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1. 发明公开

EP0946479A1 VERFAHREN ZUR HERSTELLUNG VON CARBONYLVERBINDUNGEN 失效
公开(公告)号：EP0946479A1
公开(公告)日：1999-10-06
申请号：EP97953759.0
申请日：1997-12-09
申请人： BASF AKTIENGESELLSCHAFT
发明人： FETZER, Thomas , DEMUTH, Dirk , RÜTTER, Heinz , MENIG, Helmuth , RESCH, Peter , RUPPEL, Wilhelm , WACHE, Harro
IPC分类号： C07B61 , C07C45 , C07C47
CPC分类号： C07C45/39 , C07C45/38 , C07C47/04 , C07C47/127
摘要： The invention relates to a method for producing carbonyl compounds of formula (I), in which R1 is a hydrogen atom or alkyl radical with between 1 and 3 C atoms; R2 is a hydrogen atom or a radical of formula (II), in which R3 is a hydrogen atom or, together with R4, an oxygen atom; R4 is the radical OR6 or, together with R3, an oxygen atom; R5 is a hydrogen atom, an alkyl radical with between 1 and 8 C atoms or a cyclohexyl or cyclopentyl radical; and R6 is an alkyl radical with between 1 and 4 C atoms, a cyclohexyl or cyclopentyl radical or a radical of the formula -CH¿2?-CHO or -CH2-CH2-O-CH2-CHO. According to said method, the carbonyl compounds are produced by gas phase oxidation of methanol or alcohols of formula (III), in which R?1 and R5¿ have the meaning assigned above and R7 is a hydrogen atom or an OR8 radical, and R8 is a hydrogen atom, an alkyl radical with between 1 and 4 C atoms, a cyclohexyl or cyclopentyl radical or a radical of the formula -CH¿2?-CH2-OH or -CH2-CH2-O-CH2-CH2-OH, with a gas containing oxygen, in the presence of catalysts containing copper and/or silver, and a phosphorus compound which is volatile under reaction conditions in such a quantity that the amount of phosphorus (calculated as P), in relation to the part by weight of alcohol used, is up to 20 ppm. Said method is characterized in that the quantity of phosphorus is added in at least two parts: a) the first part is added with the gaseous starting mixture before the catalyst bed, and b) at least one other part is added in the catalyst bed.
摘要翻译：本发明涉及制备式（I）的羰基化合物的方法，其中R 1为氢原子或具有1至3个C原子的烷基; R2是氢原子或式（II）的基团，其中R3是氢原子或与R4一起形成氧原子; R4是基团OR6或与R3一起形成氧原子; R5是氢原子，具有1至8个C原子的烷基或环己基或环戊基; 并且R 6是具有1至4个C原子的烷基，环己基或环戊基或式-CH 2 -CHO或-CH 2 -CH 2 -O-CH 2 -CHO的基团。根据所述方法，羰基化合物是通过甲醇或式（III）醇的气相氧化生成的，其中R 1和R 5具有上面指定的含义，R 7是氢原子或OR 8基团，R 8 是氢原子，具有1至4个C原子的烷基，环己基或环戊基或式-CH 2 -CH 2 -OH或-CH 2 -CH 2 -O-CH 2 -CH 2 -OH的基团，与含有氧气的气体在含有铜和/或银的催化剂存在下反应，以及在反应条件下挥发的磷化合物，使得磷的量（以P计算）相对于重量份数的酒精使用量高达20 ppm。所述方法的特征在于，磷的量以至少两部分加入：a）第一部分在催化剂床之前加入气态起始混合物，和b）在催化剂床中加入至少一个其他部分。

