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1. 发明公开

EP1470095A1 VERFAHREN ZUR HERSTELLUNG VON ALKENYLAROMATISCHEN VERBINDUNGEN 审中-公开
标题翻译：用于生产链烯基芳化合物
公开(公告)号：EP1470095A1
公开(公告)日：2004-10-27
申请号：EP03701528.6
申请日：2003-01-20
申请人： BASF AKTIENGESELLSCHAFT
发明人： WALSDORFF, Christian , BAIER, Michael , HARTH, Klaus , WEBER, Susanne , RUPPEL, Wilhelm , SCHINDLER, Götz-Peter
IPC分类号： C07C5/333
CPC分类号： C07C5/3332 , B01J23/83 , B01J37/0009 , B01J2523/00 , C07C2523/02 , C07C2523/10 , C07C2523/28 , C07C2523/745 , C07C15/46 , C07C15/52 , C07C15/44 , B01J2523/13 , B01J2523/22 , B01J2523/23 , B01J2523/3712 , B01J2523/842
摘要： The invention relates to a method for producing alkenyl aromatic compounds. Said compounds are obtained by reacting alkyl aromatic compounds with a suitable catalyst in the presence of water vapour and natural gas or methane, at a temperature of between 400 and 800 °C and at a pressure of between 0.01 and 10 bar, whereby the molar ratio of water vapour to alkyl aromatic compound is from 6.9:1 to 1:1, or the molar ratio of methane to alkyl aromatic compound is from 0.1:1 to 8:1.

2. 发明公开

EP1601458A1 VERFAHREN ZUR REGENERIERUNG VON RE sb 2 /sb O sb 7 /sb DOTIERTEN TRÄGERKATALYSATOREN 审中-公开
标题翻译：的再生方法RE SB 2 / SB SB O 7 / Sb掺杂负载型催化剂
公开(公告)号：EP1601458A1
公开(公告)日：2005-12-07
申请号：EP04711362.6
申请日：2004-02-16
申请人： BASF Aktiengesellschaft
发明人： STEPHAN, Jürgen , SCHUBERT, Markus , WEICHERT, Christian , RUPPEL, Wilhelm , RESCH, Peter , ZIMDAHL, Soeren , MRZENA, Frank , MOLITOR, Andreas , BERG, Stefan , FOHRMANN, Mathias
IPC分类号： B01J23/36 , C07C6/04 , B01J38/00
CPC分类号： B01J23/92 , B01J23/36 , B01J38/12 , B01J38/14 , C07C6/04 , Y02P20/584
摘要： The invention relates to a method for a Re2O7 doped catalyst support deactivated (deactivated catalyst) by a hydrocarbon mixture containing C2-C6 olefin (C2-6 lot) used during a metathesis. The inventive method consists in treating the deactivated catalyst at a temperature ranging from 400 to 800 °C with an inert gas (regeneration gas K1). Afterwards, the thus pre-treated deactivated catalyst is treated with said regeneration gas K1 and an oxygen-containing gas (regeneration gas K2).

3. 发明公开

EP1261597A1 VERFAHREN ZUR HERSTELLUNG VON MALEINSÄUREANHYDRID 审中-公开
标题翻译：用于生产顺丁烯二酸酐
公开(公告)号：EP1261597A1
公开(公告)日：2002-12-04
申请号：EP01923639.7
申请日：2001-03-06
申请人： BASF AKTIENGESELLSCHAFT
发明人： WEIGUNY, Jens , STORCK, Sebastian , TENTEN, Andreas , RUPPEL, Wilhelm
IPC分类号： C07D307/60
CPC分类号： B01J8/067 , B01J2208/00212 , B01J2208/0053 , C07C51/215 , C07C57/145
摘要： A method for producing maleic acid anhydride by heterogeneous catalytic gas phase oxidation of hydrocarbons comprising at least four carbon atoms with gases containing oxygen in the presence of a volatile phosphorus bond on a catalyst containing vanadium, phosphorus and oxygen in a multitube fixed-bed reactor unit consisting of at least two successive cooled reaction areas, wherein the temperature of the first reactor area is 350 - 450 °C and the temperature of the second and other reaction area is 350 - 480 °C, the difference in temperature between the hottest and coldest reaction area being at least 2 °C.

