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    • 39. 发明公开
    • Fluorine-containing acrylate
    • Fluorhaltiges Acrylat
    • EP2196488A1
    • 2010-06-16
    • EP09178350.6
    • 2009-12-08
    • Shin-Etsu Chemical Co., Ltd.
    • Sakano, YasunoriKoike, NoriyukiKishita, Hirofumi
    • C08G77/04C07F7/21C09D4/00C09D175/16
    • C08G77/045C07F7/21C08F220/22C08F220/24C08F230/08C08G18/61C08G18/8116C08G77/38C08G77/388C09D175/16
    • The present invention is a fluorine-containing acrylate or alpha-substituted, fluorine-containing acrylate, represented by the following formula (1):

      wherein a is an integer of from 1 to 4 and b is an integer of from 1 to 4, provided that the total of a and b is 3, 4, or 5;
      R 1 is a group represented by the following formula (2):

               -(C 4 H 8 O) d (C 3 H 6 O) e (C 2 H 4 O) f (CH 2 O) g -     (2)

      wherein d, e, f, and g are, independently of each other, an integer of from 0 to 4, provided that the molecular weight of R 1 is in the range of 30 to 300, and
      these repeating units may be sequenced at random;
      R 2 is an acryl group- or alpha-substituted acryl group-containing group having 4 to 20 carbon atoms and represented by the following formula (3):

      wherein R 3 is, independently of each other, a hydrogen atom, a fluorine atom, a methyl group, or a trifluoromethyl group,
      R 4 is a divalent or trivalent linking moiety having 1 to 18 carbon atoms, optionally having an ether bond and/or an ester bond, and
      n is 1 or 2;

      Rf is a perfluoropolyether residue represented by the following formula (4):

      wherein j, k, 1, and m are, independently of each other, an integer of from 0 to 50, provided that the molecular weight of Rf is in the range of 200 to 6000,
      X is a fluorine atom or a trifluoromethyl group, and these repeating units may be sequenced at random;
      Z is a divalent organic group; and
      c is 0 or 1.
    • 本发明是由下式(1)表示的含氟丙烯酸酯或α-取代的含氟丙烯酸酯,其中a为1〜4的整数,b为1〜4的整数, a和b的总和是3,4或5; R 1是由下式(2)表示的组:ƒ€ƒ€ƒ€ƒ€ƒ€ƒ - (C 4 H 8 O)d(C 3 H 6 O)e(C 2 H 2 O)f(CH 2 O)g - €ƒ€ƒ€ƒ(ƒ)其中d,e,f和g彼此独立地为0至4的整数, R 1的分子量在30〜300的范围内,这些重复单元可以随机排序; R 2是具有4〜20个碳原子的丙烯酰基或α-取代的含丙烯酰基的基团,由下式(3)表示:其中R 3彼此独立地为氢原子,氟原子, 甲基或三氟甲基,R 4是具有1至18个碳原子的任选具有醚键和/或酯键的二价或三价连接部分,n为1或2; Rf是由下式(4)表示的全氟聚醚残基:其中j,k,1和m彼此独立地为0至50的整数,条件是Rf的分子量在 200〜6000,X为氟原子或三氟甲基,这些重复单元可以随机排列; Z是二价有机基团; c为0或1。