2. 发明公开

EP0946480A1 VERFAHREN ZUR HERSTELLUNG VON CARBONYLVERBINDUNGEN 失效
标题翻译：用于生产羰基
公开(公告)号：EP0946480A1
公开(公告)日：1999-10-06
申请号：EP97953760.0
申请日：1997-12-09
申请人： BASF AKTIENGESELLSCHAFT
发明人： FETZER, Thomas , DEMUTH, Dirk , RÜTTER, Heinz , MENIG, Helmuth , RESCH, Peter , RUPPEL, Wilhelm , WACHE, Harro
IPC分类号： B01J23 , C07C45 , C07C47
CPC分类号： C07C45/39 , C07C45/38 , C07C47/04 , C07C47/127
摘要： The invention relates to a method for producing carbonyl compounds of formula (I), in which R1 is a hydrogen atom or an alkyl radical with between 1 and 3 C atoms; R2 is a hydrogen atom or a radical of formula (II) in which R3 is a hydrogen atom or, together with R4, an oxygen atom; R4 is the radical OR6 or, together with R3, an oxygen atom; R5 is a hydrogen atom, an alkyl radical with between 1 and 8 C atoms or a cyclohexyl or cyclopentyl radical; and R6 is an alkyl radical with between 1 and 4 C atoms, a cyclohexyl or cyclopentyl radical or a radical of the formula -CH¿2?-CHO or -CH2-CH2-O-CH2-CHO. According to said method, the carbonyl compounds are produced by gas-phase oxidation of methanol or alcohols of formula (III), in which R?1 and R5¿ have the meaning assigned above and R7 is a hydrogen atom or an OR8 radical, and R8 is a hydrogen atom, an alkyl radical with between 1 and 4 C atoms, a cyclohexyl or cyclopentyl radical or a radical of the formula -CH¿2?-CH2-OH or -CH2-CH2-O-CH2-CH2-OH, with a gas containing oxygen, in the presence of catalysts containing copper and/or silver and a phosphorus compounds which is volatile under reaction conditions, in such a quantity that the quantity of phosphorus (calculated as P) in relation to the part by weight of alcohol used is up to 20 ppm. The method is characterized in that the quantity of phosphorus is added in the catalyst bed.

3. 发明公开

EP1575870A2 BLAUSÄURE AUS FORMAMID 有权
标题翻译： BLUE化合物是由甲酰胺
公开(公告)号：EP1575870A2
公开(公告)日：2005-09-21
申请号：EP03789120.7
申请日：2003-12-03
申请人： BASF Aktiengesellschaft
发明人： BASSLER, Peter , SIEGEL, Wolfgang , ACHHAMMER, Günther , NEGELE, Anton , MENIG, Helmuth , RUPPEL, Wilhelm , ZEHNER, Peter , LUYKEN, Hermann , VOGT, Volker
IPC分类号： C01B3/02
CPC分类号： C01C3/0204 , B01J12/007 , B01J15/005 , B01J19/02 , B01J19/2415 , B01J23/866 , B01J2219/00135 , B01J2219/0236
摘要： The invention relates to a method for producing hydrocyanic acid (HCN) by means of catalytic dehydration of gaseous formamide in a reactor having an inner reactor surface consisting of a steel-containing iron, chromium and nickel. The invention also relates to a reactor for producing hydrocyanic acid by means of catalytic dehydration of gaseous formamide, said reactor having an inner reactor surface consisting of a steel-containing iron, chromium and nickel. The invention further relates to the use of the inventive reactor in a method for producing hydrocyanic acid by means of catalytic dehydration of gaseous formamide.

4. 发明授权

EP0946479B1 VERFAHREN ZUR HERSTELLUNG VON CARBONYLVERBINDUNGEN 失效
标题翻译：制备羰基化合物的方法
公开(公告)号：EP0946479B1
公开(公告)日：2001-09-12
申请号：EP97953759.4
申请日：1997-12-09
申请人： BASF AKTIENGESELLSCHAFT
发明人： FETZER, Thomas , DEMUTH, Dirk , RÜTTER, Heinz , MENIG, Helmuth , RESCH, Peter , RUPPEL, Wilhelm , WACHE, Harro
IPC分类号： C07C45/38 , C07C45/39 , C07C47/127
CPC分类号： C07C45/39 , C07C45/38 , C07C47/04 , C07C47/127

5. 发明公开

EP1890966A2 VERFAHREN ZUR HERSTELLUNG VON SALZEN DER BLAUSÄURE 审中-公开
标题翻译：用于生产酸性蓝盐
公开(公告)号：EP1890966A2
公开(公告)日：2008-02-27
申请号：EP06763395.8
申请日：2006-05-31
申请人： BASF AKTIENGESELLSCHAFT
发明人： DECKERS, Andreas , SCHNEIDER, Thomas , MENIG, Helmuth
IPC分类号： C01C3/08
CPC分类号： C01C3/08 , C01C3/10
摘要： The invention relates to a method for producing a solution of hydrocyanic acid salts, said method comprising the following steps: a) a raw gas containing hydrocyanic acid is produced by dehydrating formamide to a formamide transformation percentage of ≥ 97; b) optionally the raw gas obtained in step a) is subjected to acid washing; c) the raw gas obtained in step a) or optionally step b) is then reacted with an aqueous solution of a hydroxide M(OH)x, where M is selected from the group of alkali metals and earth alkali metals and x represents 1 or 2 according to the oxidation number of M.

