelated compound having the general formula (I) R?1R2E1-Z-E2R3R4¿, in which the substituents and indexes have the following meanings: E1, E2 stand for an element of group VA of the periodic system; Z stands for a bridging structural unit made of one, two or three substructural units of elements of groups IVA, VA, VIA of the periodic system; R1 to R4 stand for substituents selected in the group of C¿1?-C20 organic carbon and C3-C30 organic silicium residues that may contain one or several elements of groups IVA, VA, VIA and VIIA of the periodic system.

2. 发明授权

EP1423474B1 POLYMERZUSAMMENSETZUNG, ENTHALTEND WENIGSTENS EIN MITTELMOLEKULARES REAKTIVES POLYISOBUTEN 有权
标题翻译：聚合物组合至少包含一个中心分子活性聚异丁烯
公开(公告)号：EP1423474B1
公开(公告)日：2006-08-16
申请号：EP02772220.6
申请日：2002-08-28
申请人： BASF Aktiengesellschaft
发明人： LANGE, Arno , HÜFFER, Stefan , LANG, Gabriele , MACH, Helmut , RATH, Hans, Peter , SCHAUSS, Eckard
IPC分类号： C08L23/20 , C08L23/22
CPC分类号： C08L51/06 , C08L21/00 , C08L23/22 , C08L23/26 , C08L2666/04
摘要： The invention relates to a polymer composition containing at component that contains at least one polyisobutene based on one middle molecular weight polyisobutene and at least another polymer different therefrom.

3. 发明公开

EP1546213A1 VERFAHREN ZUR HERSTELLUNG VON POLYISOBUTEN 有权
标题翻译：用于生产聚异丁烯
公开(公告)号：EP1546213A1
公开(公告)日：2005-06-29
申请号：EP03798168.5
申请日：2003-09-18
申请人： BASF AKTIENGESELLSCHAFT
发明人： RATH, Hans-Peter , HÜFFER, Stephan , LANG, Gabriele , LANGE, Arno , SCHAUSS, Eckard
IPC分类号： C08F4/14 , C08F10/10
CPC分类号： C08F10/10 , C08F110/10 , C08F4/14 , C08F2500/03 , C08F2500/02
摘要： Disclosed is a method for producing polyisobutene containing at least 75 mole percent of terminal vinylidene groupings. According to the inventive method, isobutene or hydrocarbon mixtures containing isobutene is/are polymerized in a liquid phase in the presence of a boron trifluoride complex catalyst having the composition a(BF3): b(Co1): c(Co2), wherein Co1 represents at least one tertiary alcohol, Co2 represents a compound selected among water, primary alcohols, secondary alcohol, dialkyl ethers, alkanecarboxylic acids, and phenols, the ratio c:b ranges from 0.9 to 1.8, and the ratio (b+c):a ranges from 0.9 to 3.0.

4. 发明公开

EP1404726A2 NIEDER- UND HOCHMOLEKULARE EMULGATOREN, INSBESONDERE AUF BASIS VON POLYISOBUTYLEN, SOWIE DEREN MISCHUNGEN 审中-公开
标题翻译： LOWER和高分子乳化剂，尤其是基于聚异丁烯和它们的混合物
公开(公告)号：EP1404726A2
公开(公告)日：2004-04-07
申请号：EP02750949.6
申请日：2002-05-17
申请人： BASF AKTIENGESELLSCHAFT
发明人： HÜFFER, Stephan , SCHWAB, Peter , SCHÜRMANN, Gregor , RATH, Hans, Peter , MACH, Helmut , SCHAUSS, Eckard
IPC分类号： C08F8/14 , C08F8/32 , B01F17/00 , C10L1/18 , C10L1/22 , C10L1/32 , C10M133/54 , C10M133/56 , C10M129/95 , C10M145/38 , C11D1/04
CPC分类号： C10L10/08 , B01F17/0028 , B01F17/005 , B01F17/0085 , B01F17/0092 , C08F8/14 , C08F110/10 , C08F2810/20 , C10L1/10 , C10L1/125 , C10L1/1266 , C10L1/1824 , C10L1/1826 , C10L1/1852 , C10L1/1857 , C10L1/191 , C10L1/198 , C10L1/1985 , C10L1/2222 , C10L1/238 , C10L1/2383 , C10L1/2387 , C10L1/328 , C10L10/02 , C10L10/04 , C10M129/76 , C10M129/95 , C10M133/16 , C10M133/56 , C10M141/02 , C10M141/06 , C10M173/00 , C10M2207/288 , C10M2215/12 , C10M2215/28 , C10N2210/01 , C10N2210/02 , C10N2220/021 , C10N2230/04 , C10N2230/06 , C10N2230/12 , C10N2250/022 , C11D1/008 , C11D3/3715 , C11D3/3757 , C08F2500/02 , C08F2500/03
摘要： The invention relates to low-molecular and high-molecular diblock emulsifiers, particularly based on polyisobutylene, of general formulas (Ia) and (Ib), and to mixtures thereof, whereby: La represents a polyisobutylene group having a numerical average molecular weight M¿n? ranging from 300 to 1000; L?b¿ represents a polyisobutylene group having a numerical average molecular weight M¿n? ranging from 2000 to 20000; -A- represents -O-, -N(H)- or N(R?1)-; M+¿ represents H+, an alkali metal ion, 0.5 alkaline-earth metal ions or NH¿4?+, whereby in NH¿4?+, one or more H's can be substituted by alkyl radicals; R represents a linear or branched saturated hydrocarbon radical, which supports at least one substituent selected from the group consisting of OH, NH¿2? or NH3?+¿ and optionally supports one or more C(O)H groups while optionally containing one or more non-adjacent -O- and/or secondary amines and/or tertiary amines and, in the NH¿2? or NH3?+¿ groups, one or more H's can be substituted by alkyl radicals, and; R1 represents a linear or branched saturated hydrocarbon radical, which optionally supports one or more substituents selected from the group consisting of OH, NH¿2, NH3?+ or C(O)H while optionally containing one or more non-adjacent -O- and/or secondary amines and/or tertiary amines and, in the NH¿2? or NH3?+¿ groups, one or more H's can be substituted by alkyl radicals, and the proportion of A-R on the compound of general formula (Ib) equals at least 20 wt. %.

