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1. 发明授权

US5223565A Polymerizable compositions 失效
标题翻译：可聚合组合物
公开(公告)号：US5223565A
公开(公告)日：1993-06-29
申请号：US704454
申请日：1991-05-23
申请人： Yuuji Takayama , Hirokazu Matsueda , Maseto Sugiura , Tatsuhiko Ozaki , Hirotaka Wada , Iwao Komiya
发明人： Yuuji Takayama , Hirokazu Matsueda , Maseto Sugiura , Tatsuhiko Ozaki , Hirotaka Wada , Iwao Komiya
IPC分类号： C08K3/00 , C08F2/44 , C08F283/00 , C08F290/00 , C08F290/06 , C08F299/06 , C08K3/22 , C08L75/00 , C08L75/14 , C08L75/16
CPC分类号： C08F283/008 , Y10S525/92
摘要： Molded products with improved dimensional stability and surface property can be obtained by in-mold curing of a polymerizable composition containing unsaturated urethane of a specified structure, alkyl (meth)acrylate, and a thermoplastic macromolecular compound capable of dissolving in or swelling by impregnating alkyl (meth)acrylate. These components are contained at specified weight ratio. The mold is initially at temperature 30.degree..about.120.degree. C. and the curing is effected in the presence of a radical initiator.
摘要翻译：具有改善的尺寸稳定性和表面性能的成型制品可以通过使含有特定结构的不饱和聚氨酯的聚合性组合物（（甲基）丙烯酸酯）和能够溶解或膨胀的热塑性高分子化合物甲基）丙烯酸酯。这些组分以规定的重量比包含。模具最初温度为30℃，温度为120℃，固化在自由基引发剂存在下进行。

2. 发明授权

US5237029A Polymerizable molding liquid resins, compositions containing same and in-mold cured products therefrom 失效
标题翻译：可聚合成型液体树脂，含有该组合物的组合物及其内部固化的产品
公开(公告)号：US5237029A
公开(公告)日：1993-08-17
申请号：US851636
申请日：1992-03-16
申请人： Yuuji Takayama , Hirokazu Matsueda , Masato Sugiura , Tatsuhiko Ozaki , Hirotaka Wada , Iwao Komiya
发明人： Yuuji Takayama , Hirokazu Matsueda , Masato Sugiura , Tatsuhiko Ozaki , Hirotaka Wada , Iwao Komiya
IPC分类号： C08F299/06 , B29C39/00 , B29K33/00 , C08F2/44 , C08F20/34 , C08F212/00 , C08F212/08 , C08F220/10 , C08F220/18 , C08F290/00 , C08F290/02 , C08F290/14
CPC分类号： C08F290/147
摘要： Radical polymerizable liquid resins contain unsaturated urethane of a specified structure and vinyl monomers at weight ratio of (unsaturated urethane)/(vinyl monomers)=10/90-90/10. The unsaturated urethane has (meth)acryloyl and higher aliphatic hydrocarbon groups in its molecule, and the vinyl monomers are copolymerizable with this unsaturated urethane. Radical polymerizable liquid resin compositions are obtained by adding inorganic powder filler to such radical polymerizable liquid resins In-mold cured products obtained from such radical polymerizable resins or radical polymerizable resin compositions have improved water resistance and other favorable properties

