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1. 发明授权

US4701524A Pyridone monoazo compound having vinylsulfone type fiber-reactive group 失效
标题翻译：具有乙烯基砜型纤维反应性基团的吡啶酮单偶氮化合物
公开(公告)号：US4701524A
公开(公告)日：1987-10-20
申请号：US795123
申请日：1985-11-05
申请人： Yutaka Kayane , Hirokazu Sawamoto , Takashi Omura , Naoki Harada , Akira Takeshita
发明人： Yutaka Kayane , Hirokazu Sawamoto , Takashi Omura , Naoki Harada , Akira Takeshita
IPC分类号： C09B62/51 , D06P1/38 , D06P1/384 , C09B62/45 , C09B62/53 , D06P3/66
CPC分类号： C09B62/51
摘要： A monoazo compound, or a salt thereof, of the formula, ##STR1## wherein W is a hydrogen atom or a carbamoyl group, R.sub.1 is a lower alkyl group, R.sub.2 and R.sub.3 are independently a hydrogen atom or a lower alkyl group, A is an unsubstituted or substituted phenylene or naphthylene group, Y is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Z, in which Z is a group capable of being split by the action of an alkali, and X is an aromatic or aliphatic group substituted with one or two members selected from sulfonic acid group and carboxylic acid group, which is useful for dyeing fiber materials to give dyed products of a characteristic yellow color excellent in various fastness properties.
摘要翻译：下式的单偶氮化合物或其盐，其中W是氢原子或氨基甲酰基，R1是低级烷基，R2和R3独立地是氢原子或低级烷基，A是未取代或取代的亚苯基或亚萘基，Y是-SO 2 CH = CH 2或-SO 2 CH 2 CH 2 Z，其中Z是能够被碱作用的基团，X是被一个或两个成员取代的芳族或脂族基团选自磺酸基和羧酸基，其可用于染色纤维材料以得到具有优异的各种牢度性质的特征黄色的染色产品。

2. 发明授权

US4618671A 4-methyl-pyridone monoazo compound having both monochlorotriazinyl and vinylsulfone type fiber-reactive groups 失效
标题翻译：具有单氯三嗪基和乙烯基砜型纤维反应性基团的4-甲基 - 吡啶酮单偶氮化合物
公开(公告)号：US4618671A
公开(公告)日：1986-10-21
申请号：US682241
申请日：1984-12-17
申请人： Yutaka Kayane , Tetsuya Miyamoto , Takashi Omura , Hirokazu Sawamoto , Naoki Harada , Akira Takeshita
发明人： Yutaka Kayane , Tetsuya Miyamoto , Takashi Omura , Hirokazu Sawamoto , Naoki Harada , Akira Takeshita
IPC分类号： C09B62/51 , C09B62/44 , D06P1/38 , D06P1/384 , C09B62/085 , C09B62/53 , D06P1/382 , D06P3/66
CPC分类号： C09B62/4413 , D06P1/384
摘要： A pyridone compound of the following formula, or a salt thereof, ##STR1## wherein R.sub.1 and R.sub.2 are independently a hydrogen atom or a lower alkyl group having up to 4 carbon atoms, X is a hydrogen atom or a methyl or sulfo group, A is an unsubstituted or substituted phenylene or naphthylene group, and Y is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Z, in which Z is a group capable of being split by the action of an alkali. The compound is useful for dyeing or printing fiber materials to give a dyed product of a brilliant yellow color excellent in various fastness properties with good reproducibility.
摘要翻译：下式的吡啶酮化合物或其盐，其中R 1和R 2独立地为氢原子或具有至多4个碳原子的低级烷基，X为氢原子或甲基或磺基，A 是未取代或取代的亚苯基或亚萘基，Y是-SO 2 CH = CH 2或-SO 2 CH 2 CH 2 Z，其中Z是能够通过碱的作用而分裂的基团。该化合物可用于染色或印刷纤维材料，得到具有良好重现性的各种牢度性能优异的亮黄色染色产品。

