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1. 发明公开

EP3394010A1 CONVERSION OF ALCOHOLS TO HYDROCARBONS USING A DUAL CATALYST SYSTEM COMPRISING BASIC OXIDE ON MIXED OXIDE OR MESOPOROUS CARRIER AND ETCHED METAL LOADED ZEOLITE CATALYST 审中-实审
公开(公告)号：EP3394010A1
公开(公告)日：2018-10-31
申请号：EP16879487.3
申请日：2016-12-20
申请人： Eco-Oil Miljöbränslen i Sverige AB
发明人： MIKKOLA, Jyri-Pekka , SAMIKANNU, Ajaikumar , VANKLINT, Kent , SILJEBO, William
IPC分类号： C07C1/20 , B01J21/06 , B01J29/42 , B01J29/85 , B01J21/02 , B01J21/10
CPC分类号： C07C2/12 , B01J21/12 , B01J23/78 , B01J29/072 , B01J29/44 , B01J29/46 , B01J29/85 , B01J35/0006 , C07C1/20 , C07C1/24 , C07C2521/08 , C07C2521/10 , C07C2521/12 , C07C2523/755 , C07C2529/44 , C10G3/00 , C10G3/44 , C10G3/45 , C10G3/47 , C10G3/48 , C10G3/49 , C10G3/62 , C10G2400/02 , C10G2400/04 , C10G2400/08 , Y02P20/52 , Y02P30/20 , C07C11/04 , C07C11/167 , C07C9/14 , C07C11/02
摘要： A method for converting an alcohol to hydrocarbons comprises two serially placed catalysts. The fraction of aromatics is reduced to desired levels. The method comprises: a) contacting the alcohol with a first catalyst on a carrier, said carrier is selected from a mixed oxide and a mesoporous carrier, said first catalyst comprises at least one basic oxide and optionally at least one selected from the group consisting of metals and metal oxides, then b) contacting the resulting mixture from step a) with a second catalyst wherein said second catalyst is an etched metal loaded zeolite catalyst wherein the etched metal loaded zeolite catalyst is manufactured with a method comprising etching with subsequent loading of metal onto the catalyst, wherein the metal is in the form of nanoparticles, and wherein at least two different metals are loaded onto the etched zeolite catalyst. The hydrocarbons are recovered and used for instance for fuel including gasoline, kerosene, diesel, and jet propellant, and jet fuel. Naturally, other uses of hydrocarbons should not be excluded.

2. 发明公开

EP3378848A1 HYDRIERUNGSVERFAHREN ZUR SYNTHESE VON METHAN UND METHANOL 有权转让
公开(公告)号：EP3378848A1
公开(公告)日：2018-09-26
申请号：EP17162561.9
申请日：2017-03-23
申请人： Karlsruher Institut für Technologie
发明人： Lefebvre, Jonathan , Ortloff, Felix , Müller, Christian , Bajohr, Siegfried , Graf, Frank , Kolb, Thomas
IPC分类号： C07C1/02 , C07C9/04 , C07C29/159 , C07C31/04 , B01J8/22
CPC分类号： C07C1/02 , C07C29/159 , C07C2521/04 , C07C2521/08 , C07C2523/755 , C07C2523/80 , C07C9/04 , C07C31/04
摘要： Die vorliegende Erfindung betrifft ein neues Hydrierungsverfahren zur Synthese von Methan und Methanol durch Hydrierung von kohlenstoffhaltigen Gasen mit Wasserstoff unter Verwendung hydrierter Wärmeträgeröle, sowie ein Reaktorsystem zur Durchführung des neuen Hydrierungsverfahrens und ein neues Hydrierungsmittel zur Verwendung in einem solchen Verfahren der Transferhydrierung.

4. 发明公开

EP3360535A1 NOVEL EMOLLIENT COMPOSITION 审中-公开
公开(公告)号：EP3360535A1
公开(公告)日：2018-08-15
申请号：EP17155898.4
申请日：2017-02-13
申请人： Total Marketing Services
发明人： DUPUY, Carole
IPC分类号： A61K8/31 , A61Q19/00 , C10G45/00 , C10G50/00 , C10G65/04 , C10G69/12 , C07C5/03 , C07C9/16
CPC分类号： C07C5/03 , A61K8/31 , A61Q19/00 , C07C2523/755 , C10G69/126 , C07C9/16
摘要： The invention provides an emollient composition comprising at least one hydrocarbon fluid in an amount of 50 to 100% by weight, preferably from 80 to 100% by weight, more preferably from 90 to 100% by weight and preferably equal to 100% by weight relative to the total weight of the composition, said fluid being obtainable by a process of catalytically hydrogenating a feed comprising more than 90% by weight of oligomerized olefins, at a temperature from 115 to 195 °C and at a pressure from 30 to 70 bars.
The invention further provides a cosmetic, dermatological or pharmaceutical composition comprising at least one emollient composition according to the invention, and uses thereof.