3. 发明授权

US5185417A Polymerizable compositions and in-mold cured products using same 失效
标题翻译：可聚合组合物和使用相同的模具固化产品
公开(公告)号：US5185417A
公开(公告)日：1993-02-09
申请号：US865977
申请日：1992-04-09
申请人： Yuuji Takayama , Hirokazu Matsueda , Masato Sugiura , Tatsuhiko Ozaki , Hirotaka Wada , Iwao Komiya
发明人： Yuuji Takayama , Hirokazu Matsueda , Masato Sugiura , Tatsuhiko Ozaki , Hirotaka Wada , Iwao Komiya
IPC分类号： C08F299/02 , C08F220/36 , C08F290/00 , C08F290/06 , C08G18/08 , C08G18/67 , C08L75/00 , C08L75/16
CPC分类号： C08F220/36
摘要： Unsaturated urethane having specified molecular structure shown by Formula (1) given below and vinyl monomers which are copolymerizable with such unsaturated urethane can form together polymerizable compositions which, as well as in-mold cured products therefrom, have improved characteristics such as compatibility between the constituents and water resistance: ##STR1## where X is a residual group obtained by removing the hydroxyl groups from a trihydric or tetrahydric polyol; R.sup.1 and R.sup.3 are each H or CH.sub.3 ; R.sup.2 is higher aliphatic hydrocarbon group with 5.about.21 carbon atoms; p and q are each 1 or 2; r is an integer 0.about.2 such that p+q+r=3 or 4 and p+r=2 or 3; and a is an integer 2.about.4.

4. 发明授权

US5382619A Polymerizable compositions and in-mold cured products using same 失效
标题翻译：可聚合组合物和使用其的模内固化产物
公开(公告)号：US5382619A
公开(公告)日：1995-01-17
申请号：US54554
申请日：1993-04-28
申请人： Yuji Takayama , Hirokazu Matsueda , Masato Sugiura , Tatsuhiko Ozaki , Hirotaka Wada , Toshiharu Suzuki , Iwao Komiya
发明人： Yuji Takayama , Hirokazu Matsueda , Masato Sugiura , Tatsuhiko Ozaki , Hirotaka Wada , Toshiharu Suzuki , Iwao Komiya
IPC分类号： C08F283/00 , C08K3/22 , C08F226/02 , C08F271/00 , C08L39/00
CPC分类号： C08F283/008
摘要： A polymerizable composition contains unsaturated urethane shown by Formula (1) given below, vinyl monomer which is copolymerizable with this unsaturated urethane, and an inorganic powder filler at weight ratio of (unsaturated urethane)/(vinyl monomer)=10/90-90/10, the inorganic powder filler being 30-300 weight parts with respect to 100 weight parts of the sum of the unsaturated urethane and vinyl monomer: ##STR1## where X is a residual group obtained by removing isocyanate groups from polyisocyanate; Y is a residual group obtained by removing hydroxyl groups from polyol; R.sup.1 is a residual group obtained by removing hydroxyl group from non-radical polymerizable mono-ol having aliphatic hydrocarbon group with 6-22 carbon atoms; R.sup.2 is H or CH.sub.3 ; and p, q and r are each an integer 1-3 such that 2.ltoreq.p+q.ltoreq.4 and qr.gtoreq.2. In-mold cured products obtained from such a polymerizable composition have superior external appearance and water-resistance, and their mold shrinkage is small.
摘要翻译：聚合性组合物含有下述式（1）所示的不饱和氨基甲酸酯，可与该不饱和氨基甲酸酯共聚的乙烯基单体和（不饱和氨基甲酸酯）/（乙烯基单体）= 10/90〜90 / 10，无机粉末填料相对于不饱和聚氨酯和乙烯基单体总和的100重量份为30-300重量份：其中X是通过从多异氰酸酯除去异氰酸酯基团而获得的残基; Y是通过从多元醇中除去羟基获得的残基; R1是通过从具有6-22个碳原子的脂族烃基的不可自由基聚合的单醇中除去羟基而获得的残基; R2是H或CH3; 并且p，q和r各自是整数1-3，使得2 = p + q 4和qr> / = 2。由这种可聚合组合物获得的模内固化产物具有优异的外观和耐水性，并且它们的模具收缩率小。

