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1. 发明授权

US4626589A Organic dye compound having both pyridiniotriazinyl and vinylsulfone type fiber-reactive groups 失效
标题翻译：具有吡啶并三嗪基和乙烯基砜型纤维反应性基团的有机染料化合物
公开(公告)号：US4626589A
公开(公告)日：1986-12-02
申请号：US699182
申请日：1985-02-07
申请人： Takashi Omura , Yutaka Kayane , Mikoto Takahashi , Tetsuya Miyamoto , Akira Takeshita , Naoki Harada , Katsumasa Otake
发明人： Takashi Omura , Yutaka Kayane , Mikoto Takahashi , Tetsuya Miyamoto , Akira Takeshita , Naoki Harada , Katsumasa Otake
IPC分类号： C09B62/002 , C09B62/04 , C09B62/44 , C09B62/503 , D06P1/38 , C09B44/02 , C09B44/08 , C09B62/523 , C09B62/527
CPC分类号： C09B62/4403 , D06P1/38
摘要： A compound of the formula, ##STR1## wherein D is an organic dye moiety, R.sub.1 and R.sub.2 are independently hydrogen or a substituted or unsubstituted lower alkyl group, R.sub.3 is hydrogen or a substituted or unsubstituted lower alkyl, phenyl or naphthyl group, X.sub.1 and X.sub.2 are independently hydrogen, halogen or a lower alkyl, cyano, carbamoyl, vinyl, .beta.-hydroxyethyl, .beta.-sulfoethyl, .beta.-sulfatoethyl, carboxyl, carboxylic acid ester or sulfonic acid group, and Z is appended to the above-defined D or R.sub.3 and stands for --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Y, in which Y is a group capable of being split by the action of an alkali, which is useful for dyeing hydroxyl or amido group-containing fiber materials with excellent build-up properties, thereby giving dyed products having excellent various fastness properties.
摘要翻译：下式的化合物，其中D是有机染料部分，R1和R2独立地是氢或取代或未取代的低级烷基，R3是氢或取代或未取代的低级烷基，苯基或萘基，X1和 X 2独立地是氢，卤素或低级烷基，氰基，氨基甲酰基，乙烯基，β-羟基乙基，β-磺基乙基，β-磺基乙基，羧基，羧酸酯或磺酸基，并且Z附加到上述定义的D或 R3代表-SO2CH = CH2或-SO2CH2CH2Y，其中Y是能够通过碱的作用分裂的基团，其可用于染色具有优异累积性质的含羟基或含酰胺基的纤维材料，因此给出具有优异的各种牢度特性的染色产品。

2. 发明授权

US4618671A 4-methyl-pyridone monoazo compound having both monochlorotriazinyl and vinylsulfone type fiber-reactive groups 失效
标题翻译：具有单氯三嗪基和乙烯基砜型纤维反应性基团的4-甲基 - 吡啶酮单偶氮化合物
公开(公告)号：US4618671A
公开(公告)日：1986-10-21
申请号：US682241
申请日：1984-12-17
申请人： Yutaka Kayane , Tetsuya Miyamoto , Takashi Omura , Hirokazu Sawamoto , Naoki Harada , Akira Takeshita
发明人： Yutaka Kayane , Tetsuya Miyamoto , Takashi Omura , Hirokazu Sawamoto , Naoki Harada , Akira Takeshita
IPC分类号： C09B62/51 , C09B62/44 , D06P1/38 , D06P1/384 , C09B62/085 , C09B62/53 , D06P1/382 , D06P3/66
CPC分类号： C09B62/4413 , D06P1/384
摘要： A pyridone compound of the following formula, or a salt thereof, ##STR1## wherein R.sub.1 and R.sub.2 are independently a hydrogen atom or a lower alkyl group having up to 4 carbon atoms, X is a hydrogen atom or a methyl or sulfo group, A is an unsubstituted or substituted phenylene or naphthylene group, and Y is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Z, in which Z is a group capable of being split by the action of an alkali. The compound is useful for dyeing or printing fiber materials to give a dyed product of a brilliant yellow color excellent in various fastness properties with good reproducibility.
摘要翻译：下式的吡啶酮化合物或其盐，其中R 1和R 2独立地为氢原子或具有至多4个碳原子的低级烷基，X为氢原子或甲基或磺基，A 是未取代或取代的亚苯基或亚萘基，Y是-SO 2 CH = CH 2或-SO 2 CH 2 CH 2 Z，其中Z是能够通过碱的作用而分裂的基团。该化合物可用于染色或印刷纤维材料，得到具有良好重现性的各种牢度性能优异的亮黄色染色产品。