6. 发明授权

EP1064246B1 VERFAHREN ZUR HERSTELLUNG VON CARBONYLVERBINDUNGEN 有权
标题翻译：用于生产羰基
公开(公告)号：EP1064246B1
公开(公告)日：2004-06-23
申请号：EP99939843.1
申请日：1999-02-25
申请人： BASF AKTIENGESELLSCHAFT
发明人： DEMUTH, Dirk , FETZER, Thomas , PRATSCH, Volker , WENDRICH, Thomas , MENIG, Helmuth , WAMBACH, Ludwig , HARTH, Klaus
IPC分类号： C07C45/38 , C07C45/39 , C07C47/127 , C07C47/04
CPC分类号： C07C45/39 , C07C45/38 , C07C47/04 , C07C47/127

7. 发明授权

EP0946480B1 VERFAHREN ZUR HERSTELLUNG VON CARBONYLVERBINDUNGEN 失效
公开(公告)号：EP0946480B1
公开(公告)日：2001-11-07
申请号：EP97953760.2
申请日：1997-12-09
申请人： BASF AKTIENGESELLSCHAFT
发明人： FETZER, Thomas , DEMUTH, Dirk , RÜTTER, Heinz , MENIG, Helmuth , RESCH, Peter , RUPPEL, Wilhelm , WACHE, Harro
IPC分类号： C07C45/38 , C07C45/39 , C07C47/127
CPC分类号： C07C45/39 , C07C45/38 , C07C47/04 , C07C47/127

8. 发明公开

EP1064246A1 VERFAHREN ZUR HERSTELLUNG VON CARBONYLVERBINDUNGEN 有权
标题翻译：用于生产羰基
公开(公告)号：EP1064246A1
公开(公告)日：2001-01-03
申请号：EP99939843.1
申请日：1999-02-25
申请人： BASF AKTIENGESELLSCHAFT
发明人： DEMUTH, Dirk , FETZER, Thomas , PRATSCH, Volker , WENDRICH, Thomas , MENIG, Helmuth , WAMBACH, Ludwig , HARTH, Klaus
IPC分类号： C07C45/38 , C07C45/39 , C07C47/127 , C07C47/04
CPC分类号： C07C45/39 , C07C45/38 , C07C47/04 , C07C47/127
摘要： The invention relates to a method for producing carbonyl compounds of formula (I), wherein R1 is a hydrogen atom or an alkyl radical with 1 to 3 C-atoms and R2 is a hydrogen atom, a C¿2?-C4-alkenyl radical which can be unsubstituted or substituted one to three times with C1-C3-alkyl or a radical of formula (II), wherein R?3¿ is a hydrogen atom or an oxygen atom together with R4, R4 is the radical OR6 or an oxygen atom together with R3, R5 is a hydrogen atom, an alkyl radical with 1 to 8 C-atoms, a C¿2?-C4-alkenyl radical which can be unsubstituted or substituted one to three times with C1-C3-alkyl or a cyclohexyl or cyclopentyl radical and R?6¿ is an alkyl radical with 1 to 4 C-atoms, a cyclohexyl or cyclopentyl radical or a radical of formula -CH¿2?-CHO or -CH2-CH2-O-CH2-CHO by gas phase oxidation of methanol or alcohols of formula (III), wherein R?1 and R5¿ have the meaning given above and R7 is a hydrogen atom or a radical OR?8 and R8¿ is a hydrogen atom, an alkyl radical with 1 to 4 C-atoms, a cyclohexyl or cyclopentyl radical or a radical of formula -CH¿2?-CH2-OH or -CH2-CH2-O-CH2-OH with an oxygen-containing gas in the presence of catalysts containing copper and/or silver and optionally, a phosphor compound which is volatile in the reaction conditions, the quantity of phosphor (calculated as P) being up to 20 ppm in relation to the quantity in weight of alcohol used. The inventive method is characterised in that it uses a catalyst system consisting of one catalyst which is essentially phosphor-free and at least one catalyst containing phosphor-containing copper and/or silver.

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