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    • 2. 发明授权
    • Silver halide photographic materials
    • 卤化银照相材料
    • US4286044A
    • 1981-08-25
    • US176442
    • 1980-08-08
    • Yuji MiharaHaruo TakeiNoriyuki InoueTadashi IkedaKenichi Kuwabara
    • Yuji MiharaHaruo TakeiNoriyuki InoueTadashi IkedaKenichi Kuwabara
    • G03C1/28G03C1/29G03C1/08
    • G03C1/29
    • A lith-type silver halide photographic material having high sensitivity and providing good dot quality images comprising a support having coated thereon a silver halide emulsion containing a sensitizing dye of dimethine merocyanine type represented by formula (I) and a sensitizing dye represented by formula (II): ##STR1## wherein R.sub.1 represents a sulfoalkyl group, a carboxyalkyl group, a sulfoaralkyl group, or a carboxyaralkyl group; the alkyl moiety of each alkyl group contains up to 4 carbon atoms; R.sub.2 represents a substituted or unsubstituted alkyl group or an aryl group; R.sub.3 represents --(CH.sub.2).sub.n.sbsb.1 CONH(CH.sub.2).sub.m.sbsb.1 OH or --(CH.sub.2).sub.n.sbsb.2 O(CH.sub.2).sub.m.sbsb.2 OH (wherein m.sub.1, m.sub.2, n.sub.1, and n.sub.2 each is 1 to 7; m.sub.1 +n.sub.1 and m.sub.2 +n.sub.2 each is 8 or less); W represents a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, an alkoxy group or a substituted or unsubstituted phenyl group; ##STR2## wherein Z represents a non-metallic atomic group necessary to complete a thiazolidine ring or a 4-thiazoline ring; R.sub.4 and R.sub.5 each represent a substituted or unsubstituted alkyl group, an allyl group, or a substituted or unsubstituted phenyl group; at least one of R.sub.4 and R.sub.5 being a sulfoalkyl group or a carboxyalkyl group; and R.sub.6 represents a hydrogen atom, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted phenyl group.
    • 一种具有高灵敏度并且提供良好的点质量图像的锂离子型卤化银照相材料,其包含其上涂覆有包含式(I)表示的二甲亚砜部花青型敏化染料的卤化银乳剂的支持体和由式(II)表示的增感染料 ):其中R1表示磺基烷基,羧基烷基,磺基烷基或羧基烷基的(Ⅰ)化合物。 每个烷基的烷基部分含有至多4个碳原子; R2表示取代或未取代的烷基或芳基; R3表示 - (CH2)n1CONH(CH2)m1OH或 - (CH2)n2O(CH2)m2OH(其中m1,m2,n1和n2各自为1至7; m1 + n1和m2 + n2分别为8或更小) ; W表示氢原子,卤素原子,取代或未取代的烷基,烷氧基或取代或未取代的苯基; (II)其中Z表示完成噻唑烷环所需的非金属原子团或4-噻唑啉环; R4和R5各自表示取代或未取代的烷基,烯丙基或取代或未取代的苯基; R4和R5中的至少一个是磺基烷基或羧基烷基; R6表示氢原子,取代或未取代的烷基或取代或未取代的苯基。
    • 6. 发明授权
    • Silver halide photographic emulsion
    • 卤化银照相乳剂
    • US4040841A
    • 1977-08-09
    • US602508
    • 1975-08-06
    • Masanao HinataHaruo TakeiAkira SatoTadashi IkedaAtsuo Iwamoto
    • Masanao HinataHaruo TakeiAkira SatoTadashi IkedaAtsuo Iwamoto
    • G03C1/28G03C1/29G03C1/14
    • G03C1/29
    • A silver halide photographic emulsion spectrally sensitized in the relatively shorter wavelength region ranging from blue to green with a supersensitizing combination of at least one sensitizing dye represented by the general formula (I) ##STR1## WHEREIN Z.sup.1 represents the atoms necessary to form a benzimidazole ring, an oxazole ring, a benzoxazole ring or a naphthoxazole ring; Z.sup.2 represents the atoms necessary to form a thiazole ring, a benzothiazole ring, a naphthothiazole ring, a selenazole ring, a benzoselenazole ring or a naphthoselenazole ring; R.sup.1 and R.sup.2 each represents an aliphatic group containing up to 8 carbon atoms, which may be unsubstituted or substituted, and the carbon chain of which may be interrupted with an oxygen atom or a sulfur atom; R.sup.3 represents an alkyl group containing up to 3 carbon atoms, an aryl group or an aralkyl group; X.sup.1 represents an acid anion; and m represents 1 or 2, wherein m equals 1 when the dye forms an intramolecular salt; and at least one dye selected from the group consisting of a simple merocyanine and a dimethinemerocyanine dye, or with a supersensitizing combination of at least one sensitizing dye represented by the general formula (I) as defined above and at least one sensitizing dye represented by the general formula (II) ##STR2## wherein Z.sup.3 represents the atoms necessary to form a 5- or 6-membered heterocyclic ring; Q represents the atoms necessary to form a rhodanine ring, a thiohydantoin ring or a 2-thioxazolidinedione ring; R.sup.4 represents an aliphatic group containing up to 4 carbon atoms, which may be unsubstituted or substituted and the carbon chain of which may be interrupted by an oxygen atom or a sulfur atom; R.sup.5 represents a hydrogen atom, an alkyl group, an aryl group or an aralkyl group; and n represents 1 or 2.