3. 发明授权

US4843149A Fiber reactive yellow dye of acetoacetonilide having vinyl sulfone-type reactive group 失效
标题翻译：具有乙烯基砜型反应性基团的乙酰乙酰苯胺的纤维活性黄色染料
公开(公告)号：US4843149A
公开(公告)日：1989-06-27
申请号：US797488
申请日：1985-11-13
申请人： Yutaka Kayane , Hirokazu Sawamoto , Takashi Omura , Naoki Harada , Akira Takeshita
发明人： Yutaka Kayane , Hirokazu Sawamoto , Takashi Omura , Naoki Harada , Akira Takeshita
IPC分类号： C09B62/44
CPC分类号： C09B62/4413 , Y10S534/01
摘要： A monoazo compound, or a salt thereof, represented by the formula, ##STR1## wherein D is a sulfophenyl group substituted with a methyl, ethyl, methoxy, ethoxy, phenoxy, acetylamino, pripionylamino, benzoylamino, carboxybenzoylamino, maleinylamino or succinylamino group, a naphthyl group substituted with two or three sulfo groups of a group of the formula ##STR2## any one of X.sub.1 or X.sub.2 is a sulfo group and the other is a methoxy or ethoxy group, Y is a fluorine or chlorine atom or an arylamino group substituted with one or two sulfo groups, R is a hydrogen atom or an unsubstituted or substituted lower alkyl group, A is an unsubstituted or substitued phenylene or naphthylene group, and Z is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub..sub.2 CH.sub.2 Z.sub.1 in which Z.sub.1 is a group capable of being split by the action of an alkali, which is useful as a fiber-reactive dye for dyeing materials in a greenish yellow color excellent in various fastness properties.
摘要翻译：其中D为被甲基，乙基，甲氧基，乙氧基，苯氧基，乙酰氨基，丙酰氨基，苯甲酰基氨基，羧基苯甲酰氨基，马来酰氨基或琥珀酰氨基取代的磺基苯基的单偶氮化合物或其盐，被两个或三个下式的基团取代的萘基：X 1或X 2中的任一个是磺基，另一个是甲氧基或乙氧基，Y是氟或氯原子或芳基氨基取代的具有一个或两个磺基，R为氢原子或未取代或取代的低级烷基，A为未取代或取代的亚苯基或亚萘基，Z为-SO2CH = CH2或-SO2CH2CH2Z1，其中Z1为能够通过碱的作用分裂，其可用作用于以各种牢度性能优异的绿黄色染色材料的纤维活性染料。

4. 发明授权

US4698421A Fiber-reactive disazo brown dye having vinylsulfone-type reactive group 失效
标题翻译：具有乙烯基砜型反应性基团的纤维反应性二偶氮棕色染料
公开(公告)号：US4698421A
公开(公告)日：1987-10-06
申请号：US742309
申请日：1985-06-07
申请人： Yutaka Kayane , Hirokazu Sawamoto , Takashi Omura , Naoki Harada
发明人： Yutaka Kayane , Hirokazu Sawamoto , Takashi Omura , Naoki Harada
IPC分类号： C09B62/44 , C09B62/513 , D06P1/38 , C09B62/453 , C09B62/533 , D06P1/384 , D06P3/66
CPC分类号： C09B62/4415 , C09B62/513
摘要： A compound, or a salt thereof, represented by the following formula, ##STR1## wherein A is a substituted or unsubstituted phenylene or naphthylene group, B is ##STR2## in which R.sub.3 is a hydrogen atom or a lower alkyl, lower alkoxy, acylamino or ureido group, and R.sub.4 is a hydrogen atom or a lower alkyl or lower alkoxy group, R.sub.1 and R.sub.3 are independently a hydrogen atom or a substituted or unsubstituted lower alkyl group, X is a substituted or unsubstituted amino, lower alkoxy, substituted phenoxy or sulfo group, Y is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Z, in which Z is a group capable of being split by the action of an alkali, and m is 2 or 3, which is useful for dyeing hydroxyl group- or amide group-containing fiber materials to give dyed products of a brown color having excellent fastness properties with good build-up property.
摘要翻译：由下式表示的化合物或其盐，其中A是取代或未取代的亚苯基或亚萘基，B是其中R 3是氢原子或低级烷基，低级烷氧基，酰氨基或脲基，R4为氢原子或低级烷基或低级烷氧基，R1和R3独立地为氢原子或取代或未取代的低级烷基，X为取代或未取代的氨基，低级烷氧基，取代的苯氧基或磺基，Y是-SO 2 CH = CH 2或-SO 2 CH 2 CH 2 Z，其中Z是能够被碱作用分裂的基团，m是2或3，其可用于染色羟基 - 或含酰胺基的纤维材料，得到棕色的染色产品，具有优异的耐牢度性能和良好的聚集性能。