5. 发明公开

EP3154686A1 CATALYSEUR MESOPOREUX ET MACROPOREUX A BASE DE NICKEL OBTENU PAR COMALAXAGE ET AYANT UN DIAMETRE MEDIAN MACROPOREUX SUPERIEUR A 300 NM ET SON UTILISATION EN HYDROGENATION D'HYDROCARBURES 审中-公开
标题翻译：介孔和大孔的催化剂FROM通过联合磨削生产的镍和与宏多孔介质直径大于300纳米及其用途中的烃的氢化
公开(公告)号：EP3154686A1
公开(公告)日：2017-04-19
申请号：EP15730988.1
申请日：2015-06-09
申请人： IFP Énergies nouvelles
发明人： BOUALLEG, Malika , DUBREUIL, Anne-Claire , MAILLE, Emily , THOMAZEAU, Cecile
IPC分类号： B01J23/755 , B01J21/04 , B01J35/10 , B01J37/03 , B01J37/04 , B01J37/08 , B01J37/16 , B01J37/20 , B01J33/00 , C10G45/36 , C10G45/48 , C07C5/03 , C07C5/10 , B01J27/185 , C01F7/02 , C01F7/34
CPC分类号： B01J23/755 , B01J21/04 , B01J33/00 , B01J35/006 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1057 , B01J35/1061 , B01J35/1066 , B01J35/1071 , B01J35/108 , B01J37/009 , B01J37/0236 , B01J37/03 , B01J37/036 , B01J37/04 , B01J37/08 , B01J37/16 , B01J37/20 , C07C5/03 , C07C5/05 , C07C5/10 , C07C2521/04 , C07C2523/755 , C07C2601/14 , C10G45/36 , C10G45/40 , C10G45/48 , C10G45/52 , C10G2300/1096 , C10G2300/705 , C07C13/18 , C07C15/073 , C07C11/10 , C07C9/18
摘要： The invention concerns a catalyst comprising a predominantly calcined aluminium oxide matrix and an active phase comprising nickel, said active phase being at least partially comulled in said predominantly calcined aluminium oxide matrix, the nickel content being between 5 and 65% by weight of said element relative to the total mass of the catalyst, said active phase not comprising group VIB metal, the nickel particles having a diameter less than 15 nm, said catalyst having a mesoporous median diameter of between 8 nm and 25 nm, a macroporous median diameter greater than 300 nm, a mesoporous volume measured by mercury porosimetry greater than or equal to 0.30 mL/g and a total porous volume measured by mercury porosimetry greater than or equal to 0.34 mL/g. The invention also concerns the method of preparing said catalyst and the use of same in a hydrogenation method.
摘要翻译：本发明涉及一种催化剂，其包含煅烧的氧化物基体的所有主要是氧化铝和在活性相包含镍，所述活性相是至少部分共混合所述煅烧氧化物基质内的所有这主要是氧化铝，镍含量范围为5％为至65％重量的所述元件相对于催化剂的总质量，所述活性相不包含选自第VIB族的金属，其具有直径小于15纳米的镍颗粒，所述催化剂具有在范围为8的中值孔直径纳米至25纳米，超过300纳米，介孔体积的中值大孔直径，由压汞法测定的12:30毫升/ g以上，总孔体积，通过压汞法测定的12点34毫升/克或更多，。因此，本发明涉及所述方法为催化剂。所述的制备，和它在氢化过程中使用。