5. 发明授权

US5331041A Polymerizable compositions and in-mold cured products using same 失效
标题翻译：可聚合组合物和使用其的模内固化产物
公开(公告)号：US5331041A
公开(公告)日：1994-07-19
申请号：US52634
申请日：1993-04-22
申请人： Yuji Takayama , Hirokazu Matsueda , Masato Sugiura , Tatsuhiko Ozaki , Hirotaka Wada , Toshiharu Suzuki
发明人： Yuji Takayama , Hirokazu Matsueda , Masato Sugiura , Tatsuhiko Ozaki , Hirotaka Wada , Toshiharu Suzuki
IPC分类号： B29C39/00 , B29K75/00 , B29K105/16 , C08F20/34 , C08F220/36 , C08F290/00 , C08F299/06 , C08G18/67 , C08J5/04 , C08L75/00 , C08L75/14 , C09D4/00 , C08J3/02 , C08K3/00 , C08L39/00 , C08L51/00
CPC分类号： C08G18/672 , C08F220/36 , C09D4/00 , Y10S525/92
摘要： A polymerizable composition contains unsaturated urethane shown by Formula (1) given below, vinyl monomer which is copolymerizable with this unsaturated urethane, and an inorganic powder filler at weight ratio of (unsaturated urethane)/(vinyl monomer)=10/90-90/10, the inorganic powder filler being 30-300 weight parts with respect to 100 weight parts of the sum of the unsaturated urethane and vinyl monomer: ##STR1## where R.sup.1 is hydrogen atom or methyl group; X is a residual group obtained by removing isocyanate groups from diisocyanate; Y is a residual group obtained by removing hydroxyl groups from non-radical polymerizable di-ol or tri-ol of a specified kind; Z is an organic group in the form of (R.sup.2 O).sub.m or R.sup.3 O, R.sup.2 being an alkylene group with 2-4 carbon atoms, R.sup.3 being an alkylene group with 2-12 carbon atoms, and m being an integer 2-10; and n is 2 or 3.
摘要翻译：聚合性组合物含有下述式（1）所示的不饱和氨基甲酸酯，可与该不饱和氨基甲酸酯共聚的乙烯基单体和重量比为（不饱和氨基甲酸酯）/（乙烯基单体）= 10/90〜90 / 如图10所示，无机粉末填料相对于不饱和聚氨酯和乙烯基单体的总和的100重量份为30-300重量份：其中R 1是氢原子或甲基; X是通过从二异氰酸酯中除去异氰酸酯基而获得的残基; Y是通过从特定种类的不可自由基聚合的二醇或三醇中除去羟基获得的残基; Z是（R 2 O）m或R 3 O的形式的有机基团，R 2是具有2-4个碳原子的亚烷基，R 3是具有2-12个碳原子的亚烷基，m是整数2-10; n为2或3。

6. 发明授权

US5364903A Molded products for molding compositions containing thermalsetting (meth)acrylate liquid resins 失效
标题翻译：含有热固性（甲基）丙烯酸酯液体树脂的成型组合物的成型产品
公开(公告)号：US5364903A
公开(公告)日：1994-11-15
申请号：US930975
申请日：1992-08-14
申请人： Yuji Takayama , Hirotaka Wada , Iwao Komiya
发明人： Yuji Takayama , Hirotaka Wada , Iwao Komiya
IPC分类号： C08F220/36 , C08G18/81 , C08K3/22 , C08F220/26
CPC分类号： C08G18/8116 , C08F220/36
摘要： Thermosetting (meth)acrylate molding liquid resin consisting of a specified type of unsaturated oligourethane and alkyl (meth)acrylate within a specified range of ratio. Such a specified type of unsaturated oligourethane may be obtained by reaction between 2-isocyanatoalkyl (meth)acrylate and polyhydric alcohol or by reacting 2-isocyanatoalkyl (meth)acrylate with polyhydric alcohol at molar ratio of functional groups NCO/OH between 1.1 and 1.6 to form a urethane compound and reacting hydroxyalkyl (meth)acrylate with a residual portion of 2-isocyanatoalkyl (meth)acrylate at molar ratio of functional groups OH/NCO between 1.0 and 1.5. This invention also includes molding compositions containing such liquid resin and a specified type of inorganic filler and/or a certain type of thermoplastic high molecular compound as well as molded objects obtained by curing such compositions in a mold.
摘要翻译：由指定类型的不饱和低聚氨酯和（甲基）丙烯酸烷基酯组成的热固性（甲基）丙烯酸酯成型液体树脂在指定的比例范围内。这种特定类型的不饱和低聚氨酯可以通过（甲基）丙烯酸2-异氰酸烷基酯与多元醇反应或通过使异氰酸烷基（甲基）丙烯酸酯与多元醇与官能团NCO / OH的摩尔比在1.1和1.6之间反应获得，形成氨基甲酸酯化合物，并使（甲基）丙烯酸羟烷基酯与官能团OH / NCO的摩尔比在1.0和1.5之间的残留部分的（甲基）丙烯酸-2-异氰酸烷基酯反应。本发明还包括含有这种液体树脂和特定类型的无机填料和/或某种类型的热塑性高分子化合物的模塑组合物以及通过在模具中固化这种组合物而获得的模制物品。

