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    • 4. 发明公开
    • METHOD FOR MANUFACTURING FLUORINE-CONTAINING POLYMER PARTICLES
    • VERFAHREN ZUR HERSTELLUNG VON FLUORPOLYMERPARTIKELN
    • EP2368920A1
    • 2011-09-28
    • EP09834743.8
    • 2009-12-15
    • Asahi Glass Company Limited
    • SAITO, SusumuSHIMOHIRA, TetsujiSAEKI, TakashiTAYANAGI, Junichi
    • C08F6/12
    • C08F6/24C08F6/001C08F6/003C08F6/12C08F6/20C08F6/22C08F14/18C08L27/12C08F2/04
    • To provide a process for producing fluoropolymer particles, whereby formation of fine particles is suppressed.
      A process for producing fluoropolymer particles, which comprises (i) a step of preparing a solution or dispersion of a fluoropolymer (A) having the fluoropolymer (A) dissolved or dispersed in a solvent (B), wherein the solvent (B) contains a good solvent (B2) whereby the degree of swelling of the fluoropolymer (A) exceeds 50%, and the degree of swelling of the fluoropolymer (A) by the solvent (B) is from 50 to 1,200%; and (ii) a step of mixing the solution or dispersion of a fluoropolymer (A) with a solvent (C) to flocculate the fluoropolymer (A) thereby to form particles of the fluoropolymer (A), wherein the solvent (C) contains a poor solvent (C1) whereby the degree of swelling of the fluoropolymer (A) is at most 50%, the degree of swelling of the fluoropolymer (A) by a mixed solvent (BC) of the solvents (B) and (C) is from 0 to 100%, the ratio (W C /W B ) of the mass (W C ) of the solvent (C) to the mass (W B ) of the solvent (B) is from 1 to 5, and the ratio (S BC /S B ) of the degree of swelling (S BC ) of the fluoropolymer (A) by the mixed solvent (BC) to the degree of swelling (S B ) of the fluoropolymer (A) by the solvent (B) is at most 0.5.
    • 提供一种生产含氟聚合物颗粒的方法,从而抑制细颗粒的形成。 一种生产含氟聚合物颗粒的方法,其包括(i)制备溶解或分散在溶剂(B)中的含氟聚合物(A)的含氟聚合物(A)的溶液或分散体的步骤,其中溶剂(B)含有 良溶剂(B2),含氟聚合物(A)的溶胀度超过50%,溶剂(B)的含氟聚合物(A)的溶胀度为50〜1200% 和(ii)将含氟聚合物(A)的溶液或分散体与溶剂(C)混合以使含氟聚合物(A)絮凝从而形成含氟聚合物(A)的颗粒的步骤,其中溶剂(C)含有 不良溶剂(C1),含氟聚合物(A)的溶胀度为50%以下,溶剂(B)和(C)的混合溶剂(BC)的含氟聚合物(A)的溶胀度为 0〜100%时,溶剂(C)的质量(WC)与溶剂(B)的质量(WB)的比(WC / WB)为1〜5,比率(S BC / 通过混合溶剂(BC)的含氟聚合物(A)的溶胀度(S BC)与溶剂(B)的含氟聚合物(A)的溶胀度(SB)的比例SB(SB)为0.5以下。