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101. 发明公开

EP2842625A4 CATALYST FOR PRODUCING BUTADIENE, METHOD FOR PRODUCING SAID CATALYST, AND METHOD FOR PRODUCING BUTADIENE USING SAID CATALYST 审中-公开
标题翻译：用于制备丁二烯的催化剂，生产该催化剂的方法以及使用该催化剂生产丁二烯的方法
公开(公告)号：EP2842625A4
公开(公告)日：2015-10-28
申请号：EP13782374
申请日：2013-04-19
申请人： NIPPON KAYAKU KK
发明人： HIRAOKA RYOTA , HINO YUMI , OKUMURA KIMITO , MOTOMURA HIROKI
IPC分类号： B01J23/88 , B01J35/10 , B01J37/00 , C07B61/00 , C07C5/48 , C07C11/167
CPC分类号： B01J23/8876 , B01J23/002 , B01J23/8878 , B01J23/8885 , B01J23/8898 , B01J35/08 , B01J35/1038 , B01J2523/00 , C07C5/48 , C07C2521/12 , C07C2523/04 , C07C2523/18 , C07C2523/28 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2523/883 , C07C2523/887 , B01J2523/54 , B01J2523/68 , B01J2523/842 , B01J2523/845 , B01J2523/847 , C07C11/167

102. 发明公开

EP2928603A1 VERFAHREN ZUR OXIDATIVEN DEHYDRIERUNG VON N-BUTENEN ZU BUTADIEN 审中-公开
公开(公告)号：EP2928603A1
公开(公告)日：2015-10-14
申请号：EP13814454.8
申请日：2013-12-04
申请人： BASF SE
发明人： GRÜNE, Philipp , RÜTTINGER, Wolfgang , HAMMEN, Oliver , WALSDORFF, Christian
IPC分类号： B01J37/03 , B01J23/887 , B01J35/00 , B01J35/02 , B01J35/10 , B01J37/02 , C07C5/48
CPC分类号： B01J23/8878 , B01J23/28 , B01J35/008 , B01J35/026 , B01J37/0221 , B01J37/033 , B01J37/08 , B01J2523/00 , C07C2/06 , C07C5/32 , C07C5/48 , C07C2521/02 , C07C2521/06 , C07C2523/02 , C07C2523/04 , C07C2523/06 , C07C2523/10 , C07C2523/14 , C07C2523/16 , C07C2523/18 , C07C2523/26 , C07C2523/28 , C07C2523/30 , C07C2523/34 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C10G27/04 , C10G2400/02 , C10G2400/04 , B01J2523/13 , B01J2523/54 , B01J2523/67 , B01J2523/68 , B01J2523/842 , B01J2523/845 , C07C11/167 , C07C11/08
摘要： The invention relates to a catalyst which is obtainable from a catalyst precursor comprising a catalytically active multimetal oxide which contains molybdenum and at least one further metal and is of the general formula (I) Mo
12 Bi
a Fe
b Co
c Ni
d Cr
e X
1
f X
2
g O
x ,in which the variables have the following meaning: X
1 = W, Sn, Mn, La, Ce, Ge, Ti, Zr, Hf, Nb, P, Si, Sb, Al, Cd and/or Mg; X
2 = Li, Na, K, Cs and/or Rb, a = 0.1 to 7, preferably 0.3 to 1.5; b = 0 to 5, preferably 2 to 4; c = 0 to 10, preferably 3 to 10; d = 0 to 10; e = 0 to 5, preferably 0.1 to 2; f = 0 to 24, preferably 0.1 to 2; g = 0 to 2, preferably 0.01 to 1; and x = a number which is determined by the valency and frequency of the elements in (I) that are different from oxygen, characterized in that the catalyst has the shape of a hollow cylinder, wherein the inner diameter is 0.2 to 0.8-times the outer diameter and the length is 0.5 to 2.5-times the outer diameter, and in that the catalyst precursor does not contain pore formers.
摘要翻译：本发明涉及可由包含催化活性多金属氧化物的催化剂前体获得的催化剂，所述催化活性多金属氧化物包含钼和至少一种其他金属并且具有通式（I）Mo 12 Bi a Fe b Co c Ni dCr eX 1 fX 2 gO x，其中变量具有以下含义：X 1 = W，Sn，Mn，La，Ce，Ge，Ti，Zr，Hf，Nb，P，Si，Sb，Al，Cd和/或Mg; X 2 = Li，Na，K，Cs和/或Rb，a = 0.1至7，优选0.3至1.5; b = 0至5，优选2至4; c = 0至10，优选3至10; d = 0至10; e = 0-5，优选0.1-2; f = 0-24，优选0.1-2; g = 0-2，优选0.01-1; x =由（I）中的元素的价数和频率确定的与氧不同的数，其特征在于，催化剂具有中空圆柱体的形状，其中内径为0.2至0.8倍外径和长度为外径的0.5至2.5倍，并且催化剂前体不含成孔剂。