3. 发明授权

US4511507A Monoazo compound having both monochlorotriazinyl and vinylsulfone type reactive groups 失效
标题翻译：具有单氯三嗪基和乙烯基砜型反应性基团的单偶氮化合物
公开(公告)号：US4511507A
公开(公告)日：1985-04-16
申请号：US563587
申请日：1983-12-20
申请人： Yutaka Kayane , Takashi Omura , Katsumasa Otake , Akira Takeshita
发明人： Yutaka Kayane , Takashi Omura , Katsumasa Otake , Akira Takeshita
IPC分类号： C09B33/10 , C09B62/44 , C09B62/51 , D06P1/38 , C09B62/08 , D06P3/10
CPC分类号： D06P1/38 , C09B62/4413 , Y10S8/918
摘要： A monoazo compound which is useful for dyeing or printing fiber materials, particularly cellulose fiber materials in red color, and which is represented by a free acid of the formula, ##STR1## wherein D is a phenyl group substituted with one to three substituents selected from the group consisting of halogen atoms and methyl, ethyl, methoxy, ethoxy, acetylamino, propionylamino, sulfo and carboxyl groups, R is a C.sub.1 to C.sub.4 alkyl group unsubstituted or substituted with a halogen atom or a hydroxyl, cyano, alkyl, alkoxy, carboxyl, carbamoyl, alkoxycarbonyl or sulfo group, A is a phenylene group unsubstituted or substituted with one or two substituents selected from the group consisting of methyl, ethyl, methoxy, ethoxy and sulfo groups and chlorine and bromine atoms, or a naphthylene group unsubstituted or substituted with one sulfo group, and X is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Y in which Y is a group capable of being split by the action of an alkali.
摘要翻译：用于染色或印刷纤维材料，特别是红色的纤维素纤维材料的单偶氮化合物，其由下式的游离酸表示，其中D是被一至三个选自以下的取代基取代的苯基：由卤素原子和甲基，乙基，甲氧基，乙氧基，乙酰氨基，丙酰氨基，磺基和羧基组成的基团，R是未被取代或被卤素原子或羟基，氰基，烷基，烷氧基，羧基取代的C1至C4烷基，氨基甲酰基，烷氧基羰基或磺基，A是未被取代或被一个或两个选自甲基，乙基，甲氧基，乙氧基和磺基以及氯和溴原子的取代基取代的亚苯基，或未取代或取代的亚萘基具有一个磺基，X是-SO 2 CH = CH 2或-SO 2 CH 2 CH 2 Y，其中Y是能够通过碱的作用而分裂的基团。