5. 发明授权

US6136970A Asymmetric dioxazine compounds and method for dyeing or printing fiber materials using the same 失效
标题翻译：不对称二恶嗪化合物及其染色或印花方法
公开(公告)号：US6136970A
公开(公告)日：2000-10-24
申请号：US967617
申请日：1992-10-29
申请人： Kazufumi Yokogawa , Takahiko Fujisaki , Miyao Takahashi , Shigeru Kawabata , Naoki Harada , Kingo Akahori , Yutaka Kayane , Takashi Omura
发明人： Kazufumi Yokogawa , Takahiko Fujisaki , Miyao Takahashi , Shigeru Kawabata , Naoki Harada , Kingo Akahori , Yutaka Kayane , Takashi Omura
IPC分类号： C07D265/34 , C09B19/00 , C09B62/002 , C09B62/02 , C09B62/44 , C09B62/503 , C07D498/04
CPC分类号： C09B62/5033 , C09B62/0025 , C09B62/021 , C09B62/4405
摘要： An asymmetric dioxazine compound represented by the following formula (I) in the free acid form: ##STR1## wherein A.sub.1 and A.sub.2 independently of one another are each sulfo, halo, alkyl or alkoxy, X.sub.1 and X.sub.2 independently of one another are each hydrogen, halo, alkyl, alkoxy or phenoxy, R.sub.1 is hydrogen or unsubstituted or substituted alkyl, R.sub.2 and R.sub.3 independently of one another are each hydrogen, alkyl, alkoxy, halo or unsubstituted or substituted amino, Z is a fiber-reactive group, m and n independently of one another are each 0 or 1, provided that m.noteq.n, and L is 1 or 2. This compound is suitable for dyeing and printing cellulose fiber, natural and synthetic polyamide fibers, polyurethane fiber, leather and the like and mixed yarns thereof, to obtain dyed or printed products of a color fast to light, wetness and chlorine with superior build-up and level dyeing properties.
摘要翻译：由游离酸形式的下式（I）表示的不对称二嗪类化合物：其中A1和A2彼此独立地各自为磺基，卤素，烷基或烷氧基，X 1和X 2彼此独立地为氢，卤素，烷基，烷氧基或苯氧基，R 1是氢或未取代或取代的烷基，R 2和R 3彼此独立地各自为氢，烷基，烷氧基，卤素或未取代或取代的氨基，Z为纤维反应性基团，m和n独立地为一个另外每个都为0或1，条件是m注意n和L为1或2.该化合物适用于将纤维素纤维，天然和合成聚酰胺纤维，聚氨酯纤维，皮革等及其混合纱线染色和印刷到获得染色或印刷的产品，颜色快速到轻，湿和氯，具有优异的积聚和水平的染色性能。

6. 发明授权

US5266696A 1-aminoanthraquinone dye compound having fiber reactive group through sulfur or oxygen atom at 4-position and imparting red color 失效
标题翻译：具有纤维反应性基团的1-氨基蒽醌染料化合物，通过硫或氧原子在4位上赋予红色
公开(公告)号：US5266696A
公开(公告)日：1993-11-30
申请号：US836825
申请日：1992-02-19
申请人： Kingo Akahori , Naoki Harada , Yutaka Kayane , Takashi Omura
发明人： Kingo Akahori , Naoki Harada , Yutaka Kayane , Takashi Omura
IPC分类号： C09B62/024 , C09B62/44 , C09B62/505 , C07D251/70 , C09B62/06 , D06P1/382 , D06P1/384
CPC分类号： C09B62/024 , C09B62/4409 , C09B62/505
摘要： Anthraquinone compounds of the formula, ##STR1## wherein R is hydrogen, alkyl or the like, R.sub.1 and R.sub.2 are each hydrogen, halogen or sulfo, l is 1 or 2, X is sulfo or the like or --V--A--(W).sub.m --Z, and Y is --V.sub.1 --A.sub.1 --U, wherein V and V.sub.1 are each --O-- or --S--, A and A.sub.1 are each a divalent group such as ##STR2## W is --NH-- or the like, Z is hydrogen or a fiber reactive group, and U is hydrogen, a fiber reactive group or a fiber reactive group-containing group, provided that at least one of Z and U is or has a fiber reactive group, which is useful for dyeing or printing fiber materials such as cotton to give a dyed or printed product having excellent fastness properties, particularly those such as light fastness and perspiration-light fastness.
摘要翻译：下式的蒽醌化合物，其中R是氢，烷基等，R 1和R 2各自为氢，卤素或磺基，l为1或2，X为磺基等或-VA-（W）mZ ，Y为-V1-A1-U，其中V和V1各自为-O-或-S-，A和A1各自为二价基团，例如W为-NH-等，Z为氢或纤维反应性基团，U为氢，纤维反应性基团或含纤维反应性基团，条件是Z和U中的至少一个为或具有纤维反应性基团，其可用于染色或印刷纤维材料例如棉，以得到具有优异坚牢性的染色或印刷产品，特别是耐光牢度和耐汗牢度等。