103. 发明公开

EP2928602A1 SCHALENKATALYSATOR ZUR OXIDATIVEN DEHYDRIERUNG VON N-BUTENEN ZU BUTADIEN 审中-公开
标题翻译：壳催化剂用于正丁烯氧化脱氢丁二烯
公开(公告)号：EP2928602A1
公开(公告)日：2015-10-14
申请号：EP13801580.5
申请日：2013-12-06
申请人： BASF SE
发明人： GRÜNE, Philipp , DOBNER, Cornelia Katharina , SCHMITT, Christine , RÜTTINGER, Wolfgang , WALSDORFF, Christian , ROSOWSKI, Frank
IPC分类号： B01J37/03 , B01J35/00 , B01J35/02 , B01J37/00 , B01J37/02 , C07C5/48
CPC分类号： B01J37/033 , B01J23/18 , B01J23/26 , B01J23/28 , B01J23/745 , B01J23/75 , B01J23/755 , B01J35/002 , B01J35/008 , B01J35/023 , B01J35/026 , B01J37/0036 , B01J37/0221 , B01J37/08 , B01J2523/00 , C07C5/48 , C07C2523/04 , C07C2523/18 , C07C2523/26 , C07C2523/28 , C07C2523/745 , C07C2523/75 , C07C2523/887 , C07C11/167 , B01J2523/54 , B01J2523/67 , B01J2523/68 , B01J2523/842 , B01J2523/845 , B01J2523/847 , B01J2523/13
摘要： The invention relates to a shell catalyst, comprising (a) a carrier body, (b) a shell containing a catalytically active multi-metal oxide containing molybdenum and at least one additional metal, wherein the shell is constructed of multi-metal oxide particles having a d
50 value of 6 to 13 μm, which shell catalyst can be obtained by (i) producing a multi-metal oxide precursor mass containing molybdenum and at least one additional metal, (ii) producing a molded body from the multi-metal oxide precursor mass, (iii) calcination of the molded body made of the multi-metal oxide precursor mass in order to produce a multi-metal oxide mass, (iv) grinding the molded body made of multi-metal oxide mass in order to form multi-metal oxide particles having a d
50 value of 6 to 13 μm, (v) coating the carrier body with the multi-metal oxide particles, (vi) thermally treating the coated carrier body.

104. 发明公开

EP2914568A1 BUTADIENE EXTRACTION PROCESS 有权
标题翻译：丁二烯萃取工艺
公开(公告)号：EP2914568A1
公开(公告)日：2015-09-09
申请号：EP13850380.0
申请日：2013-10-15
申请人： Lummus Technology Inc.
发明人： SCHWINT, Kevin, John , BRUMMER, Robert, J.
IPC分类号： C07C7/08 , C07C11/167 , B01J19/24
CPC分类号： B01D3/40 , B01D3/143 , B01D19/0068 , C07C7/08 , C07C11/167
摘要： A process for recovering 1,3-butadiene from a C
4 fraction, where the butadiene extraction processes may be operated at an intermediate pressure using a liquid ring type compressor. The use of a liquid ring compressor, among other process options presented herein, may advantageously reduce capital and operating costs, similar to the compressorless option, while mitigating the risks associated with the higher operating temperatures and pressures associated with the compressorless option. Thus, the embodiments of the processes disclosed herein encompass the best features of the conventional design (low pressure, with a compressor) with the advantages of the compressorless design (low capital and operating cost), as well as other advantages unique to the systems disclosed herein.
摘要翻译：一种从C 4馏分中回收1,3-丁二烯的方法，其中丁二烯萃取过程可以使用液环式压缩机在中压下操作。类似于无压缩机选项，使用液体环式压缩机以及本文中呈现的其他过程选项可以有利地降低资本和运行成本，同时减轻与无压缩机选项相关联的更高的操作温度和压力相关联的风险。因此，本文公开的过程的实施例包括具有无压缩机设计（低资本和运行成本）的优点的常规设计（低压，具有压缩机）的最佳特征以及对于所公开的系统独特的其他优点于此。