4. 发明授权

US4631341A Anthraquinone compound having both monohalogenotriazinyl and vinylsulfone type fiber reactive groups 失效
标题翻译：具有单卤代三嗪基和乙烯基砜型纤维反应性基团的蒽醌化合物
公开(公告)号：US4631341A
公开(公告)日：1986-12-23
申请号：US610750
申请日：1984-05-16
申请人： Yutaka Kayane , Takashi Omura , Katsumasa Otake , Akira Takeshita
发明人： Yutaka Kayane , Takashi Omura , Katsumasa Otake , Akira Takeshita
IPC分类号： C09B62/44 , D06P1/38 , C07D251/50
CPC分类号： C09B62/4409 , D06P1/38
摘要： A compound, or a salt thereof, represented by the formula, ##STR1## wherein X is a halogen atom, Y is a group of --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Z (in which Z is a group capable of being split by the action of an alkali), A is an unsubstituted or substituted phenylene or naphthylene group, B is a cycloalkylene group of the formula, ##STR2## an arylene group of the formula, ##STR3## or an alkylene of the formula --(CH.sub.2).sub.1 --, (in which R.sub.3 and R.sub.4 are independently a hydrogen atom or a methyl, ethyl or methoxy group, n is 0, 1 or 2 and 1 is an integer of 2 to 6), R.sub.1 and R.sub.2 are independently a hydrogen atom or an unsubstituted or substituted lower alkyl group, and m is 0, 1 or 2, provided that the group Y is located at m- or p-position to the group ##STR4## when B is the arylene group, which is useful for dyeing fiber materials, particularly cellulose fiber materials, in a blue color having excellent fastness, with excellent build-up and level-dyeing properties.
摘要翻译：由下式表示的化合物或其盐，其中X是卤素原子，Y是-SO 2 CH = CH 2或-SO 2 CH 2 CH 2 Z的基团（其中Z是能够通过 A是未取代或取代的亚苯基或亚萘基，B是下式的亚环烷基，下式的亚芳基，或者式 - （CH 2）1 - 的亚烷基，（其中R 3和R 4独立地为氢原子或甲基，乙基或甲氧基，n为0,1或2，1为2至6的整数），R 1和R 2独立地为氢原子或未取代的或未取代的取代的低级烷基，并且m为0,1或2，条件是当B是亚芳基时，基团Y位于基团“m”或p位置，这可用于染色纤维材料，特别是纤维素纤维材料，具有优异坚牢度的蓝色，具有优异的聚集和水平染色性能。

5. 发明授权

US4701524A Pyridone monoazo compound having vinylsulfone type fiber-reactive group 失效
标题翻译：具有乙烯基砜型纤维反应性基团的吡啶酮单偶氮化合物
公开(公告)号：US4701524A
公开(公告)日：1987-10-20
申请号：US795123
申请日：1985-11-05
申请人： Yutaka Kayane , Hirokazu Sawamoto , Takashi Omura , Naoki Harada , Akira Takeshita
发明人： Yutaka Kayane , Hirokazu Sawamoto , Takashi Omura , Naoki Harada , Akira Takeshita
IPC分类号： C09B62/51 , D06P1/38 , D06P1/384 , C09B62/45 , C09B62/53 , D06P3/66
CPC分类号： C09B62/51
摘要： A monoazo compound, or a salt thereof, of the formula, ##STR1## wherein W is a hydrogen atom or a carbamoyl group, R.sub.1 is a lower alkyl group, R.sub.2 and R.sub.3 are independently a hydrogen atom or a lower alkyl group, A is an unsubstituted or substituted phenylene or naphthylene group, Y is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Z, in which Z is a group capable of being split by the action of an alkali, and X is an aromatic or aliphatic group substituted with one or two members selected from sulfonic acid group and carboxylic acid group, which is useful for dyeing fiber materials to give dyed products of a characteristic yellow color excellent in various fastness properties.
摘要翻译：下式的单偶氮化合物或其盐，其中W是氢原子或氨基甲酰基，R1是低级烷基，R2和R3独立地是氢原子或低级烷基，A是未取代或取代的亚苯基或亚萘基，Y是-SO 2 CH = CH 2或-SO 2 CH 2 CH 2 Z，其中Z是能够被碱作用的基团，X是被一个或两个成员取代的芳族或脂族基团选自磺酸基和羧酸基，其可用于染色纤维材料以得到具有优异的各种牢度性质的特征黄色的染色产品。