7. 发明授权

US4977261A Anthraquinone compound 失效
标题翻译：蒽醌化合物
公开(公告)号：US4977261A
公开(公告)日：1990-12-11
申请号：US141762
申请日：1988-01-11
申请人： Yutaka Kayane , Takashi Omura , Naoki Harada , Yasuji Mori , Yosuke Yamamoto , Tetsuya Miyamoto , Takehiro Kusumoto
发明人： Yutaka Kayane , Takashi Omura , Naoki Harada , Yasuji Mori , Yosuke Yamamoto , Tetsuya Miyamoto , Takehiro Kusumoto
IPC分类号： C09B62/505
CPC分类号： C09B62/505
摘要： A compound of the following formula in the free acid form, ##STR1## wherein and R and R.sub.1 are each hydrogen or alkyl, A is a divalent group of the formula, ##STR2## wherein R.sub.3, R.sub.4 and R.sub.5 are each hydrogen, methyl, ethyl, methoxy or ethoxy, m is 0 or 1, n, u and v are each 0, 1 or 2, p is 0, 1, 2 or 3, q and s are each an integer of 2 to 6, and r is 1 or 2, B.sub.1 is phenylene or naphthylene, Z.sub.1 is vinyl, .beta.-sulfatoethyl or the like, l is 0, 1 or 2, and X is a group of the formula, ##STR3## wherein R.sub.2 is hydrogen or alkyl, B.sub.2 is phenylene or naphtylene, Z.sub.2 is vinyl, .beta.-sulfatoethyl or the like, R.sub.6 and R.sub.7 are each hydrogen, alkyl, phenyl, naphthyl or benzyl, and R, A and l are as defined above, which is useful for dyeing or printing fiber materials to give a dyed or printed product of a brilliant blue color superior in fastness properties such as light fastness and perspiration-light fastness, with superior build-up property.

8. 发明授权

US4975094A Anthrapyridone compounds having vinylsulfone type fiber reactive group through triazinyl bridging group 失效
标题翻译：通过三嗪基桥连基团具有乙烯基砜型纤维反应性基团的蒽并吡啶酮化合物
公开(公告)号：US4975094A
公开(公告)日：1990-12-04
申请号：US390278
申请日：1989-08-07
申请人： Masayuki Miki , Kingo Akahori , Yutaka Kayane , Naoki Harada , Takashi Omura
发明人： Masayuki Miki , Kingo Akahori , Yutaka Kayane , Naoki Harada , Takashi Omura
IPC分类号： C09B62/44 , C09B62/505
CPC分类号： C09B62/505 , C09B62/4403
摘要： Anthrapyridone compounds of the formula, ##STR1## wherein R.sub.1 is hydrogen, benzoyl, acetyl or alkyloxycarbonyl, R.sub.2 is hydrogen or alkyl, R.sub.3 is hydrogen, halogen, sulfo, phenoxy, phenylthio or alkoxy, R.sub.4 is hydrogen, halogen or sulfo, R.sub.5 and R.sub.6 are each hydrogen or alkyl, V is --O--, --S-- or ##STR2## in which R.sub.7 is hydrogen, acetyl or alkyl, B is phenylene or naphthylene, D is vinyl or --CH.sub.2 CH.sub.2 L such as --CH.sub.2 CH.sub.2 OSO.sub.3 H, A is a divalent group, and X is halogen, quaternary ammonium, pyridinio, amino or a ##STR3## like group, which are useful for dyeing or printing fiber materials with superior dyeing performance.