    • 在由蓝色到绿色的相对短的波长区域中进行光谱增感的卤化银照相乳剂,其具有由通式(I)(I)表示的至少一种敏化染料的超敏化组合,其中Z1表示形成所需的原子 苯并咪唑环,恶唑环,苯并恶唑环或萘并恶唑环; Z2表示形成噻唑环所需的原子,苯并噻唑环,萘并噻唑环,硒咯环,苯并硒唑环或萘并吩唑环。 R1和R2各自表示含有至多8个碳原子的脂族基团,其可以是未取代的或取代的,并且其碳链可以被氧原子或硫原子间隔; R3表示含有至多3个碳原子的烷基,芳基或芳烷基; X1表示酸性阴离子; m表示1或2,当染料形成分子内盐时,m等于1; 和至少一种选自简单的部花菁和二甲基异亮氨酸染料的染料,或与如上定义的由通式(I)表示的至少一种敏化染料的超敏化组合和至少一种由 通式(II)(II)其中Z 3表示形成5-或6-元杂环所必需的原子; Q表示形成绕丹宁环所需的原子,硫代乙内酰脲环或2-噻恶唑烷二酮环; R4表示含有至多4个碳原子的脂族基团,其可以是未取代的或取代的,并且其碳链可被氧原子或硫原子间隔; R5表示氢原子,烷基,芳基或芳烷基; n表示1或2。
    • 8. 发明授权
    • Spectrally sensitized silver halide photographic emulsion
    • 光谱增感卤化银照相乳剂
    • US4010037A
    • 1977-03-01
    • US653995
    • 1976-01-28
    • Masanao HinataHaruo TakeiTadashi IkedaMitsuo Iwamoto
    • Masanao HinataHaruo TakeiTadashi IkedaMitsuo Iwamoto
    • G03C1/29G03C1/14
    • G03C1/29
    • A silver halide photographic emulsion containing, in combination, supersensitizing amounts of at least one sensitizing dye of the following general formula (I) ##STR1## wherein Z.sub.1 and Z.sub.2 each represents an atomic group required for forming a benzimidazole ring; R.sub.1 and R.sub.2 each represents an aliphatic group and at least one of R.sub.1 and R.sub.2 represents an alkyl group having a carboxy group, a hydroxyalkyl group or an alkyl group having a sulfo group; X.sub.1 represents an acid anion; and m is 1 or 2, m being 1 when the dye forms an inner salt (a betaine-like structure) and at least one sensitizing dye of the following general formula (II) ##STR2## wherein Z.sub.3 represents an atomic group required for forming a benzoxazole ring or a .beta.-naphthoxazole ring; Z.sub.4 represents an atomic group required for forming a benzothiazole ring, a benzoselenazole ring, a .beta.-naphthothiazole ring or a .beta.-naphthoselenazole ring; R.sub.3 and R.sub.4 each represents an aliphatic group and at least one of R.sub.3 and R.sub.4 represents an alkyl group having a carboxy group or an alkyl group having a sulfo group; R.sub.5 represents a hydrogen atom or an alkyl group; X.sub.2 represents an acid anion; and n is 1 or 2, n being 1 when the dye forms an inner salt.
    • 一种卤化银照相乳剂,其组合含有至少一种以下通式(I)的敏化染料的超敏化剂,其中Z1和Z2各自表示形成苯并咪唑环所需的原子团; R 1和R 2各自表示脂族基,R 1和R 2中的至少一个表示具有羧基,羟基烷基或具有磺基的烷基的烷基; X1表示酸性阴离子; m为1或2,当染料形成内盐(甜菜碱样结构)时,m为1,以及至少一种以下通式(II)的增感染料,其中Z 3表示原子团 形成苯并恶唑环或β-萘恶唑环所需的; Z4表示形成苯并噻唑环,苯并硒唑环,β-萘噻唑环或β-萘并噻唑环所需的原子团; R 3和R 4各自表示脂族基,R 3和R 4中的至少一个表示具有羧基或具有磺基的烷基的烷基; R5表示氢原子或烷基; X2表示酸性阴离子; n为1或2,当染料形成内盐时,n为1。