6. 发明授权

US4977261A Anthraquinone compound 失效
标题翻译：蒽醌化合物
公开(公告)号：US4977261A
公开(公告)日：1990-12-11
申请号：US141762
申请日：1988-01-11
申请人： Yutaka Kayane , Takashi Omura , Naoki Harada , Yasuji Mori , Yosuke Yamamoto , Tetsuya Miyamoto , Takehiro Kusumoto
发明人： Yutaka Kayane , Takashi Omura , Naoki Harada , Yasuji Mori , Yosuke Yamamoto , Tetsuya Miyamoto , Takehiro Kusumoto
IPC分类号： C09B62/505
CPC分类号： C09B62/505
摘要： A compound of the following formula in the free acid form, ##STR1## wherein and R and R.sub.1 are each hydrogen or alkyl, A is a divalent group of the formula, ##STR2## wherein R.sub.3, R.sub.4 and R.sub.5 are each hydrogen, methyl, ethyl, methoxy or ethoxy, m is 0 or 1, n, u and v are each 0, 1 or 2, p is 0, 1, 2 or 3, q and s are each an integer of 2 to 6, and r is 1 or 2, B.sub.1 is phenylene or naphthylene, Z.sub.1 is vinyl, .beta.-sulfatoethyl or the like, l is 0, 1 or 2, and X is a group of the formula, ##STR3## wherein R.sub.2 is hydrogen or alkyl, B.sub.2 is phenylene or naphtylene, Z.sub.2 is vinyl, .beta.-sulfatoethyl or the like, R.sub.6 and R.sub.7 are each hydrogen, alkyl, phenyl, naphthyl or benzyl, and R, A and l are as defined above, which is useful for dyeing or printing fiber materials to give a dyed or printed product of a brilliant blue color superior in fastness properties such as light fastness and perspiration-light fastness, with superior build-up property.

7. 发明授权

US4843149A Fiber reactive yellow dye of acetoacetonilide having vinyl sulfone-type reactive group 失效
标题翻译：具有乙烯基砜型反应性基团的乙酰乙酰苯胺的纤维活性黄色染料
公开(公告)号：US4843149A
公开(公告)日：1989-06-27
申请号：US797488
申请日：1985-11-13
申请人： Yutaka Kayane , Hirokazu Sawamoto , Takashi Omura , Naoki Harada , Akira Takeshita
发明人： Yutaka Kayane , Hirokazu Sawamoto , Takashi Omura , Naoki Harada , Akira Takeshita
IPC分类号： C09B62/44
CPC分类号： C09B62/4413 , Y10S534/01
摘要： A monoazo compound, or a salt thereof, represented by the formula, ##STR1## wherein D is a sulfophenyl group substituted with a methyl, ethyl, methoxy, ethoxy, phenoxy, acetylamino, pripionylamino, benzoylamino, carboxybenzoylamino, maleinylamino or succinylamino group, a naphthyl group substituted with two or three sulfo groups of a group of the formula ##STR2## any one of X.sub.1 or X.sub.2 is a sulfo group and the other is a methoxy or ethoxy group, Y is a fluorine or chlorine atom or an arylamino group substituted with one or two sulfo groups, R is a hydrogen atom or an unsubstituted or substituted lower alkyl group, A is an unsubstituted or substitued phenylene or naphthylene group, and Z is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub..sub.2 CH.sub.2 Z.sub.1 in which Z.sub.1 is a group capable of being split by the action of an alkali, which is useful as a fiber-reactive dye for dyeing materials in a greenish yellow color excellent in various fastness properties.
摘要翻译：其中D为被甲基，乙基，甲氧基，乙氧基，苯氧基，乙酰氨基，丙酰氨基，苯甲酰基氨基，羧基苯甲酰氨基，马来酰氨基或琥珀酰氨基取代的磺基苯基的单偶氮化合物或其盐，被两个或三个下式的基团取代的萘基：X 1或X 2中的任一个是磺基，另一个是甲氧基或乙氧基，Y是氟或氯原子或芳基氨基取代的具有一个或两个磺基，R为氢原子或未取代或取代的低级烷基，A为未取代或取代的亚苯基或亚萘基，Z为-SO2CH = CH2或-SO2CH2CH2Z1，其中Z1为能够通过碱的作用分裂，其可用作用于以各种牢度性能优异的绿黄色染色材料的纤维活性染料。