105. 发明公开

EP2842625A1 CATALYST FOR PRODUCING BUTADIENE, METHOD FOR PRODUCING SAID CATALYST, AND METHOD FOR PRODUCING BUTADIENE USING SAID CATALYST 审中-公开
标题翻译：催化剂丁二烯的生产用于制丁二烯使用这种催化剂该催化剂和方法生产方法
公开(公告)号：EP2842625A1
公开(公告)日：2015-03-04
申请号：EP13782374.6
申请日：2013-04-19
申请人： Nippon Kayaku Kabushiki Kaisha
发明人： HIRAOKA Ryota , HINO Yumi , OKUMURA Kimito , MOTOMURA Hiroki
IPC分类号： B01J23/88 , B01J35/10 , B01J37/00 , C07C5/48 , C07C11/167 , C07B61/00
CPC分类号： B01J23/8876 , B01J23/002 , B01J23/8878 , B01J23/8885 , B01J23/8898 , B01J35/08 , B01J35/1038 , B01J2523/00 , C07C5/48 , C07C2521/12 , C07C2523/04 , C07C2523/18 , C07C2523/28 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2523/883 , C07C2523/887 , B01J2523/54 , B01J2523/68 , B01J2523/842 , B01J2523/845 , B01J2523/847 , C07C11/167
摘要： A catalyst for producing butadiene using n-butene as a raw material, a process for producing the same and a process for producing butadiene using the catalyst. Specifically, a catalyst for producing butadiene by gas-phase contact oxidative dehydrogenation of n-butene, which is capable of stably producing butadiene in a high yield from the beginning of the reaction, a process for producing the same and a process for producing butadiene. The catalyst is a shaped catalyst containing a complex metal oxide having molybdenum as an essential ingredient, wherein the pore volume of macropores is 80% or more, more preferably 90% or more, based on the total pore volume.
摘要翻译：催化剂用于使用正丁烯作为原料，其制造方法和使用该催化剂生产丁二烯的处理的过程中产生丁二烯。具体而言，通过正丁烯，所有这些都能够在从反应，其制造和用于生产丁二烯的处理的过程的开始以高收率稳定地生产丁二烯的气相接触氧化脱氢生产丁二烯的催化剂。该催化剂是一种成型催化剂含一个具有钼复合金属氧化物为必要成分，worin大孔的孔体积为80％或更多，更优选90％或更多，基于总孔体积。