7. 发明授权

US5070147A Graft copolymers effective as additives to unsaturated polyester resins 失效
标题翻译：有效地作为不饱和聚酯树脂添加剂的共聚物
公开(公告)号：US5070147A
公开(公告)日：1991-12-03
申请号：US400479
申请日：1989-08-30
申请人： Tatsuhiko Ozaki , Hirotaka Wada , Fumitoshi Sugiura
发明人： Tatsuhiko Ozaki , Hirotaka Wada , Fumitoshi Sugiura
IPC分类号： C08F283/02 , C08F283/01 , C08F290/00 , C08F290/06 , C08F293/00 , C08F299/04 , C08G63/08 , C08L67/06
CPC分类号： C08F299/0485
摘要： A graft copolymer, which is effective as an additive to unsaturated polyester resins, contains 10-80 weight % of a macromonomer of a specified kind, 20-89.9 weight % of a vinyl monomer of another specified kind, and 0.1-5 weight % of vinyl monomers of still other kinds. If necessary, up to 40 weight % of still another constituent of a specified kind may be contained.

8. 发明授权

US5064900A Curable unsaturated polyester resin composition 失效
标题翻译：可固化不饱和聚酯树脂组合物
公开(公告)号：US5064900A
公开(公告)日：1991-11-12
申请号：US469748
申请日：1990-01-19
申请人： Hisayuki Iwai , Yasuhrio Mishima , Ken Hatta , Kenichi Nishino , Sanji Aoki , Tatsuhiko Ozaki , Hirotaka Wada
发明人： Hisayuki Iwai , Yasuhrio Mishima , Ken Hatta , Kenichi Nishino , Sanji Aoki , Tatsuhiko Ozaki , Hirotaka Wada
IPC分类号： C08K13/02 , C08F2/44 , C08F283/01 , C08F299/04 , C08K7/02 , C08L67/06
CPC分类号： C08L67/06
摘要： A curable unsaturated polyester resin composition contains graft copolymers each having 10-60 weight % of a first constituent given by ##STR1## 38-89.7 weight % of a second constituent given by ##STR2## and 0.3-2 weight % of a third constituent which is a vinyl monomer unit having carboxylic acid or carboxylic anhydride groups, unsaturated polyester, vinyl monomer, a filler, a curing catalyst, and reinforcing fibers, where either of R.sup.1 and R.sup.2 is H, the other being either H or CH.sub.3, R.sub.3 is ethylene group or propylene group, R.sup.4 is hydrocarbon group with 1-18 carbton atoms, R.sup.5 is alkyl group with 1-4 carbon atoms, R.sup.6 is alkyl group with 1-3 carbon atoms, m is 6-90 and n is 1-5.
摘要翻译：可固化的不饱和聚酯树脂组合物含有接枝共聚物，它们各自具有10-60重量％的第一组分，由第<！ - SIPO - >图38-89.7重量％作为具有羧酸或羧酸酐基团的乙烯基单体单元的第三组分，不饱和聚酯，乙烯基单体，填料，固化催化剂和增强纤维，其中R 1和R 2中的任一个是H，另一个是H或CH 3， R3是亚乙基或亚丙基，R4是具有1-18个碳原子的烃基，R5是1-4个碳原子的烷基，R6是1-3个碳原子的烷基，m是6-90，n是1 -5。