8. 发明授权

US5116956A Polyazo dye compounds having vinylsulfone type and pyridinium type fiber reactive groups 失效
标题翻译：具有乙烯基砜型和吡啶类型纤维反应性基团的聚氨酯染料化合物
公开(公告)号：US5116956A
公开(公告)日：1992-05-26
申请号：US524743
申请日：1990-05-17
申请人： Tetsuya Miyamoto , Kazufumi Yokogawa , Yutaka Kayane , Takashi Omura , Takeshi Washimi , Naoki Harada , Kingo Akahori
发明人： Tetsuya Miyamoto , Kazufumi Yokogawa , Yutaka Kayane , Takashi Omura , Takeshi Washimi , Naoki Harada , Kingo Akahori
IPC分类号： C09B62/44
CPC分类号： C09B62/4415
摘要： A polyazo compound of the following formula, ##STR1## wherein X is ##STR2## --NR.sub.2 R.sub.3, --OR.sub.4 or --SR.sub.5, in which R.sub.1 is hydrogen or alkyl, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are each hydrogen, alkyl, phenyl, naphthyl or benzyl, A is phenylene, naphthylene or alkylene, Z is a fiber-reactive group of --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Z' in which Z' is a splittable group, Y is pyridinio, and F is polyazo dye moiety carrying a fiber-reactive group like that represented by Z, which compound is useful for dyeing or printing fiber materials to obtain a product dyed or printed in a color superior in various fastness properties with superior build-up property.

9. 发明授权

US5112959A Polyazo dye compounds having plural vinylsulfone type fiber reactive groups in one molecule 失效
标题翻译：在一个分子中具有多种乙烯基纤维素类型的纤维反应组的聚氨基染料化合物
公开(公告)号：US5112959A
公开(公告)日：1992-05-12
申请号：US526708
申请日：1990-05-22
申请人： Tetsuya Miyamoto , Kazufumi Yokogawa , Yutaka Kayane , Takashi Omura , Takeshi Washimi , Naoki Harada , Kingo Akahori
发明人： Tetsuya Miyamoto , Kazufumi Yokogawa , Yutaka Kayane , Takashi Omura , Takeshi Washimi , Naoki Harada , Kingo Akahori
IPC分类号： C09B62/513
CPC分类号： C09B62/513
摘要： A polyazo compound of the following formula, ##STR1## wherein A is phenylene, naphthylene or alkylene, X is --NR.sub.2 R.sub.3, --OR.sub.4 or --SR.sub.5 in which R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are each hydrogen, alkyl, phenyl, naphthylene or benzyl, Z is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Z' in which Z' is a splittable group, R.sub.1 is hydrogen or alkyl, and F is polyazo dye moiety carrying a fiber reactive group like that represented by Z. This compound is useful for the dyeing or printing of fiber materials to obtain a product dyed or printed in a color superior in various fastness properties with superior build-up property.

10. 发明授权

US5486607A Dioxazine blue dye compound having vinylsulfone type fiber reactive groups 失效
标题翻译：具有乙烯基砜型纤维反应性基团的二恶嗪蓝染料化合物
公开(公告)号：US5486607A
公开(公告)日：1996-01-23
申请号：US379028
申请日：1995-01-27
申请人： Tetsuya Miyamoto , Miyao Takahashi , Takahiko Fujisaki , Naoki Harada , Yutaka Kayane , Takashi Omura
发明人： Tetsuya Miyamoto , Miyao Takahashi , Takahiko Fujisaki , Naoki Harada , Yutaka Kayane , Takashi Omura
IPC分类号： C07D498/04 , C09B62/503 , D06P1/38
CPC分类号： C09B62/5033
摘要： A dioxazine compound represented by the following formula in the free acid form, ##STR1## wherein V is a direct linkage or ##STR2## in which R.sub.3 is hydrogen or alkyl, X is a direct linkage or an aliphatic, araliphatic or aromatic bridging group, Y is phenylene or naphthylene, Z is a so-called vinylsulfone type fiber reactive group, and R.sub.1 and R.sub.2 are each hydrogen or alkyl, which is useful for dyeing or printing fiber materials to give a dyed or printed product of a blue color superior in fastness properties with superior build-up property.
摘要翻译：由游离酸形式的下式表示的二恶嗪化合物，其中V是直接键合或其中R 3是氢或烷基，X是直链或者脂族，芳脂族或芳族桥连基团，Y为亚苯基或亚萘基，Z为所谓的乙烯基砜型纤维反应性基团，R 1和R 2各自为氢或烷基，可用于染色或印花纤维材料染色或具有优异的牢固性能的蓝色的印刷产品具有优异的堆积性能。

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