4. 发明授权

EP0946480B1 VERFAHREN ZUR HERSTELLUNG VON CARBONYLVERBINDUNGEN 失效
公开(公告)号：EP0946480B1
公开(公告)日：2001-11-07
申请号：EP97953760.2
申请日：1997-12-09
申请人： BASF AKTIENGESELLSCHAFT
发明人： FETZER, Thomas , DEMUTH, Dirk , RÜTTER, Heinz , MENIG, Helmuth , RESCH, Peter , RUPPEL, Wilhelm , WACHE, Harro
IPC分类号： C07C45/38 , C07C45/39 , C07C47/127
CPC分类号： C07C45/39 , C07C45/38 , C07C47/04 , C07C47/127

5. 发明授权

EP1611079B1 VERFAHREN DER HETEROGEN KATALYSIERTEN PARTIELLEN GASPHASENOXIDATION VON ACROLEIN ZU ACRYLS URE 有权转让
标题翻译： METHOD丙烯醛的非均相催化部分气相氧化成丙烯酸
公开(公告)号：EP1611079B1
公开(公告)日：2007-05-23
申请号：EP04722167.6
申请日：2004-03-20
申请人： BASF Aktiengesellschaft
发明人： DIETERLE, Martin , PETZOLDT, Jochen , ARNOLD, Heiko , RUPPEL, Wilhelm , MÜLLER-ENGEL, Klaus, Joachim
IPC分类号： C07C57/055
CPC分类号： C07C51/252 , C07C57/04
摘要： The invention relates to a method for the heterogeneously catalysed partial gas phase oxidation of acrolein to form acrylic acid, whereby the initial mixture of reaction gas is oxidised on a fixed-bed catalyst bed which consists of at least two fixed-bed catalyst bed zones and is arranged in two successive temperature zones A and B. The transition from temperature zone A to temperature zone B does not coincide with a transition from a fixed-bed catalyst bed zone to another fixed-bed catalyst bed zone.

6. 发明公开

EP1529039A2 VERFAHREN ZUR HERSTELLUNG VON MALEINS UREANHYDRID 有权
标题翻译：用于生产马来酸酐
公开(公告)号：EP1529039A2
公开(公告)日：2005-05-11
申请号：EP03784039.4
申请日：2003-07-22
申请人： BASF AKTIENGESELLSCHAFT
发明人： WEIGUNY, Jens , RUPPEL, Wilhelm , DUDA, Mark
IPC分类号： C07D307/60
CPC分类号： C07D307/60
摘要： The invention relates to a method for producing maleic anhydride by the heterogeneous catalytic gas phase oxidation of hydrocarbons comprising at least four carbon atoms with gases containing oxygen, in the presence of a volatile phosphorus compound, on a catalyst containing vanadium, phosphor and oxygen in a multitube flow reactor unit with at least one reaction zone that is cooled by a heat-transfer medium, at a temperature ranging between 350 and 500 °C. In the first reaction zone, in relation to the educt supply, the supply temperature and/or the supply quantity is set in such a way that the average temperature of the heat transfer medium in the first reaction zone TSB(1st zone), said temperature being produced by the average value formation of the supply temperature and the drainage temperature of the heat-transfer medium, fulfils the formulas (I) and (II): (I) TSB(1st zone) ≤ TD(1st zone) - TSafety(1st zone); (II) TSB,Amax(1st zone) - TA(1st zone) ≤ TSB(1st zone) ≤ TSB,Amax(1st zone) + TB(1st zone), whereby TD(1st zone) represents the throughput temperature of the first reaction zone, TSafety(1st zone) represents the safety temperature of the first reaction zone and is 1 °C; TSB,Amax(1st zone) represents the average temperature of the heat-transfer medium in the first reaction zone, the maximum yield of maleic anhydride being obtained in the range TSB(1st zone) ≤ TD(1st zone), TA(1st zone) is 20 °C and TB(1st zone) is 10 °C.

7. 发明公开

EP1379470A2 EISENOXIDE MIT HÖHEREM VEREDELUNGSGRAD 有权
标题翻译：后缩聚程度高，氧化铁
公开(公告)号：EP1379470A2
公开(公告)日：2004-01-14
申请号：EP02732550.5
申请日：2002-04-03
申请人： BASF AKTIENGESELLSCHAFT
发明人： WALSDORFF, Christian , BAIER, Michael , KÖRNER, Reinhard , HARTH, Klaus , VORBERG, Gerald , RUPPEL, Wilhelm
IPC分类号： C01G49/02 , C09C1/24
CPC分类号： C01G49/06 , B01J23/745 , B01J23/78 , B01J23/881 , B01J23/8872 , B01J35/023 , B01J37/08 , B01J37/088 , C01G49/02 , C01P2004/51 , C01P2004/61 , C01P2004/62 , C01P2006/12 , C01P2006/14 , C01P2006/16 , C01P2006/80 , C07C5/3332 , C07C2523/745 , Y10S423/01 , C07C15/46
摘要： The invention relates to a method for refining iron oxide by calcination of the iron oxides at a temperature of from 700 to 1200 °C.