106. 发明公开

EP2831022A1 LOW EMISSIONS OXIDATIVE DEHYDROGENATION PROCESS FOR PRODUCING BUTADIENE 有权
标题翻译：低排放氧化脱氢生产丁二烯的工艺
公开(公告)号：EP2831022A1
公开(公告)日：2015-02-04
申请号：EP13769936.9
申请日：2013-03-28
申请人： TPC Group LLC
发明人： CACIULA, Liana , DUFF, Joseph, G. , BALLARD, Elizabeth , POTTER, Mark , CHADA, Sirisha
IPC分类号： C07C5/333 , C07C11/167 , C07C11/08 , B01J23/745
CPC分类号： B01J19/24 , B01J23/8892 , B01J27/187 , B01J2219/00103 , B01J2219/24 , B01J2523/00 , C07C5/09 , C07C5/48 , C07C7/005 , C07C2523/745 , C07C2523/80 , C07C2527/185 , Y02P20/51 , C07C11/167 , B01J2523/23 , B01J2523/27 , B01J2523/51 , B01J2523/72 , B01J2523/842
摘要： Butadiene is made from a butene rich feed by passing a superheated butene rich feed including superheated steam and oxygen at a temperature of at least about 343° C. (650° F.) over a catalyst bed having a depth of over about 69 cm (27 inches) of granules of ferritic oxidative dehydrogenation catalyst. Inlet conditions being controlled such that the oxidative dehydrogenation reactions initially occur in the lower most layers of catalyst. Process control includes monitoring the temperature throughout the bed and increasing the inlet temperature in response to a drop in the temperature in the active layer, when the active layer of oxidative dehydrogenation catalyst begins to become deactivated so that the reaction zone moves upwardly in the oxidative dehydrogenation bed.
摘要翻译：丁二烯是通过丁烯的脱氢而形成的，丁烯与水蒸汽和氧气混合，然后通过在铁氧化物氧化物催化剂上氧化脱氢转化为丁二烯，其中氧化脱氢反应产物中的显热与由低价值挥发性物质产品形成以减少能源需求和二氧化碳排放。在高温下使用明显的热量用于过热进料，并且在稍低的温度下用于在该过程中的连续位置处蒸发进料。

107. 发明公开

EP2711350A4 METHOD FOR MANUFACTURING CONJUGATED DIOLEFIN AND MANUFACTURING DEVICE THEREFOR 有权转让
标题翻译：生产共轭二烯的方法及其生产设备
公开(公告)号：EP2711350A4
公开(公告)日：2014-12-31
申请号：EP12786240
申请日：2012-05-09
申请人： ASAHI KASEI CHEMICALS CORP
发明人： YANO HIROYUKI , WATANABE HARUHIKO
IPC分类号： C07C7/152 , B01J21/08 , B01J23/00 , B01J23/88 , B01J23/883 , B01J37/00 , B01J37/02 , C07B61/00 , C07C2/10 , C07C5/48 , C07C7/10 , C07C11/167
CPC分类号： C07C2/10 , B01J21/08 , B01J23/002 , B01J23/883 , B01J37/0045 , B01J37/0201 , B01J2523/00 , C07C5/48 , C07C7/10 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/02 , C07C2523/04 , C07C2523/10 , C07C2523/18 , C07C2523/755 , C07C2523/881 , C07C2523/883 , C08F36/06 , C08F136/06 , C07C11/167 , B01J2523/13 , B01J2523/14 , B01J2523/22 , B01J2523/3712 , B01J2523/54 , B01J2523/68 , B01J2523/842 , B01J2523/847 , B01J2523/12 , B01J2523/305 , B01J2523/845 , C08F2/06
摘要： To provide a method for producing a conjugated diolefin that can suppress reaction byproducts with high boiling point from remaining in steps following a quenching step by a quenching tower, and a method for producing a conjugated diolefin (e.g., 1,3-butadiene) that can be used as a raw material for synthetic rubber, resin and the like, even when using an industrial grade mixed hydrocarbon that may not necessarily have a high purity as a raw material to produce the conjugated diolefin (e.g., butadiene), provided is a method for producing a conjugated diolefin, which includes a step of producing a product gas by reaction containing a conjugated diolefin by feeding a hydrocarbon containing a monoolefin having 4 or more carbon atoms and oxygen to a reactor accommodated with a catalyst which comprises a metal oxide and a carrier, and a step of sending the product gas by reaction to a quenching tower and washing with a quenching agent, wherein an organic amine aqueous solution is used as the quenching agent.
摘要翻译：提供一种用于制备可以抑制由淬火塔淬火步骤后残留的高沸点反应副产物的共轭二烯烃的方法，以及可以制备共轭二烯烃（例如，1,3-丁二烯）的方法，其可以作为合成橡胶，树脂等的原料，即使使用不一定具有高纯度的工业级混合烃作为原料来制造共轭二烯烃（例如，丁二烯），只要是方法用于制备共轭二烯烃，其包括通过将含有具有4个或更多个碳原子的单烯烃和氧气的烃进料到含有金属氧化物和催化剂的反应器的反应器中，通过含有共轭二烯烃的反应生产产物气体的步骤载体，以及通过与淬火塔反应并将产物气体用猝灭剂洗涤的步骤，其中使用有机胺水溶液 e淬火剂。