9. 发明申请

US20060204074A1 PC board inspecting method and apparatus and inspection logic setting method and apparatus 有权
标题翻译： PC板检查方法及装置及检查逻辑设定方法及装置
公开(公告)号：US20060204074A1
公开(公告)日：2006-09-14
申请号：US11358914
申请日：2006-02-21
申请人： Toshihiro Moriya , Hirotaka Wada , Takako Onishi , Atsushi Shimizu , Akira Nakajima
发明人： Toshihiro Moriya , Hirotaka Wada , Takako Onishi , Atsushi Shimizu , Akira Nakajima
IPC分类号： G06K9/00
CPC分类号： H05K13/08
摘要： A PC board inspecting method capable of detecting deviation of an IC component at high speed with small storage capacity utilizes inspection logic particular to a component to be inspected. The inspection logic includes a color condition for specifying a color appearing in the body of the component to be inspected. The component is radiated with a plurality of color rays at different angles of incidence. An image formed by reflection light of the color rays is captured, and an inspection image including at least part of an edge of the body of the component to be inspected is captured. By using the color condition, a component body area satisfying the color condition is extracted from the inspection image by an image process.
摘要翻译：能够以小的存储容量检测IC组件在高速下的偏差的PC板检查方法利用要检查的部件特有的检查逻辑。检查逻辑包括用于指定出现在要检查的部件的主体中的颜色的颜色条件。该组件以不同入射角的多根彩色光线照射。捕获由彩色光线的反射光形成的图像，并且捕获包括要检查的部件的主体的边缘的至少一部分的检查图像。通过使用颜色条件，通过图像处理从检查图像中提取满足色彩条件的部件体区域。

10. 发明申请

US20060153439A1 PC board inspecting apparatus, inspection logic setting method, and inspection logic setting apparatus 审中-公开
标题翻译： PC板检查装置，检查逻辑设定方法以及检查逻辑设定装置
公开(公告)号：US20060153439A1
公开(公告)日：2006-07-13
申请号：US11329432
申请日：2006-01-11
申请人： Toshihiro Moriya , Hirotaka Wada , Takako Onishi , Atsushi Shimizu , Akira Nakajima
发明人： Toshihiro Moriya , Hirotaka Wada , Takako Onishi , Atsushi Shimizu , Akira Nakajima
IPC分类号： G06K9/00
CPC分类号： G01R31/048 , G01N21/95684
摘要： A technology is provided for automatically producing an inspection logic to be used in the action of inspecting a PC board. An inspection logic setting apparatus is arranged for acquiring a plurality of first images of components to be detected by the inspection and a plurality of second images of components to be rejected by the inspection, dividing each first and second images into the plurality of blocks, calculating a color distance between the plurality of first images and the plurality of second images in each block, selecting one or more blocks from the plurality of blocks which are relatively greater in the color distance, and assigning the selected block(s) to an area condition.
摘要翻译：提供了一种技术，用于自动产生在检查PC板的动作中使用的检查逻辑。一种检查逻辑设置装置，用于通过检查获取待检测的成分的多个第一图像以及通过检查要被拒绝的成分的多个第二图像，将每个第一和第二图像划分成多个块，计算在每个块中的多个第一图像和多个第二图像之间的颜色距离，从多个颜色距离相对较大的多个块中选择一个或多个块，并将所选择的块分配给区域条件。

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