9. 发明授权

US4626589A Organic dye compound having both pyridiniotriazinyl and vinylsulfone type fiber-reactive groups 失效
标题翻译：具有吡啶并三嗪基和乙烯基砜型纤维反应性基团的有机染料化合物
公开(公告)号：US4626589A
公开(公告)日：1986-12-02
申请号：US699182
申请日：1985-02-07
申请人： Takashi Omura , Yutaka Kayane , Mikoto Takahashi , Tetsuya Miyamoto , Akira Takeshita , Naoki Harada , Katsumasa Otake
发明人： Takashi Omura , Yutaka Kayane , Mikoto Takahashi , Tetsuya Miyamoto , Akira Takeshita , Naoki Harada , Katsumasa Otake
IPC分类号： C09B62/002 , C09B62/04 , C09B62/44 , C09B62/503 , D06P1/38 , C09B44/02 , C09B44/08 , C09B62/523 , C09B62/527
CPC分类号： C09B62/4403 , D06P1/38
摘要： A compound of the formula, ##STR1## wherein D is an organic dye moiety, R.sub.1 and R.sub.2 are independently hydrogen or a substituted or unsubstituted lower alkyl group, R.sub.3 is hydrogen or a substituted or unsubstituted lower alkyl, phenyl or naphthyl group, X.sub.1 and X.sub.2 are independently hydrogen, halogen or a lower alkyl, cyano, carbamoyl, vinyl, .beta.-hydroxyethyl, .beta.-sulfoethyl, .beta.-sulfatoethyl, carboxyl, carboxylic acid ester or sulfonic acid group, and Z is appended to the above-defined D or R.sub.3 and stands for --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Y, in which Y is a group capable of being split by the action of an alkali, which is useful for dyeing hydroxyl or amido group-containing fiber materials with excellent build-up properties, thereby giving dyed products having excellent various fastness properties.
摘要翻译：下式的化合物，其中D是有机染料部分，R1和R2独立地是氢或取代或未取代的低级烷基，R3是氢或取代或未取代的低级烷基，苯基或萘基，X1和 X 2独立地是氢，卤素或低级烷基，氰基，氨基甲酰基，乙烯基，β-羟基乙基，β-磺基乙基，β-磺基乙基，羧基，羧酸酯或磺酸基，并且Z附加到上述定义的D或 R3代表-SO2CH = CH2或-SO2CH2CH2Y，其中Y是能够通过碱的作用分裂的基团，其可用于染色具有优异累积性质的含羟基或含酰胺基的纤维材料，因此给出具有优异的各种牢度特性的染色产品。

10. 发明授权

US5486607A Dioxazine blue dye compound having vinylsulfone type fiber reactive groups 失效
标题翻译：具有乙烯基砜型纤维反应性基团的二恶嗪蓝染料化合物
公开(公告)号：US5486607A
公开(公告)日：1996-01-23
申请号：US379028
申请日：1995-01-27
申请人： Tetsuya Miyamoto , Miyao Takahashi , Takahiko Fujisaki , Naoki Harada , Yutaka Kayane , Takashi Omura
发明人： Tetsuya Miyamoto , Miyao Takahashi , Takahiko Fujisaki , Naoki Harada , Yutaka Kayane , Takashi Omura
IPC分类号： C07D498/04 , C09B62/503 , D06P1/38
CPC分类号： C09B62/5033
摘要： A dioxazine compound represented by the following formula in the free acid form, ##STR1## wherein V is a direct linkage or ##STR2## in which R.sub.3 is hydrogen or alkyl, X is a direct linkage or an aliphatic, araliphatic or aromatic bridging group, Y is phenylene or naphthylene, Z is a so-called vinylsulfone type fiber reactive group, and R.sub.1 and R.sub.2 are each hydrogen or alkyl, which is useful for dyeing or printing fiber materials to give a dyed or printed product of a blue color superior in fastness properties with superior build-up property.
摘要翻译：由游离酸形式的下式表示的二恶嗪化合物，其中V是直接键合或其中R 3是氢或烷基，X是直链或者脂族，芳脂族或芳族桥连基团，Y为亚苯基或亚萘基，Z为所谓的乙烯基砜型纤维反应性基团，R 1和R 2各自为氢或烷基，可用于染色或印花纤维材料染色或具有优异的牢固性能的蓝色的印刷产品具有优异的堆积性能。

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