5. 发明公开

EP0981551A1 KATALYSATORLÖSUNG ZUR POLYMERISATION VON ALPHA-OLEFINEN 失效
标题翻译： α-烯烃的催化剂溶液聚合
公开(公告)号：EP0981551A1
公开(公告)日：2000-03-01
申请号：EP98921488.7
申请日：1998-04-24
申请人： BASF AKTIENGESELLSCHAFT
发明人： GONIOUKH, Andrei , SCHAUSS, Eckard , KLIMESCH, Roger , DECKERS, Andreas , WEBER, Wilhelm
IPC分类号： C08F4/629 , C08F10/00
CPC分类号： C08F10/00 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F110/02 , Y10S526/943 , C08F4/65908 , C08F2500/12 , C08F2500/03 , C08F2500/23
摘要： The invention relates to a catalyst solution for the polymerization of α-olefins obtained by: reacting a metallocene compound with an activator compound, which is able to react with the metallocene compound in such a way that a ligand is displaced from the central atom and the resulting cationic complex is stabilized by a non-coordinating anion as ion pair; adding one or several α-olefins at a molar ratio of metallocene compound: α-olefins of between 1: 1 and 1: 100; and mixing the resulting product with at least 10 volume parts of an aliphatic hydrocarbon.

6. 发明公开

EP0827515A1 POLYMERE AUS OLEFINISCH UNGESÄTTIGTEN MONOMEREN 失效
标题翻译： POLYMERE AUS OLEFINISCH UNGESTATITTEN单体
公开(公告)号：EP0827515A1
公开(公告)日：1998-03-11
申请号：EP96914188.0
申请日：1996-05-09
申请人： BASF AKTIENGESELLSCHAFT
发明人： LIPPERT, Ferdinand , HÖHN, Arthur , SCHAUSS, Eckard
IPC分类号： C08F4 , C08F10
CPC分类号： C08F10/00 , C08F4/80
摘要： Polymers are obtained by polymerising olefinically unsaturated monomers in the presence of a metal complex having the general formula (I), in which the substituents and indexes have the following meanings: M is a metal of group VIIIB of the periodic table of elements; E1, E2 stand for an element of group VA of the periodic table of elements; Z is a bridging structural unit made of one, two or three substructural units of elements of groups IVA, VA, VIA of the periodic table of elements; R1 to R4 stand for substituents selected in the group that consists of C¿1?-C20 organic carbon residues and C3-C30 organic silicium residues which may contain one or several elements of groups IVA, VA, VIA and VIIA of the periodic table of elements; L?1, L2¿ stand for formally charged or neutral ligands; X stands for monovalent or polyvalent anions; p equals 0, 1 or 2; m, n equal 0, 1 or 2, whereas p = m x n.
摘要翻译：聚合物通过在具有通式（I）的金属配合物存在下聚合烯属不饱和单体而获得，其中取代基和指数具有以下含义：M是元素周期表中VIIIB族的金属; E1，E2代表元素周期表中的VA族元素; Z是由元素周期表第IVA，VA，VIA族元素的一个，两个或三个子结构单元构成的桥联结构单元; R1至R4表示选自由C1-C20有机碳残基和C3-C30有机硅残基组成的组中的取代基，所述有机硅残基可含有一种或多种元素周期表中的IVA，VA，VIA和VIIA族要素; L 1，L 2'代表正式带电荷或中性配体; X代表单价或多价阴离子; p等于0,1或2; m，n等于0,1或2，而p = m×n。