6. 发明公开

EP3134376A1 VERFAHREN ZUR HERSTELLUNG VON CYCLOHEXAN AUS BENZOL UND METHYLCYCLOPENTAN MIT VORGESCHALTETER BENZOLHYDRIERUNG 有权
标题翻译：用于生产环己烷苯和甲基环戊烷与上游苯加氢
公开(公告)号：EP3134376A1
公开(公告)日：2017-03-01
申请号：EP15716549.9
申请日：2015-04-20
申请人： BASF SE
发明人： HÜBNER, Michael , SCHULZ, Lukas , CZAJKA, Pawel , GOBIN, Oliver Christian , HOLUB, Nicole , PFEIFFER, Daniel , WEICKGENANNT, Andreas , PORTA GARCIA, Marta
IPC分类号： C07C5/10 , C07C5/29 , C07C13/18
CPC分类号： C07C5/03 , C07C5/10 , C07C5/29 , C07C5/31 , C07C7/04 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/46 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2527/08 , C07C2527/11 , C07C2527/1213 , C07C2527/126 , C07C2527/135 , C07C2531/02 , C07C2601/14 , C07C13/18
摘要： The present invention concerns a process for preparing cyclohexane from methylcyclopentane (MCP) and benzene. In the present invention, MCP and benzene are constituents of a hydrocarbon mixture (KG1) also including dimethylpentanes (DMP), optionally cyclohexane and optionally at least one compound (low boiler) selected from non-cyclic C
5 -C
6 alkanes and cyclopentane. First, benzene is reacted in a hydrogenation step to give cyclohexane (present in the hydrocarbon mixture (KG2)), while MCP is isomerized to cyclohexane in the presence of a catalyst, preferably an acidic ionic liquid. After the hydrogenation but before the isomerization, the dimethylpentanes (DMP) are removed, and initially the cyclohexane present in the hydrocarbon mixture (KG2) is removed together with DMP. This pre-isomerization cyclohexane can be freed of DMP again in a downstream step of rectification and isolated and/or returned to the cyclohexane preparation process. If the hydrocarbon mixture (KG1) comprises low boilers, they can be removed between DMP removal and MCP isomerization. Following the isomerization comes the isolation of the cyclohexane, with optional recycling of unisomerized MCP and any low boilers. The hydrocarbon mixture (KG1) preferably includes cyclohexane and/or low boilers, and so low-boiler removal between DMP removal before isomerization is a preferred operation. Also preferred is an additional removal of DMP from the cyclohexane - that is, the cyclohexane fraction arising from the benzene hydrogenation and possibly forming part of the starting mixture (KG1) is isolated and hence recovered.
摘要翻译：本发明涉及一种用于从甲基环戊烷（MCP）和苯制备环己烷的方法。在本发明的上下文中，MCP和苯是烃混合物（HM1）另外包括dimethylpentanes（DMP）的成分，可能是环己烷和无环C5-C6链烷烃和环戊烷选择可能的至少一种化合物（低沸点）。首先，苯转化成氢化步骤以环己烷（即存在于烃混合物（HM2）），而MCP在催化剂的存在下异构化，优选的酸性离子液体，环己烷。所述dimethylpentanes（DMP）被删除到异构化氢化，但先前的后，与初始移除存在于烃混合物（HM2）用DMP一起环己烷。此环己烷已经存在之前的异构化可以再次从DMP在下游精馏步骤中分离和分离和/或再循环到用于制备环己烷的过程。之间的DMP去除和MCP异构化 - 如果低沸点是存在于烃混合物（HM1） - 低沸物，任选地除去。异构化后，环己烷是孤立的，任选低沸点的未异构化的MCP和可选的回报。优选地，环己烷和/或低沸点是存在于烃混合物（HM1）等的低沸物分离从异构化的DMP之间去除优选进行。这是另外优选并除去从DMP环己烷的附加传导，意思没有环己烷组分在苯加氢它产生，并且可以存在于起始混合物（HM1）是分离的，因此回收。

7. 发明授权

EP2033943B1 Catalyst for methanation of carbon oxides, preparation method of the catalyst and process for the methanation 有权
标题翻译：一种催化剂对碳氧化物的甲烷化，处理用于催化剂和Methanierungsverfahren的制备
公开(公告)号：EP2033943B1
公开(公告)日：2017-03-01
申请号：EP08161695.5
申请日：2008-08-04
申请人： Hitachi Zosen Corporation , Hashimoto, Koji
发明人： Hashimoto, Koji Daiki Ataka Engineering Co., Ltd. , Takano, Hiroyuki Daiki Ataka Engineering Co., Ltd. , Izumiya, Kouichi Daiki Ataka Engineering Co., Ltd. , Kumagai, Naokazu Daiki Ataka Engineering Co., Ltd. , Kato, Zenta , Shinomiya, Hiroyuki
IPC分类号： C07C1/04 , C07C1/02 , B01J37/00 , B01J23/74 , B01J21/00
CPC分类号： C07C1/12 , B01J23/002 , B01J23/78 , B01J23/83 , B01J37/0236 , B01J37/04 , B01J37/08 , B01J2523/00 , C07C1/0435 , C07C1/044 , C07C2521/06 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2523/78 , C07C2523/83 , C10G2/332 , C10L3/08 , Y02P20/52 , C07C9/04 , B01J2523/23 , B01J2523/3706 , B01J2523/3737 , B01J2523/48 , B01J2523/847 , B01J2523/842 , B01J2523/3718 , B01J2523/845 , B01J2523/3762 , B01J2523/3725 , B01J2523/36 , B01J2523/22 , B01J2523/3712 , B01J2523/375
摘要： Disclosed is a catalyst for methanation reaction producing methane with high conversion by reaction of hydrogen with carbon dioxide, or a gas mixture of carbon dioxide and carbon monoxide, or a gas mixture containing these compounds as the main components. The catalyst is prepared by the steps of mixing (A) aqueous zirconia sol with salts of (B) stabilizing element(s), which is selected from the group consisting of Y, La, Ce, Pr, Nd, Sm, Gd, Dy, Ca and Mg, and (C) iron group element(s), drying and calcining the mixture to obtain a catalyst precursor, and subsequent reduction of the precursor. The catalyst comprises, by atomic %, A: 18-17%, B: 1-20% and C: 25-80% based on the elemental states of the metals. The catalyst is characterized by multiple oxide of tetragonal zirconia structure, in which not only the stabilizing element (s) but also a part of the iron group element(s) is incorporated, and on which the iron group element(s) in the metallic state is supported.