108. 发明公开

EP2809633A1 VERFAHREN ZUR HERSTELLUNG VON BUTADIEN UND/ODER BUTENEN AUS N-BUTAN 有权
标题翻译： PROCESS FOR由正丁烷PRODUCING丁二烯和/或丁烯
公开(公告)号：EP2809633A1
公开(公告)日：2014-12-10
申请号：EP13701487.4
申请日：2013-01-30
申请人： BASF SE
发明人： GIESA, Sonja , BENFER, Regina
IPC分类号： C07C5/333 , C07C7/08 , C07C11/167
CPC分类号： C07C5/333 , C07C5/48 , C07C7/08 , C07C7/11 , C07C11/08 , C07C11/167
摘要： The process for preparing butadiene from n-butane comprises the steps of A) providing an input gas stream a comprising n-butane; B) feeding the input gas stream a comprising n-butane into at least one first dehydrogenation zone; C) compressing in at least one first compression stage and cooling the gas stream b; D) absorption of the butenes and of the stream c2 comprising butadiene, n-butane, hydrogen, water vapour, possibly inert gases and possibly carbon oxides with a selective solvent; E) extractive distillation of the selective solvents; F) distillation of the selective solvents; G) feeding the stream f and an oxygenous gas into at least one second dehydrogenation zone and oxidatively dehydrogenating 1-butene and 2-butenes.

109. 发明公开

EP2800733A1 VERFAHREN ZUR AUFREINIGUNG EINES RECYCLE-STROMES AUS EINER 1,3-BUTADIEN VERARBEITENDEN ANLAGE 有权
标题翻译：法净化循环流从一个1.3 - 丁二烯生产厂房
公开(公告)号：EP2800733A1
公开(公告)日：2014-11-12
申请号：EP13700056.8
申请日：2013-01-02
申请人： BASF SE
发明人： HEIDA, Bernd , HUGO, Randolf
IPC分类号： C07C7/08 , C07C11/167
CPC分类号： C07C7/08 , C07C11/167
摘要： A process is proposed for purifying a recycle stream (1) from an installation (A) processing 1,3-butadiene, wherein - the recycle stream (1) is divided into two substreams, namely a first substream (3) which is purified in a stripping column (K1) for prepurification of the pure 1,3-butadiene feed stream (2), obtaining a first purified recycle stream (4) which co-comprises the prepurified pure 1,3-butadiene feed stream (2), and also - a second substream (5) which is purified in an extracted distillation installation by extractive distillation using a selective solvent (6), wherein the extractive distillation installation comprises - a main scrubber (K2) which is constructed as an enrichment column, and also - a gas-stripper column (K3), with the proviso that the recycle stream (1) is divided in such a manner that a quantitative stream as large as possible is apportioned to the first substream (3), maintaining the specification requirements for the sum of all streams that are fed into the installation (A) processing 1,3-butadiene, of a fraction of 1,3-butadiene of greater than or equal to 90% by weight, based on the total weight of the C
4 hydrocarbons of the sum of all streams fed into the installation (A) processing 1,3-butadiene.

110. 发明授权

EP2681178B1 VERFAHREN ZUR AUFARBEITUNG EINES BUTEN- UND/ODER BUTADIEN ENTHALTENDEN STOFFSTROMS 有权
标题翻译：方法处理的丁烯和/或材料含丁二烯流
公开(公告)号：EP2681178B1
公开(公告)日：2014-11-05
申请号：EP12706605.8
申请日：2012-03-02
申请人： BASF SE
发明人： KOSTOVA, Albena , BENFER, Regina , GÖTZ, Jochen , REZAI, Alireza , MORILLO, Aristides , OLBERT, Gerhard , PFAB, Peter , KOLIOS, Grigorios , WEBER, Markus , WECK, Alexander
IPC分类号： C07C7/04 , C07C7/08 , C07C7/11 , C07C11/08 , C07C11/167 , C07C9/10 , B01D3/40
CPC分类号： B01D3/40 , C07C7/04 , C07C7/08 , C07C7/11 , C07C11/16 , C07C11/167

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