7. 发明公开

EP1701985A1 HERSTELLUNG HOCHREAKTIVER POLYISOBUTENE MIT NIEDRIGEM HALOGENGEHALT 有权转让
标题翻译：制备高反应性聚异丁烯卤素含量低
公开(公告)号：EP1701985A1
公开(公告)日：2006-09-20
申请号：EP04804379.8
申请日：2004-12-29
申请人： BASF Aktiengesellschaft
发明人： RATH, Hans, Peter , PERNER, Thomas , SCHAUSS, Eckard
IPC分类号： C08F8/26 , C08F10/10 , C08F4/14
CPC分类号： C08F8/26 , C08F110/10 , C08F10/10 , C08F4/14 , C08F2500/02
摘要： The invention relates to a method for producing low halogen polyisobutenes. The inventive method is characterized in that isobutene is polymerized in the presence of a catalyst which contains a halogenated Lewis acid, the catalyst is removed and/or deactivated, and the polyisobutene so obtained is brought into contact with a zeolite having an average pore size of from 5 to 15 Å.

8. 发明授权

EP1546213B1 VERFAHREN ZUR HERSTELLUNG VON POLYISOBUTEN 有权
标题翻译：用于生产聚异丁烯
公开(公告)号：EP1546213B1
公开(公告)日：2006-05-31
申请号：EP03798168.5
申请日：2003-09-18
申请人： BASF Aktiengesellschaft
发明人： RATH, Hans-Peter , HÜFFER, Stephan , LANG, Gabriele , LANGE, Arno , SCHAUSS, Eckard
IPC分类号： C08F4/14 , C08F10/10
CPC分类号： C08F10/10 , C08F110/10 , C08F4/14 , C08F2500/03 , C08F2500/02
摘要： Disclosed is a method for producing polyisobutene containing at least 75 mole percent of terminal vinylidene groupings. According to the inventive method, isobutene or hydrocarbon mixtures containing isobutene is/are polymerized in a liquid phase in the presence of a boron trifluoride complex catalyst having the composition a(BF3): b(Co1): c(Co2), wherein Co1 represents at least one tertiary alcohol, Co2 represents a compound selected among water, primary alcohols, secondary alcohol, dialkyl ethers, alkanecarboxylic acids, and phenols, the ratio c:b ranges from 0.9 to 1.8, and the ratio (b+c):a ranges from 0.9 to 3.0.

9. 发明公开

EP1012193A1 KATALYSATORZUBEREITUNG FÜR DIE (CO)POLYMERISATION VON ALK-1-ENEN 无效
标题翻译：催化剂制备为ALK-1恩恩（共）聚合
公开(公告)号：EP1012193A1
公开(公告)日：2000-06-28
申请号：EP98946384.9
申请日：1998-08-19
申请人： BASF AKTIENGESELLSCHAFT
发明人： GONIOUKH, Andrei , DECKERS, Andreas , SCHAUSS, Eckard , KLIMESCH, Roger , WEBER, Wilhelm
IPC分类号： C08F4/629 , C08F10/00
CPC分类号： C08F10/00 , C08F4/63908 , C08F4/63916 , C08F4/63922 , C08F110/02 , C08F210/16 , Y10S526/943 , C08F4/63912 , C08F2500/12 , C08F2500/03
摘要： The invention relates to a catalyst preparation suitable for the (co)polymerisation of Alk-1-enes. To obtain said preparation a metallocene complex is mixed with a C3-20-Alk-1-ene in an inert solvent and the resulting mixture is reacted in a controlled manner with a compound forming metallocene ions. The mixture obtained is diluted with an inert, non-polar, essentially aliphatic solvent. In addition, the catalyst preparation is possibly applied to a particulate substrate material.

10. 发明公开

EP1423474A2 POLYMERZUSAMMENSETZUNG, ENTHALTEND WENIGSTENS EIN MITTELMOLEKULARES REAKTIVES POLYISOBUTEN 有权
标题翻译：聚合物组合至少包含一个中心分子活性聚异丁烯
公开(公告)号：EP1423474A2
公开(公告)日：2004-06-02
申请号：EP02772220.6
申请日：2002-08-28
申请人： BASF Aktiengesellschaft
发明人： LANGE, Arno , HÜFFER, Stefan , LANG, Gabriele , MACH, Helmut , RATH, Hans, Peter , SCHAUSS, Eckard
IPC分类号： C08L23/20 , C08L23/22
CPC分类号： C08L51/06 , C08L21/00 , C08L23/22 , C08L23/26 , C08L2666/04
摘要： The invention relates to a polymer composition containing at component that contains at least one polyisobutene based on one middle molecular weight polyisobutene and at least another polymer different therefrom.

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