8. 发明公开

EP3132009A1 PROCESS 有权
标题翻译：处理
公开(公告)号：EP3132009A1
公开(公告)日：2017-02-22
申请号：EP15713573.2
申请日：2015-03-20
申请人： Johnson Matthey Public Limited Company
发明人： ABBOTT, Peter Edward James
IPC分类号： C10L3/08 , C10L3/10
CPC分类号： C07C1/0435 , C07C1/04 , C07C1/12 , C07C7/14816 , C07C2523/46 , C07C2523/755 , C10G2/332 , C10K3/02 , C10L3/08 , C10L3/101 , C10L2290/141 , C07C9/04
摘要： A process is described for producing a methane-containing gas mixture comprising the steps of: (i) passing a first feed gas mixture comprising hydrogen and carbon dioxide through a bed of methanation catalyst to react a portion of the hydrogen with at least a portion of the carbon dioxide and form a methane-containing gas mixture containing residual hydrogen, (ii) adding an oxygen-containing gas to the methane-containing gas mixture containing residual hydrogen to form a second feed gas mixture, and (iii) passing the second feed gas mixture through a bed of an oxidation catalyst to reactthe residual hydrogen and oxygen to form a hydrogen depleted methane-containing gas mixture. The first feed gas mixture may be a synthesis gas comprising hydrogen, carbon dioxide and carbon monoxide, and may be desulphurised before the methanation step.
摘要翻译：描述了用于生产含甲烷的气体混合物的方法，其包括以下步骤：（i）将包含氢气和二氧化碳的第一进料气体混合物通过甲烷化催化剂床以使一部分氢气与至少一部分（ii）向含有残留氢的含甲烷气体混合物中加入含氧气体以形成第二进料气体混合物，以及（iii）使第二进料气体混合物通过氧化催化剂床以使剩余的氢和氧反应以形成贫氢的含甲烷的气体混合物。第一进料气体混合物可以是包含氢气，二氧化碳和一氧化碳的合成气体，并且可以在甲烷化步骤之前脱硫。

9. 发明授权

EP2928849B1 VERFAHREN ZUR OXIDATIVEN DEHYDRIERUNG VON N-BUTENEN ZU BUTADIEN 有权
标题翻译： VERFAHREN ZUR氧化物DEHYDRIERUNG VON N-BUTENEN ZU BUTADIEN
公开(公告)号：EP2928849B1
公开(公告)日：2017-02-22
申请号：EP13802325.4
申请日：2013-12-04
申请人： BASF SE
发明人： GRÜNE, Philipp , RÜTTINGER, Wolfgang , WALSDORFF, Christian
IPC分类号： C07C5/48
CPC分类号： B01J37/08 , B01J23/882 , B01J23/883 , B01J23/8878 , B01J35/008 , B01J35/023 , B01J37/0045 , B01J2523/00 , C07C5/48 , C07C2521/08 , C07C2523/04 , C07C2523/18 , C07C2523/26 , C07C2523/28 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2523/887 , Y02P20/584 , C07C11/167 , B01J2523/13 , B01J2523/54 , B01J2523/67 , B01J2523/68 , B01J2523/842 , B01J2523/845 , B01J2523/41

10. 发明授权

EP2673248B1 LIQUID PHASE HYDROGENATION OF ALKYNES 有权
标题翻译：在液相炔烃的加氢
公开(公告)号：EP2673248B1
公开(公告)日：2016-12-28
申请号：EP12704583.9
申请日：2012-02-02
申请人： Saudi Basic Industries Corporation
发明人： MAMEDOV, Edouard , HORN, Jillian , ALLMAN, Jim , ARAUJO, Armando , SIMMONS, Meghann
IPC分类号： C07C7/163 , C07C7/167 , C07C5/09
CPC分类号： C07C7/163 , C07C5/09 , C07C7/167 , C07C2521/06 , C07C2523/22 , C07C2523/44 , C07C2523/46 , C07C2523/52 , C07C2523/755 , C07C11/02 , C07C11/04

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