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    • 6. 发明公开
    • VERFAHREN ZUR HERSTELLUNG VON POLYISOBUTENEN
    • EP1343829A2
    • 2003-09-17
    • EP01991824.2
    • 2001-12-11
    • BASF AKTIENGESELLSCHAFT
    • LANGE, ArnoRATH, Hans, Peter
    • C08F10/10C08F4/06C08F4/12C08F4/16C08F4/00
    • C08F10/10C08F8/00C08F110/10C08F297/00C08F2810/30C08F2810/40C08F4/06C08F2/38C08F4/14
    • The invention relates to a method for producing polyisobutenes, wherein at least 60 mol % of the polymer chains have at least one olefinically unsaturated terminal group, by cationically polymerizing isobutene or isobutene-containing monomer mixtures in a condensed phase. The inventive method is characterized in that the polymerization is carried out in the presence of an initiator system comprising: i) a Lewis acid selected among covalent metal chlorides and metalloid chlorides, and; ii) at least one organic compound (I) having at least one functional group FG that, together with the Lewis acid, forms a carbocation or a cationogenic complex under polymerization conditions, whereby FG is selected among acyloxy, alkoxy or halogen, which are bound to a secondary or tertiary C atom, to an allylic C atom or to a benzylic C atom. Said polymerization is carried out in a solvent that is inert to the Lewis acid, whereby the Lewis acid is used in molar deficiency with regard to the functional groups FG.
    • 本发明涉及一种生产聚异丁烯的方法,其中至少60mol%的聚合物链具有至少一个烯属不饱和端基,通过使异丁烯或含异丁烯的单体混合物在缩合相中进行阳离子聚合。 本发明方法的特征在于聚合在引发剂体系存在下进行,所述引发剂体系包含:i)选自共价金属氯化物和准金属氯化物的路易斯酸,和; ii)至少一种具有至少一个官能团FG的有机化合物(I),所述官能团FG与路易斯酸一起在聚合条件下形成碳阳离子或阳离子源配合物,由此FG选自结合的酰氧基,烷氧基或卤素 到仲或叔碳原子,到烯丙基C原子或到苄基C原子。 所述聚合在对路易斯酸呈惰性的溶剂中进行,由此路易斯酸相对于官能团FG以摩尔不足进行使用。