8. 发明公开

EP0946480A1 VERFAHREN ZUR HERSTELLUNG VON CARBONYLVERBINDUNGEN 失效
标题翻译：用于生产羰基
公开(公告)号：EP0946480A1
公开(公告)日：1999-10-06
申请号：EP97953760.0
申请日：1997-12-09
申请人： BASF AKTIENGESELLSCHAFT
发明人： FETZER, Thomas , DEMUTH, Dirk , RÜTTER, Heinz , MENIG, Helmuth , RESCH, Peter , RUPPEL, Wilhelm , WACHE, Harro
IPC分类号： B01J23 , C07C45 , C07C47
CPC分类号： C07C45/39 , C07C45/38 , C07C47/04 , C07C47/127
摘要： The invention relates to a method for producing carbonyl compounds of formula (I), in which R1 is a hydrogen atom or an alkyl radical with between 1 and 3 C atoms; R2 is a hydrogen atom or a radical of formula (II) in which R3 is a hydrogen atom or, together with R4, an oxygen atom; R4 is the radical OR6 or, together with R3, an oxygen atom; R5 is a hydrogen atom, an alkyl radical with between 1 and 8 C atoms or a cyclohexyl or cyclopentyl radical; and R6 is an alkyl radical with between 1 and 4 C atoms, a cyclohexyl or cyclopentyl radical or a radical of the formula -CH¿2?-CHO or -CH2-CH2-O-CH2-CHO. According to said method, the carbonyl compounds are produced by gas-phase oxidation of methanol or alcohols of formula (III), in which R?1 and R5¿ have the meaning assigned above and R7 is a hydrogen atom or an OR8 radical, and R8 is a hydrogen atom, an alkyl radical with between 1 and 4 C atoms, a cyclohexyl or cyclopentyl radical or a radical of the formula -CH¿2?-CH2-OH or -CH2-CH2-O-CH2-CH2-OH, with a gas containing oxygen, in the presence of catalysts containing copper and/or silver and a phosphorus compounds which is volatile under reaction conditions, in such a quantity that the quantity of phosphorus (calculated as P) in relation to the part by weight of alcohol used is up to 20 ppm. The method is characterized in that the quantity of phosphorus is added in the catalyst bed.

9. 发明公开

EP0859659A1 VERFAHREN ZUM ENTFERNEN VON STICKSTOFFOXIDEN AUS EINEM DIESE ENTHALTENDEN GASSTROM 失效
标题翻译：方法去除氮氧化物从本氧化剂气体流
公开(公告)号：EP0859659A1
公开(公告)日：1998-08-26
申请号：EP96931068.0
申请日：1996-09-10
申请人： BASF AKTIENGESELLSCHAFT
发明人： FETZER, Thomas , WAGNER, Eckhart , RÖTH, Emil , RUPPEL, Wilhelm , WISTUBA, Hermann , OTTO, Bernhard , SCHUMACHER, Volker , BÜRGER, Gert
IPC分类号： B01D53 , C01B21
CPC分类号： C01B21/38 , B01D53/56 , B01D53/8625 , B01D2257/402 , Y02C20/10 , Y02P20/153
摘要： The invention concerns a method of removing nitrogen oxides from a gas flow. The gas flow is guided: (A) through a stage in which the nitrogen oxides, apart from N2O, are absorbed in an absorption agent, or the nitrogen oxides, apart from N2O, are reacted with an absorption agent at a pressure of between 1.5 and 20 bar; and (B) through a stage for reducing the N2O content, preferably using the pressure level prevailing in step (A). The invention further concerns a device for carrying out this method and the use thereof.

10. 发明公开

EP1611073A1 VERFAHREN DER HETEROGEN KATALYSIERTEN PARTIELLEN GASPHASENOXIDATION VON PROPEN ZU ACROLEIN 有权转让
标题翻译：过程为丙烯的非均相催化部分气相氧化成丙烯醛的
公开(公告)号：EP1611073A1
公开(公告)日：2006-01-04
申请号：EP04722151.0
申请日：2004-03-20
申请人： BASF Aktiengesellschaft
发明人： PETZOLDT, Jochen , DIETERLE, Martin , ARNOLD, Heiko , RUPPEL, Wilhelm , MÜLLER-ENGEL, Klaus, Joachim
IPC分类号： C07C45/35 , C07C51/25 , C07C47/22 , C07C57/04
CPC分类号： C07C45/35 , C07C51/252 , C07C47/22 , C07C57/04
摘要： Disclosed is a method for the heterogeneously catalyzed partial gas phase oxidation of propene into acrolein, according to which the initial reaction gas mixture is oxidized on a fixed catalyst bed that comprises at least two fixed catalyst bed zones and is accommodated in two successive temperature zones A, B, the transition of temperature zone A to temperature zone B not coinciding with a transition from one fixed catalyst bed zone to another.

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